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Firefighting foam
Firefighting foam is a foam used for fire suppression. Its role is to cool the fire and to coat the fuel, preventing its contact with oxygen, thus achieving suppression of the combustion. Firefighting foam was invented by the Moldovan engineer and chemist Aleksandr Loran in 1902.
The surfactants used must produce foam in concentrations of less than 1%. Other components of fire-retardant foams are organic solvents (e.g., trimethyl-trimethylene glycol and hexylene glycol), foam stabilizers (e.g., lauryl alcohol), and corrosion inhibitors.
Class A foams were developed in the mid-1980s for fighting wildfires. Class A foams lower the surface tension of the water, which assists in the wetting and saturation of Class A foams with water. It penetrates and extinguishes embers at depth. This aids fire suppression and can prevent re-ignition. Favourable experiences led to its acceptance for fighting other types of class A fires, including structure fires.
Class B foams are designed for flammable liquid fire classes. The use of class A foam on a class B fire may yield unexpected results, as class A foams are not designed to contain the explosive vapours produced by flammable liquids. Class B foams have two major subtypes.
Synthetic foams are based on synthetic surfactants. They provide better flow and spreading over the surface of hydrocarbon-based liquids, for faster knockdown of flames. They have limited post-fire security and are toxic groundwater contaminants.
Protein foams contain natural proteins as the foaming agents. Unlike synthetic foams, protein foams are bio-degradable. They flow and spread slower, but provide a foam blanket that is more heat-resistant and more durable.
Protein foams include regular protein foam (P), fluoroprotein foam (FP) (a mixture of protein foam and fluorinated surfactants), film-forming fluoroprotein (FFFP),[full citation needed] alcohol-resistant fluoroprotein foam (AR-FP), and alcohol-resistant film-forming fluoroprotein (AR-FFFP).
Every type of foam has its application. High-expansion foams are used when an enclosed space, such as a basement or hangar, must be quickly filled. Low-expansion foams are used on burning spills. AFFF is the best for spills of jet fuels, FFFP is better for cases where the burning fuel can form deeper pools, and AR-AFFF is suitable for burning alcohols. High-performing FFF are viable alternatives to AFFF and AFFF-AR for various applications. The most flexibility is achieved by AR-AFFF or AR-FFFP. AR-AFFF must be used in areas where gasoline is blended with oxygenates, since the alcohols prevent the formation of the film between the FFFP foam and the gasoline, breaking down the foam, and rendering the FFFP foam virtually useless.
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Firefighting foam
Firefighting foam is a foam used for fire suppression. Its role is to cool the fire and to coat the fuel, preventing its contact with oxygen, thus achieving suppression of the combustion. Firefighting foam was invented by the Moldovan engineer and chemist Aleksandr Loran in 1902.
The surfactants used must produce foam in concentrations of less than 1%. Other components of fire-retardant foams are organic solvents (e.g., trimethyl-trimethylene glycol and hexylene glycol), foam stabilizers (e.g., lauryl alcohol), and corrosion inhibitors.
Class A foams were developed in the mid-1980s for fighting wildfires. Class A foams lower the surface tension of the water, which assists in the wetting and saturation of Class A foams with water. It penetrates and extinguishes embers at depth. This aids fire suppression and can prevent re-ignition. Favourable experiences led to its acceptance for fighting other types of class A fires, including structure fires.
Class B foams are designed for flammable liquid fire classes. The use of class A foam on a class B fire may yield unexpected results, as class A foams are not designed to contain the explosive vapours produced by flammable liquids. Class B foams have two major subtypes.
Synthetic foams are based on synthetic surfactants. They provide better flow and spreading over the surface of hydrocarbon-based liquids, for faster knockdown of flames. They have limited post-fire security and are toxic groundwater contaminants.
Protein foams contain natural proteins as the foaming agents. Unlike synthetic foams, protein foams are bio-degradable. They flow and spread slower, but provide a foam blanket that is more heat-resistant and more durable.
Protein foams include regular protein foam (P), fluoroprotein foam (FP) (a mixture of protein foam and fluorinated surfactants), film-forming fluoroprotein (FFFP),[full citation needed] alcohol-resistant fluoroprotein foam (AR-FP), and alcohol-resistant film-forming fluoroprotein (AR-FFFP).
Every type of foam has its application. High-expansion foams are used when an enclosed space, such as a basement or hangar, must be quickly filled. Low-expansion foams are used on burning spills. AFFF is the best for spills of jet fuels, FFFP is better for cases where the burning fuel can form deeper pools, and AR-AFFF is suitable for burning alcohols. High-performing FFF are viable alternatives to AFFF and AFFF-AR for various applications. The most flexibility is achieved by AR-AFFF or AR-FFFP. AR-AFFF must be used in areas where gasoline is blended with oxygenates, since the alcohols prevent the formation of the film between the FFFP foam and the gasoline, breaking down the foam, and rendering the FFFP foam virtually useless.