Hydrohalite | |
---|---|
General | |
Category | Halide mineral |
Formula | NaCl·2H2O |
IMA symbol | Hhl[1] |
Strunz classification | 3.BA.05 |
Dana classification | 9.1.2.1 |
Crystal system | Monoclinic |
Crystal class | Prismatic (2/m) (same H-M symbol) |
Space group | P21/c |
Identification | |
Colour | Colourless or white |
Diaphaneity | Transparent |
Hydrohalite is a halide mineral that occurs in saturated halite brines at cold temperatures (below 0.1 °C) and is the most common form of hydrated sodium chloride. It was first described in 1847 from an occurrence in Dürrnberg, Austria.
Hydrohalite has a high nucleation energy, it decomposes at 0.1°C, giving a salty brine and solid halite.
The cryohydric point of hydrohalite is at −21.2 °C (−6.2 °F), solutions will normally need to be supercooled for crystals to form. Above this temperature, liquid water saturated with salt can exist in equilibrium with hydrohalite. Unlike halite, hydrohalite has a strong positive temperature coefficient of solubility.[2] Under pressure, hydrohalite is stable between 7,900 and 11,600 atmospheres pressure. The decomposition point increases at the rate of 0.007K per atmosphere (for 1–1000 atmospheres),[2] reaching a maximum decomposition temperature is at 25.8°C around 9400 atmospheres. The decomposition temperature reduces again at higher pressures.[2]
The type locality is the Hallein Salt Mine in Austria.[3]
Hydrohalite was discovered on Ceres by Dawn,[4] suggesting an early ocean, possibly surviving as a relict ocean.