The M25 or London Orbital Motorway is a major ring road encircling most of Greater London. The 117-mile-long (188 km) motorway is one of the most important roads in the UK and one of the busiest. Margaret Thatcher opened the final section in 1986, making the M25 the longest ring road in Europe upon opening. The Dartford Crossing completes the orbital route but is not classed as motorway; it is classed as a trunk road and designated as the A282. In some cases, including notable legal contexts such as the Communications Act 2003, the M25 is used as a de facto alternative boundary for Greater London.

In the 1944 Greater London Plan, Patrick Abercrombie proposed an orbital motorway around London. This evolved into the London Ringways project in the early 1960s, and by 1966, planning had started on two projects, Ringway 3 to the north and Ringway 4 to the south. By the time the first sections opened in 1975, it was decided the ringways would be combined into a single orbital motorway. The M25 was one of the first motorway projects to consider environmental concerns and almost 40 public inquiries took place. The road was built as planned despite some protests that included the section over the North Downs and around Epping Forest which required an extension of the Bell Common Tunnel.

Although the M25 was popular during construction, it quickly became apparent that there was insufficient traffic capacity. Because of the public inquiries, several junctions merely served local roads where office and retail developments were built, attracting even more traffic onto the M25 than it was designed for. The congestion has led to traffic management schemes that include variable speed limit and smart motorway. Since opening, the M25 has been progressively widened, particularly near Heathrow Airport where it is a dual six-lane carriageway.

The M25 almost completely encircles Greater London and passes briefly through it, in the east and west. Junctions 1A–5 are in Kent, 6–13 are in Surrey, 14 and a small part of 15 are in Hillingdon, Greater London, 15–16 are in Buckinghamshire, 17–24 are in Hertfordshire, 25 is in Enfield, Greater London and 26–31 are in Essex. Law enforcement on the road is carried out by an integrated group made up of the Metropolitan, Thames Valley, Essex, Kent, Hertfordshire and Surrey police services. Primary destinations signed ahead on the motorway include the Dartford Crossing, Sevenoaks, Gatwick Airport, Heathrow Airport, Watford, Stansted Airport and Brentwood.

To the east of London the two ends of the M25 are joined to complete a loop by the non-motorway A282 Dartford Crossing of the River Thames between Thurrock and Dartford. The crossing consists of twin two-lane tunnels and the four-lane QE2 (Queen Elizabeth II) bridge, with a main span of 450 metres (1,480 ft). Passage across the bridge or through the tunnels is subject to a charge between 6 am and 10 pm, its level depending on the kind of vehicle. The road is not under motorway regulations so that other traffic can cross the Thames east of the Woolwich Ferry; the only crossing further to the east is a passenger ferry between Gravesend, Kent, and Tilbury, Essex.

At junction 5, the clockwise carriageway of the M25 is routed off the main north–south dual carriageway onto the main east–west dual carriageway with the main north–south carriageway becoming the A21. In the opposite direction, to the east of the point where the M25 diverges from the main east–west carriageway, that carriageway becomes the M26 motorway. From here to junction 8, the M25 follows the edge of the North Downs close to several historic buildings such as Chevening, Titsey Place, Hever Castle and Chartwell. The interchange with the M23 motorway near Reigate is a four-level stack; one of only a few examples in Britain. Past this, the M25 runs close to the Surrey Hills National Landscape.

To the west, the M25 passes close to the edge of Heathrow Airport, and within sight of Windsor Castle. North of this, it goes under the Chalfont Viaduct railway bridge, completed in 1906, which carries the Chiltern Main Line. Red kites can often be seen overhead to the north of this, up to junction 21. The northern section of the M25 passes close to All Saints Pastoral Centre near London Colney, Waltham Abbey and Copped Hall. This section also features two cut-and-cover tunnels, including the Bell Common Tunnel. The north-eastern section of the motorway passes close to North Ockendon, the only settlement of Greater London situated outside the M25. It then runs close to the Rainham Marshes Nature Reserve before reaching the northern end of the Dartford Crossing.

In 2004, following an opinion poll, the London Assembly proposed aligning the Greater London boundary with the M25. "Inside the M25" and "outside/beyond the M25" are colloquial, looser alternatives to "Greater London" sometimes used in haulage. The Communications Act 2003 explicitly uses the M25 as the boundary in requiring a proportion of television programmes to be made outside the London area; it states a requirement of "a suitable proportion of the programmes made in the United Kingdom" to be made "in the United Kingdom outside the M25 area", defined in Section 362 as "the area the outer boundary of which is represented by the London Orbital Motorway (M25)".