The 2013 Copa Venezuela was the 44th staging of the Copa Venezuela. The winner qualified for the 2014 Copa Sudamericana.
| Team 1 | Agg. | Team 2 | 1st leg | 2nd leg |
|---|---|---|---|---|
| Central & Oriental Group | ||||
| Universidad Central | 2–1 | Arroceros de Calabozo | 0–0 | 2–1 |
| Angostura FC | 0–1 | Estudiantes de Caroní | 0–1 | 0–0 |
| Occidental Group | ||||
| Unión Atlético Falcón | 3–1 | Universidad de los Andes | 1–0 | 2–1 |
| Lotería del Táchira | 2–2 (a) | Deportivo San Antonio | 2–2 | 0–0 |
| Team 1 | Agg. | Team 2 | 1st leg | 2nd leg |
|---|---|---|---|---|
| Central & Oriental Group | ||||
| Guatire FC | 2–1 | Tucanes de Amazonas | 1–0 | 1–1 |
| Universidad Central | 0–2 | Caracas FC | 0–0 | 0–2 |
| Estudiantes de Caroní | 2–4 | Mineros de Guayana | 1–3 | 1–1 |
| SC Guaraní | 1–6 | Aragua FC | 0–3 | 1–3 |
| Metropolitanos FC | 1–2 | Deportivo La Guaira | 1–0 | 0–2 |
| Real Anzoátegui | 2–3 | Atlético Venezuela | 1–0 | 1–3 |
| Monagas SC | 3–3 (a) | Deportivo Petare | 2–3 | 1–0 |
| Occidental Group | ||||
| Ureña SC | 1–6 | Deportivo Táchira | 1–2 | 0–4 |
| Deportivo San Antonio | 1–8 | Atlético El Vigía | 1–3 | 0–5 |
| Unión Atlético Falcón | 3–4 | Trujillanos FC | 3–1 | 0–3 |
| Portuguesa FC | 3–2 | Deportivo Lara | 2–1 | 1–1 |
| Policía de Lara | 4–4 (a) | Llaneros de Guanare | 2–0 | 2–4 |
| Yaracuyanos FC | 2–1 | Zulia FC | 1–1 | 1–0 |
| Carabobo FC | 0–5 | Estudiantes de Mérida | 0–0 | 0–5 |
| Team 1 | Agg. | Team 2 | 1st leg | 2nd leg |
|---|---|---|---|---|
| Central & Oriental Group | ||||
| Guatire FC | 2–5 | Deportivo Petare | 0–3 | 2–2 |
| Caracas FC | 3–1 | Atlético Venezuela | 2–0 | 1–1 |
| Aragua FC | 2–1 | Deportivo La Guaira | 1–0 | 1–1 |
| Mineros de Guayana | 2–2 (3–5 p) | Deportivo Anzoátegui | 2–0 | 0–2 |
| Occidental Group | ||||
| Trujillanos FC | 3–2 | Estudiantes de Mérida | 1–1 | 2–1 |
| Policía de Lara | 4–9 | Zamora FC | 0–3 | 4–6 |
| Portuguesa FC | 3–5 | Yaracuyanos FC | 2–3 | 1–2 |
| Atlético El Vigía | 1–3 | Deportivo Táchira | 1–1 | 0–2 |
| Team 1 | Agg. | Team 2 | 1st leg | 2nd leg |
|---|---|---|---|---|
| Central & Oriental Group | ||||
| Caracas FC | 4–2 | Deportivo Petare | 1–0 | 3–2 |
| Deportivo Anzoátegui | 2–4 | Aragua FC | 1–1 | 1–3 |
| Occidental Group | ||||
| Zamora FC | 2–1 | Trujillanos FC | 2–0 | 0–1 |
| Deportivo Táchira | 2–2 (3–1 p) | Yaracuyanos FC | 0–2 | 2–0 |
| Team 1 | Agg. | Team 2 | 1st leg | 2nd leg |
|---|---|---|---|---|
| Central & Oriental Group | ||||
| Aragua FC | 1–3 | Caracas FC | 0–1 | 1–2 |
| Occidental Group | ||||
| Deportivo Táchira | 3–0 | Zamora FC | 1–0 | 2–0 |
First leg: November 27; Second leg: December 5.
| Team 1 | Agg. | Team 2 | 1st leg | 2nd leg |
|---|---|---|---|---|
| Deportivo Táchira | 2–3 | Caracas FC | 2–1 | 0–2 |
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