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Bromine perchlorate

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Bromine perchlorate

Bromine perchlorate is an inorganic chemical compound with the formula BrClO4. Its structure is Br−O−ClO3. It is a shock and light-sensitive red liquid which decomposes above −20 °C.

Bromine perchlorate can be produced from the reaction of cesium perchlorate and bromine fluorosulfate at −20 °C:

Alternatively, it can also be produced by the reaction of chlorine perchlorate and bromine at -45 °C. Bromine perchlorate reacts with hydrogen bromide to regenerate bromine:

This compound also reacts with cesium perchlorate, to produce Cs+[Br(ClO4)2] (caesium diperchloratobromate(I)), and various fluorocarbon halides, to produce fluoroalkyl perchlorates.

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