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C-4 (explosive)
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C-4 (explosive)
C-4 or Composition C-4 is a common variety of the plastic explosive family known as Composition C, which uses RDX as its explosive agent. C-4 is composed of explosives, plastic binder, plasticizer to make it malleable, and usually a marker or odorizing taggant chemical. C-4 has a texture similar to modelling clay and can be molded into any desired shape. C-4 is relatively insensitive and can be detonated only by the shock wave from a detonator or blasting cap.
A similar British plastic explosive, also based on RDX but with a plasticizer different from that used in Composition C-4, is known as PE-4 (Plastic Explosive No. 4).
C-4 is a member of the Composition C family of chemical explosives. Variants have different proportions and plasticisers and include compositions C-2, C-3, and C-4. The original RDX-based material was developed by the British during World War II and redeveloped as Composition C when introduced to the U.S. military. It was replaced by Composition C-2 around 1943 and later redeveloped around 1944 as Composition C-3. The toxicity of C-3 was reduced, the concentration of RDX was increased, giving it improved safety during usage and storage. Research on a replacement for C-3 was begun prior to 1950, but the new material, C-4, did not begin pilot production until 1956. C-4 was submitted for patent as "Solid Propellant and a Process for its Preparation" March 31, 1958, by the Phillips Petroleum Company.
The Composition C-4 used by the United States Armed Forces contains 91% RDX ("Research Department Explosive", an explosive nitroamine), bound by a mixture of 5.3% dioctyl sebacate (DOS) or dioctyl adipate (DOA) as the plasticizer (to increase the plasticity of the explosive), thickened with 2.1% polyisobutylene (PIB, a synthetic rubber) as the binder, and 1.6% of a mineral oil often called "process oil". Instead of "process oil", low-viscosity motor oil is used in the manufacture of C-4 for civilian use.
The British PE4 consists of 88.0% RDX, 1.0% pentaerythrite dioleate and 11.0% DG-29 lithium grease (corresp. to 2.2% lithium stearate and 8.8% mineral oil BP) as the binder; a taggant (2,3-dimethyl-2,3-dinitrobutane, DMDNB) is added at a minimum of 0.10% weight of the plastic explosive, typically at 1.0% mass. The newer PE7 consists of 88.0% RDX, 1.0% DMDNB taggant and 11.0% of a binder composed of low molecular mass hydroxyl-terminated polybutadiene, along with an antioxidant and an agent preventing hardening of the binder upon prolonged storage. The PE8 consists of 86.5% RDX, 1.0% DMDNB taggant and 12.5% of a binder composed of di(2-ethylhexyl) sebacate thickened with high molecular mass polyisobutylene.
Technical data according to the Department of the Army for the Composition C-4 follows.
C-4 is manufactured by combining the above ingredients with binders dissolved in a solvent. Once the ingredients have been mixed, the solvent is extracted through drying and filtering. The final material is a solid with a dirty white to light brown color, a putty-like texture similar to modeling clay, and a distinct smell of motor oil. Depending on its intended usage and on the manufacturer, there are differences in the composition of C-4. For example, a 1990 U.S. Army technical manual stipulated that Class IV composition C-4 consists of 89.9±1% RDX, 10±1% polyisobutylene, and 0.2±0.02% dye that is itself made up of 90% lead chromate and 10% lamp black. RDX classes A, B, E, and H are all suitable for use in C-4. Classes are measured by granulation.
The manufacturing process for Composition C-4 specifies that wet RDX and plastic binder are added in a stainless steel mixing kettle. This is called the aqueous slurry-coating process. The kettle is tumbled to obtain a homogeneous mixture. This mixture is wet and must be dried after transfer to drying trays. Drying with forced air for 16 hours at 50 °C to 60 °C is recommended to eliminate excess moisture.
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C-4 (explosive)
C-4 or Composition C-4 is a common variety of the plastic explosive family known as Composition C, which uses RDX as its explosive agent. C-4 is composed of explosives, plastic binder, plasticizer to make it malleable, and usually a marker or odorizing taggant chemical. C-4 has a texture similar to modelling clay and can be molded into any desired shape. C-4 is relatively insensitive and can be detonated only by the shock wave from a detonator or blasting cap.
A similar British plastic explosive, also based on RDX but with a plasticizer different from that used in Composition C-4, is known as PE-4 (Plastic Explosive No. 4).
C-4 is a member of the Composition C family of chemical explosives. Variants have different proportions and plasticisers and include compositions C-2, C-3, and C-4. The original RDX-based material was developed by the British during World War II and redeveloped as Composition C when introduced to the U.S. military. It was replaced by Composition C-2 around 1943 and later redeveloped around 1944 as Composition C-3. The toxicity of C-3 was reduced, the concentration of RDX was increased, giving it improved safety during usage and storage. Research on a replacement for C-3 was begun prior to 1950, but the new material, C-4, did not begin pilot production until 1956. C-4 was submitted for patent as "Solid Propellant and a Process for its Preparation" March 31, 1958, by the Phillips Petroleum Company.
The Composition C-4 used by the United States Armed Forces contains 91% RDX ("Research Department Explosive", an explosive nitroamine), bound by a mixture of 5.3% dioctyl sebacate (DOS) or dioctyl adipate (DOA) as the plasticizer (to increase the plasticity of the explosive), thickened with 2.1% polyisobutylene (PIB, a synthetic rubber) as the binder, and 1.6% of a mineral oil often called "process oil". Instead of "process oil", low-viscosity motor oil is used in the manufacture of C-4 for civilian use.
The British PE4 consists of 88.0% RDX, 1.0% pentaerythrite dioleate and 11.0% DG-29 lithium grease (corresp. to 2.2% lithium stearate and 8.8% mineral oil BP) as the binder; a taggant (2,3-dimethyl-2,3-dinitrobutane, DMDNB) is added at a minimum of 0.10% weight of the plastic explosive, typically at 1.0% mass. The newer PE7 consists of 88.0% RDX, 1.0% DMDNB taggant and 11.0% of a binder composed of low molecular mass hydroxyl-terminated polybutadiene, along with an antioxidant and an agent preventing hardening of the binder upon prolonged storage. The PE8 consists of 86.5% RDX, 1.0% DMDNB taggant and 12.5% of a binder composed of di(2-ethylhexyl) sebacate thickened with high molecular mass polyisobutylene.
Technical data according to the Department of the Army for the Composition C-4 follows.
C-4 is manufactured by combining the above ingredients with binders dissolved in a solvent. Once the ingredients have been mixed, the solvent is extracted through drying and filtering. The final material is a solid with a dirty white to light brown color, a putty-like texture similar to modeling clay, and a distinct smell of motor oil. Depending on its intended usage and on the manufacturer, there are differences in the composition of C-4. For example, a 1990 U.S. Army technical manual stipulated that Class IV composition C-4 consists of 89.9±1% RDX, 10±1% polyisobutylene, and 0.2±0.02% dye that is itself made up of 90% lead chromate and 10% lamp black. RDX classes A, B, E, and H are all suitable for use in C-4. Classes are measured by granulation.
The manufacturing process for Composition C-4 specifies that wet RDX and plastic binder are added in a stainless steel mixing kettle. This is called the aqueous slurry-coating process. The kettle is tumbled to obtain a homogeneous mixture. This mixture is wet and must be dried after transfer to drying trays. Drying with forced air for 16 hours at 50 °C to 60 °C is recommended to eliminate excess moisture.