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Chlorosoman
Chlorosoman is a chlorine analog of soman. It is a highly toxic organophosphorus compound and used as the precursor substance for soman nerve agent. Its physical properties are estimated. Soman is insoluble in water, with a boiling point of 223 degrees Celsius and a melting point of -27 degrees Celsius. Chlorosoman is at least 2.5x less toxic than its analogue.
The ClG series of compounds is used more as a precursor to highly toxic compounds. For example, soman is a precursor to EA-2613 and EA-3209.
ClGD follows the same synthetic route as soman, with fluoridation being omitted. Chlorosoman is prepared by the Finkelstein reaction between a solution of sodium chloride in DMF and soman. A fluoride substitution is hypothetically made by the metathetic reaction between soman, anhydrous aluminum chloride, and sodium chloride in a suitable solvent, precipitating sodium hexafluoroaluminate.
![{\displaystyle {6\,\mathrm {CH} {\vphantom {A}}_{\smash[{t}]{3}}\mathrm {P} (\mathrm {O} )\mathrm {FOCH} {\vphantom {A}}_{\smash[{t}]{3}}\mathrm {CHC} (\mathrm {CH} {\vphantom {A}}_{\smash[{t}]{3}}){\vphantom {A}}_{\smash[{t}]{3}}{}+{}\mathrm {AlCl} {\vphantom {A}}_{\smash[{t}]{3}}{}+{}3\,\mathrm {NaCl} {}\mathrel {\longrightarrow } {}6\,\mathrm {CH} {\vphantom {A}}_{\smash[{t}]{3}}\mathrm {P} (\mathrm {O} )\mathrm {ClOCH} {\vphantom {A}}_{\smash[{t}]{3}}\mathrm {CHC} (\mathrm {CH} {\vphantom {A}}_{\smash[{t}]{3}}){\vphantom {A}}_{\smash[{t}]{3}}{}+{}\mathrm {Na} {\vphantom {A}}_{\smash[{t}]{3}}\mathrm {AlF} {\vphantom {A}}_{\smash[{t}]{6}}\mathrm {v} }}](https://wikimedia.org/api/rest_v1/media/math/render/svg/77b895b5b90401e1325b5aaa037dec7710c5b124)
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Chlorosoman
Chlorosoman is a chlorine analog of soman. It is a highly toxic organophosphorus compound and used as the precursor substance for soman nerve agent. Its physical properties are estimated. Soman is insoluble in water, with a boiling point of 223 degrees Celsius and a melting point of -27 degrees Celsius. Chlorosoman is at least 2.5x less toxic than its analogue.
The ClG series of compounds is used more as a precursor to highly toxic compounds. For example, soman is a precursor to EA-2613 and EA-3209.
ClGD follows the same synthetic route as soman, with fluoridation being omitted. Chlorosoman is prepared by the Finkelstein reaction between a solution of sodium chloride in DMF and soman. A fluoride substitution is hypothetically made by the metathetic reaction between soman, anhydrous aluminum chloride, and sodium chloride in a suitable solvent, precipitating sodium hexafluoroaluminate.