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Cordite

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Cordite

Cordite is a family of smokeless propellants developed and produced in Britain since 1889 to replace black powder as a military firearm propellant. Cordite is a mixture of nitrocellulose and nitroglycerine, and is therefore a mixture of a chemical high explosive stabilized with a low explosive. These produce a subsonic deflagration wave rather than the supersonic detonation wave produced by brisants, or high explosives.[not verified in body] The hot gases produced by burning gunpowder or cordite generate sufficient pressure to propel a bullet or shell to its target, but not so quickly as to routinely destroy the barrel of the gun.[not verified in body]

Cordite was used initially in the .303 British, Mark I and II, standard rifle cartridge between 1891 and 1915.[not verified in body] Shortages of cordite in World War I led to the creation of the "Devil's Porridge" munitions factory (HM Factory, Gretna) on the English–Scottish border, which produced around 800 tonnes of cordite per week. The UK also imported some United States–developed smokeless powders for use in rifle cartridges. Cordite was also used for large weapons, such as tank guns, artillery, and naval guns. It has been used mainly for this purpose since the late 19th century by the UK and British Commonwealth countries. Its use was further developed before World War II, and as 2-and-3-inch-diameter (51 and 76 mm) Unrotated Projectiles for launching anti-aircraft weapons. Small cordite rocket charges were also developed for ejector seats made by the Martin-Baker Company. Cordite was also used in the detonation system of the Little Boy atomic bomb dropped over Hiroshima in August 1945.

The term "cordite" generally disappeared from official publications between the wars. During World War II, double-base propellants were very widely used, and there was some use of triple-base propellants by artillery. Triple-base propellants were used in post-war ammunition designs and remain in production for UK weapons; most double-base propellants left service as World War II stocks were expended after the war. For small arms it has been replaced by other propellants, such as the Improved Military Rifle (IMR) line of extruded powder or the WC844 ball propellant currently in use in the 5.56×45mm NATO. Production ceased in the United Kingdom around the end of the 20th century, with the closure of the last of the World War II cordite factories, ROF Bishopton. Triple-base propellant for UK service (for example, the 105 mm L118 Light Gun) is now manufactured in Germany.

Gunpowder, a combustable mixture of sulfur, charcoal and potassium nitrate (also known as saltpetre), was the original propellant employed in firearms and fireworks. It was used from about the 10th or 11th century onward, but it had disadvantages, including the large amount of smoke it produced. With the 19th-century development of various "nitro explosives", based on the reaction of nitric acid mixtures on materials such as cellulose and glycerin, a search began for a replacement for gunpowder.

The first smokeless powder was developed in 1865 by Johann Edward Schultze. At the time of this breakthrough, Schultze was a captain of Prussian artillery. Schultze eventually rose to the rank of colonel. His formulation (dubbed Schultze Powder) was composed of nitrolignose derived from nitrated wood grains, impregnated with saltpetre or barium nitrate.

In 1882, the Explosive Company of Stowmarket introduced EC Powder, which contained nitro-cotton and nitrates of potassium and barium in a grain gelatinised by ether alcohol. It had coarser grains than other nitrocellulose powders. It proved unsuitable for rifles, but it remained in long use for shotguns and was later used for grenades and fragmentation bombs.

In 1884, the French chemist Paul Vieille produced a smokeless propellant that had some success. It was made out of collodion (nitrocellulose dissolved in ethanol and ether), resulting in a plastic colloidal substance which was rolled into very thin sheets, then dried and cut up into small flakes. It was immediately adopted by the French military for their Mle 1886 infantry rifle and called Poudre B (for poudre blanche, or white powder) to distinguish it from black powder (gunpowder). The rifle and the cartridge developed to use this powder were known generically as the 8mm Lebel, after the officer who developed its 8 mm full metal jacket bullet.

The following year, 1887, Alfred Nobel invented and patented a smokeless propellant he called Ballistite. It was composed of 10% camphor, 45% nitroglycerine and 45% collodion (nitrocellulose). Over time the camphor tended to evaporate, leaving an unstable explosive.

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