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Disulfuryl fluoride
Disulfuryl fluoride is an inorganic compound of sulfur, fluorine, and oxygen with the chemical formula S2O5F2.
Autoclave heating of sulfur trioxide and calcium fluoride:
The compound can be produced by the reaction of SSF2 and FOSO2F in deuterated chloroform at −100 °C:
It can also be produced in the reaction of iodine pentafluoride and sulfur trioxide.
Other methods are also known.
Pyrosulfuryl difluoride forms a colorless liquid that smokes slightly in the air. It causes severe suffocation and resembles phosgene in its action.
When heated, the compound is stable to a temperature of 200 °C.
It is slowly hydrolyzed by water:
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Disulfuryl fluoride
Disulfuryl fluoride is an inorganic compound of sulfur, fluorine, and oxygen with the chemical formula S2O5F2.
Autoclave heating of sulfur trioxide and calcium fluoride:
The compound can be produced by the reaction of SSF2 and FOSO2F in deuterated chloroform at −100 °C:
It can also be produced in the reaction of iodine pentafluoride and sulfur trioxide.
Other methods are also known.
Pyrosulfuryl difluoride forms a colorless liquid that smokes slightly in the air. It causes severe suffocation and resembles phosgene in its action.
When heated, the compound is stable to a temperature of 200 °C.
It is slowly hydrolyzed by water: