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Iron(II) sulfate
Iron(II) sulfate or ferrous sulfate (British English: sulphate instead of sulfate) denotes a range of salts with the formula FeSO4·xH2O. These compounds exist most commonly as the heptahydrate (x = 7), but several values for x are known. The hydrated form is used medically to treat or prevent iron deficiency, and also for industrial applications. Known since ancient times as copperas and as green vitriol (vitriol is an archaic name for hydrated sulfate minerals), the blue-green heptahydrate (hydrate with 7 molecules of water) is the most common form of this material. All the iron(II) sulfates dissolve in water to give the same aquo complex [Fe(H2O)6]2+, which has octahedral molecular geometry and is paramagnetic. The name copperas dates from times when the copper(II) sulfate was known as blue copperas, and perhaps in analogy, iron(II) and zinc sulfate were known respectively as green and white copperas.
It is on the World Health Organization's List of Essential Medicines. In 2023, it was the 89th most commonly prescribed medication in the United States, with more than 7 million prescriptions.
Industrially, ferrous sulfate is mainly used as a precursor to other iron compounds. It is a reducing agent, and as such is useful for the reduction of chromate in cement to less toxic Cr(III) compounds. Historically, ferrous sulfate was used in the textile industry for centuries as a dye fixative. It is used historically to blacken leather and as a constituent of iron gall ink. The preparation of sulfuric acid ('oil of vitriol') by the distillation of green vitriol (iron(II) sulfate) has been known for at least 700 years.
Iron(II) sulfate is sold as ferrous sulfate, a soil amendment for lowering the pH of a high alkaline soil so that plants can access the soil's nutrients.
In horticulture, it is used for treating iron chlorosis. Although not as rapid-acting as ferric EDTA, its effects are longer-lasting. It can be mixed with compost and dug into the soil to create a store, which can last for years. Ferrous sulfate can be used as a lawn conditioner. It can also be used to eliminate silvery thread moss in golf course putting greens.
Ferrous sulfate can be used to stain concrete and some limestones and sandstones a yellowish rust color.
Woodworkers use ferrous sulfate solutions to color maple wood a silvery hue.
Green vitriol is also a useful reagent in the identification of mushrooms.
Hub AI
Iron(II) sulfate AI simulator
(@Iron(II) sulfate_simulator)
Iron(II) sulfate
Iron(II) sulfate or ferrous sulfate (British English: sulphate instead of sulfate) denotes a range of salts with the formula FeSO4·xH2O. These compounds exist most commonly as the heptahydrate (x = 7), but several values for x are known. The hydrated form is used medically to treat or prevent iron deficiency, and also for industrial applications. Known since ancient times as copperas and as green vitriol (vitriol is an archaic name for hydrated sulfate minerals), the blue-green heptahydrate (hydrate with 7 molecules of water) is the most common form of this material. All the iron(II) sulfates dissolve in water to give the same aquo complex [Fe(H2O)6]2+, which has octahedral molecular geometry and is paramagnetic. The name copperas dates from times when the copper(II) sulfate was known as blue copperas, and perhaps in analogy, iron(II) and zinc sulfate were known respectively as green and white copperas.
It is on the World Health Organization's List of Essential Medicines. In 2023, it was the 89th most commonly prescribed medication in the United States, with more than 7 million prescriptions.
Industrially, ferrous sulfate is mainly used as a precursor to other iron compounds. It is a reducing agent, and as such is useful for the reduction of chromate in cement to less toxic Cr(III) compounds. Historically, ferrous sulfate was used in the textile industry for centuries as a dye fixative. It is used historically to blacken leather and as a constituent of iron gall ink. The preparation of sulfuric acid ('oil of vitriol') by the distillation of green vitriol (iron(II) sulfate) has been known for at least 700 years.
Iron(II) sulfate is sold as ferrous sulfate, a soil amendment for lowering the pH of a high alkaline soil so that plants can access the soil's nutrients.
In horticulture, it is used for treating iron chlorosis. Although not as rapid-acting as ferric EDTA, its effects are longer-lasting. It can be mixed with compost and dug into the soil to create a store, which can last for years. Ferrous sulfate can be used as a lawn conditioner. It can also be used to eliminate silvery thread moss in golf course putting greens.
Ferrous sulfate can be used to stain concrete and some limestones and sandstones a yellowish rust color.
Woodworkers use ferrous sulfate solutions to color maple wood a silvery hue.
Green vitriol is also a useful reagent in the identification of mushrooms.
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