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Fluorite
Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon.
The Mohs scale of mineral hardness, based on scratch hardness comparison, defines value 4 as fluorite.
Pure fluorite is colourless and transparent, both in visible and ultraviolet light, but impurities usually make it a colorful mineral and the stone has ornamental and lapidary uses. Industrially, fluorite is used as a flux for smelting, and in the production of certain glasses and enamels. The purest grades of fluorite are a source of fluoride for hydrofluoric acid manufacture, which is the intermediate source of most fluorine-containing fine chemicals. Optically clear transparent fluorite has anomalous partial dispersion, that is, its refractive index varies with the wavelength of light in a manner that differs from that of commonly used glasses, so fluorite is useful in making apochromatic lenses, and particularly valuable in photographic optics. Fluorite optics are also usable in the far-ultraviolet and mid-infrared ranges, where conventional glasses are too opaque for use. Fluorite also has low dispersion, and a high refractive index for its density.
The word fluorite is derived from the Latin verb fluere, meaning to flow. The mineral is used as a flux in iron smelting to decrease the viscosity of slag. The term flux comes from the Latin adjective fluxus, meaning flowing, loose, slack. The mineral fluorite, originally termed fluorspar, was first printed in a 1530 work Bermannvs sive de re metallica dialogus [Bermannus; or dialogue about the nature of metals], by Georgius Agricola, as a mineral noted for its usefulness as a flux. Agricola, a German scientist with expertise in philology, mining, and metallurgy, named fluorspar as a Neo-Latinization of the German Flussspat from Fluss (short for Flussmittel smelting flux) and Spat (meaning a nonmetallic mineral akin to gypsum, spærstān, spear stone, referring to its crystalline projections).
In 1852, fluorite gave its name to the phenomenon of fluorescence, which is prominent in fluorites from certain locations, due to certain impurities in the crystal. Fluorite also gave the name to its constitutive element fluorine. Currently, the word "fluorspar" is most commonly used for fluorite as an industrial and chemical commodity, while "fluorite" is used mineralogically and in most other senses.
In archeology, gemmology, classical studies, and Egyptology, the Latin terms murrina and myrrhina refer to fluorite. In book 37 of his Naturalis Historia, Pliny the Elder describes it as a precious stone with purple and white mottling, and noted that the Romans prized objects carved from it. It has been suggested that the Sanskrit mineral name vaikrānta (वैक्रान्तः), known from Sanskrit alchemical texts dating from the early second millennium CE onwards, may refer to fluorite.
Fluorite crystallizes in a cubic motif. Crystal twinning is common and adds complexity to the observed crystal habits. Fluorite has four perfect cleavage planes that help produce octahedral fragments. The structural motif adopted by fluorite is so common that the motif is called the fluorite structure. Element substitution for the calcium cation often includes strontium and certain rare-earth elements (REE), such as yttrium and cerium.
Fluorite forms as a late-crystallizing mineral in felsic igneous rocks typically through hydrothermal activity. It is particularly common in granitic pegmatites. It may occur as a vein deposit formed through hydrothermal activity particularly in limestones. In such vein deposits it can be associated with galena, sphalerite, barite, quartz, and calcite. Fluorite can also be found as a constituent of sedimentary rocks either as grains or as the cementing material in sandstone.
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Fluorite
Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon.
The Mohs scale of mineral hardness, based on scratch hardness comparison, defines value 4 as fluorite.
Pure fluorite is colourless and transparent, both in visible and ultraviolet light, but impurities usually make it a colorful mineral and the stone has ornamental and lapidary uses. Industrially, fluorite is used as a flux for smelting, and in the production of certain glasses and enamels. The purest grades of fluorite are a source of fluoride for hydrofluoric acid manufacture, which is the intermediate source of most fluorine-containing fine chemicals. Optically clear transparent fluorite has anomalous partial dispersion, that is, its refractive index varies with the wavelength of light in a manner that differs from that of commonly used glasses, so fluorite is useful in making apochromatic lenses, and particularly valuable in photographic optics. Fluorite optics are also usable in the far-ultraviolet and mid-infrared ranges, where conventional glasses are too opaque for use. Fluorite also has low dispersion, and a high refractive index for its density.
The word fluorite is derived from the Latin verb fluere, meaning to flow. The mineral is used as a flux in iron smelting to decrease the viscosity of slag. The term flux comes from the Latin adjective fluxus, meaning flowing, loose, slack. The mineral fluorite, originally termed fluorspar, was first printed in a 1530 work Bermannvs sive de re metallica dialogus [Bermannus; or dialogue about the nature of metals], by Georgius Agricola, as a mineral noted for its usefulness as a flux. Agricola, a German scientist with expertise in philology, mining, and metallurgy, named fluorspar as a Neo-Latinization of the German Flussspat from Fluss (short for Flussmittel smelting flux) and Spat (meaning a nonmetallic mineral akin to gypsum, spærstān, spear stone, referring to its crystalline projections).
In 1852, fluorite gave its name to the phenomenon of fluorescence, which is prominent in fluorites from certain locations, due to certain impurities in the crystal. Fluorite also gave the name to its constitutive element fluorine. Currently, the word "fluorspar" is most commonly used for fluorite as an industrial and chemical commodity, while "fluorite" is used mineralogically and in most other senses.
In archeology, gemmology, classical studies, and Egyptology, the Latin terms murrina and myrrhina refer to fluorite. In book 37 of his Naturalis Historia, Pliny the Elder describes it as a precious stone with purple and white mottling, and noted that the Romans prized objects carved from it. It has been suggested that the Sanskrit mineral name vaikrānta (वैक्रान्तः), known from Sanskrit alchemical texts dating from the early second millennium CE onwards, may refer to fluorite.
Fluorite crystallizes in a cubic motif. Crystal twinning is common and adds complexity to the observed crystal habits. Fluorite has four perfect cleavage planes that help produce octahedral fragments. The structural motif adopted by fluorite is so common that the motif is called the fluorite structure. Element substitution for the calcium cation often includes strontium and certain rare-earth elements (REE), such as yttrium and cerium.
Fluorite forms as a late-crystallizing mineral in felsic igneous rocks typically through hydrothermal activity. It is particularly common in granitic pegmatites. It may occur as a vein deposit formed through hydrothermal activity particularly in limestones. In such vein deposits it can be associated with galena, sphalerite, barite, quartz, and calcite. Fluorite can also be found as a constituent of sedimentary rocks either as grains or as the cementing material in sandstone.