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Hydrophobic soil
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Hydrophobic soil
Hydrophobic soil is a soil whose particles repel water. The layer of hydrophobicity is commonly found at or a few centimeters below the surface, parallel to the soil profile. This layer can vary in thickness and abundance and is typically covered by a layer of ash or burned soil.
Hydrophobic soil is most familiarly formed when a fire or hot air disperses waxy compounds found in the uppermost litter layer consisting of organic matter. After the compounds disperse, they mainly coat sandy soil particles near the surface in the upper layers of soil, making the soil hydrophobic. Other producers of hydrophobic coatings are contamination and industrial spillages along with soil microbial activity. Hydrophobicity can also be seen as a natural soil property that results from the degradation of natural vegetation such as Eucalyptus that has natural wax properties.
It was found that in a particular New Zealand sand, this waxy lipid coating consisted of primarily hydrocarbons and triglycerides that were basic in pH along with a lesser value of acidic long-chain fatty acids. Capillary penetration amongst soil particles is limited by the hydrophobic coating on the particles, resulting in water repellence in each particle affected as the hydrophilic head of the lipid attaches itself to the sand particle leaving the hydrophobic tail shielding the outside of the particle. This can be seen in Figure 1 below.
Other important soil water averting factors have been found to include soil texture, microbiology, soil surface roughness, soil organic matter content, soil chemical composition, acidity, soil water content, soil type, mineralogy of clay particles, and seasonal variations of the region. Soil texture plays a large role in predicting whether a soil could be water repelling as larger grained particles in the soil such as sand have smaller surface areas, making them more prone to being fully coated by hydrophobic compounds. It is much more difficult to entirely coat a silt or clay particle with more surface area, but when it does happen, the resulting water repellency of the soil is severe. As soil organic matter in the form of plant or microbial biomass decomposes, physiochemical changes can release these hydrophobic compounds into the soil as well. This, however, depends on the type of microbial activity present in the soil as it can also hinder the development of hydrophobic compounds.
Soil water repellence is almost always tested with the water droplet penetration time (WDPT) test first because of the simplicity of the test. This test is executed by recording the time it takes for one droplet of water to infiltrate a specific soil, indicating the stability of repellency. Water infiltration is expressed as water entering the soil in a spontaneous fashion and correlates with the angle of the water-soil contact. If the water-soil contact angle is greater than 90º, then the soil is determined to be hydrophobic. It has also been observed that if the test droplet is placed on hydrophobic soil, it will rapidly develop a particulate skin before disappearing.
Results of the WDPT:
Table 1: Characterizing the degree of hydrophobicity in soils based on the water droplet penetration test.
Another method for determining soil water repellency is the molarity of ethanol droplet (MED) test. The MED test uses solutions of ethanol of varying surface tensions to observe soil wetting within a time frame of 10 seconds. If there is no wetting within the specified timeframe, an aqueous solution of ethanol with lower surface tension is then placed on a different area of the sample. The results of the MED test depend on the molarity of the ethanol solution whose droplets were absorbed in the allotted 10 seconds. Classifying soil water repellency from this test can be done by using a MED index where a non-water repellent soil has an index of less than or equal to 1 and a severely water repellent soil has an index of greater than or equal to 2.2. The MED index, 90º surface tension, ethanol molarity, and volume percentage correlate and can be converted into one another. In this test, the liquid-air surface tension value of the ethanol solution that is absorbed within this timeframe is used as the ninety-degree surface tension of the soil. The water entry pressure associated with the tested soil is another indicator of infiltration rates as it is associated with the degree of water repellency along with soil pore size.
Hub AI
Hydrophobic soil AI simulator
(@Hydrophobic soil_simulator)
Hydrophobic soil
Hydrophobic soil is a soil whose particles repel water. The layer of hydrophobicity is commonly found at or a few centimeters below the surface, parallel to the soil profile. This layer can vary in thickness and abundance and is typically covered by a layer of ash or burned soil.
Hydrophobic soil is most familiarly formed when a fire or hot air disperses waxy compounds found in the uppermost litter layer consisting of organic matter. After the compounds disperse, they mainly coat sandy soil particles near the surface in the upper layers of soil, making the soil hydrophobic. Other producers of hydrophobic coatings are contamination and industrial spillages along with soil microbial activity. Hydrophobicity can also be seen as a natural soil property that results from the degradation of natural vegetation such as Eucalyptus that has natural wax properties.
It was found that in a particular New Zealand sand, this waxy lipid coating consisted of primarily hydrocarbons and triglycerides that were basic in pH along with a lesser value of acidic long-chain fatty acids. Capillary penetration amongst soil particles is limited by the hydrophobic coating on the particles, resulting in water repellence in each particle affected as the hydrophilic head of the lipid attaches itself to the sand particle leaving the hydrophobic tail shielding the outside of the particle. This can be seen in Figure 1 below.
Other important soil water averting factors have been found to include soil texture, microbiology, soil surface roughness, soil organic matter content, soil chemical composition, acidity, soil water content, soil type, mineralogy of clay particles, and seasonal variations of the region. Soil texture plays a large role in predicting whether a soil could be water repelling as larger grained particles in the soil such as sand have smaller surface areas, making them more prone to being fully coated by hydrophobic compounds. It is much more difficult to entirely coat a silt or clay particle with more surface area, but when it does happen, the resulting water repellency of the soil is severe. As soil organic matter in the form of plant or microbial biomass decomposes, physiochemical changes can release these hydrophobic compounds into the soil as well. This, however, depends on the type of microbial activity present in the soil as it can also hinder the development of hydrophobic compounds.
Soil water repellence is almost always tested with the water droplet penetration time (WDPT) test first because of the simplicity of the test. This test is executed by recording the time it takes for one droplet of water to infiltrate a specific soil, indicating the stability of repellency. Water infiltration is expressed as water entering the soil in a spontaneous fashion and correlates with the angle of the water-soil contact. If the water-soil contact angle is greater than 90º, then the soil is determined to be hydrophobic. It has also been observed that if the test droplet is placed on hydrophobic soil, it will rapidly develop a particulate skin before disappearing.
Results of the WDPT:
Table 1: Characterizing the degree of hydrophobicity in soils based on the water droplet penetration test.
Another method for determining soil water repellency is the molarity of ethanol droplet (MED) test. The MED test uses solutions of ethanol of varying surface tensions to observe soil wetting within a time frame of 10 seconds. If there is no wetting within the specified timeframe, an aqueous solution of ethanol with lower surface tension is then placed on a different area of the sample. The results of the MED test depend on the molarity of the ethanol solution whose droplets were absorbed in the allotted 10 seconds. Classifying soil water repellency from this test can be done by using a MED index where a non-water repellent soil has an index of less than or equal to 1 and a severely water repellent soil has an index of greater than or equal to 2.2. The MED index, 90º surface tension, ethanol molarity, and volume percentage correlate and can be converted into one another. In this test, the liquid-air surface tension value of the ethanol solution that is absorbed within this timeframe is used as the ninety-degree surface tension of the soil. The water entry pressure associated with the tested soil is another indicator of infiltration rates as it is associated with the degree of water repellency along with soil pore size.