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Methacrylic acid
Methacrylic acid, abbreviated MAA, is an organic compound with the formula CH2=C(CH3)CO2H. This colorless, viscous liquid is a carboxylic acid with an acrid unpleasant odor. It is soluble in warm water and miscible with most organic solvents. Methacrylic acid is produced industrially on a large scale as a precursor to its esters, especially methyl methacrylate (MMA), and to poly(methyl methacrylate) (PMMA).
In the most common route, methacrylic acid is prepared from acetone cyanohydrin, which is converted to methacrylamide sulfate using sulfuric acid. This derivative in turn is hydrolyzed to methacrylic acid, or esterified to methyl methacrylate in one step. Another route to methacrylic acid starts with isobutylene, which obtainable by dehydration of tert-butanol. Isobutylene is oxidized sequentially to methacrolein and then methacrylic acid. Methacrolein for this purpose can also be obtained from formaldehyde and ethylene. Yet a third route involves the dehydrogenation of Isobutyric acid.
Various green routes have been explored but they have not been commercialized. Specifically, the decarboxylation of itaconic acid, citraconic acid, and mesaconic acids affords methacrylic acid. Salts of methacrylic acid have been obtained by boiling citra- or meso-brompyrotartaric acids with alkalis.[citation needed]
Pyrolysis of ethyl methacrylate efficiently gives methacrylic acid.
The main use of methacrylic acid is its polymerization to poly(methyl methacrylate).
It is used in some nail primers to help acrylic nails adhere to the nail plate.
Copolymers consisting partially of methacrylic acid are used in certain types of tablet coatings in order to slow the tablet's dissolution in the digestive tract, and thus extend or delay the release of the active ingredient.
Monocarboxylic unsaturated acids such as methacrylic acid and acrylic acid are used in the production of vinyl ester resins.
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Methacrylic acid
Methacrylic acid, abbreviated MAA, is an organic compound with the formula CH2=C(CH3)CO2H. This colorless, viscous liquid is a carboxylic acid with an acrid unpleasant odor. It is soluble in warm water and miscible with most organic solvents. Methacrylic acid is produced industrially on a large scale as a precursor to its esters, especially methyl methacrylate (MMA), and to poly(methyl methacrylate) (PMMA).
In the most common route, methacrylic acid is prepared from acetone cyanohydrin, which is converted to methacrylamide sulfate using sulfuric acid. This derivative in turn is hydrolyzed to methacrylic acid, or esterified to methyl methacrylate in one step. Another route to methacrylic acid starts with isobutylene, which obtainable by dehydration of tert-butanol. Isobutylene is oxidized sequentially to methacrolein and then methacrylic acid. Methacrolein for this purpose can also be obtained from formaldehyde and ethylene. Yet a third route involves the dehydrogenation of Isobutyric acid.
Various green routes have been explored but they have not been commercialized. Specifically, the decarboxylation of itaconic acid, citraconic acid, and mesaconic acids affords methacrylic acid. Salts of methacrylic acid have been obtained by boiling citra- or meso-brompyrotartaric acids with alkalis.[citation needed]
Pyrolysis of ethyl methacrylate efficiently gives methacrylic acid.
The main use of methacrylic acid is its polymerization to poly(methyl methacrylate).
It is used in some nail primers to help acrylic nails adhere to the nail plate.
Copolymers consisting partially of methacrylic acid are used in certain types of tablet coatings in order to slow the tablet's dissolution in the digestive tract, and thus extend or delay the release of the active ingredient.
Monocarboxylic unsaturated acids such as methacrylic acid and acrylic acid are used in the production of vinyl ester resins.