Methyl vinyl ether is an organic compound with the chemical formula CH₃OCH=CH₂. A colorless gas, it is the simplest enol ether. It is used as a synthetic building block, as is the related compound ethyl vinyl ether (a liquid at room temperature).

Methyl vinyl ether can be made by reaction of acetylene and methanol in presence of a base.

The alkene portion of the molecule is reactive in many ways. It is prone to polymerization, leading to formation of polyvinyl ethers. Polymerization is typically initiated with Lewis acids such as boron trifluoride. This mode of reactivity is analogous to the way vinyl acetate and vinyl chloride can be polymerized to form polyvinyl acetate and polyvinyl chloride, respectively.

Methyl vinyl ether also participates in [4+2] cycloaddition reactions. Its reaction with acrolein is the first step in the commercial synthesis of glutaraldehyde.

The alkene can be deprotonated at the vinyl carbon adjacent to the oxygen. In particular, this approach allows the synthesis of a variety of acyl derivatives of silicon, germanium, and tin that cannot be made easily by other routes.

The toxicity of vinyl ethers has been heavily investigated because divinyl ether has been used as an anesthetic. The acute LD₅₀ for methyl vinyl ether is greater than 4 g/kg (rats, oral).