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Miyaura borylation
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Miyaura borylation
Miyaura borylation, also known as the Miyaura borylation reaction, is a named reaction in organic chemistry that allows for the generation of boronates from vinyl or aryl halides with the cross-coupling of bis(pinacolato)diboron in basic conditions with a catalyst such as PdCl2(dppf). The resulting borylated products can be used as coupling partners for the Suzuki reaction.
The Miyaura borylation has shown to work for:
Alkyl halides, aryl halides, aryl halides using tetrahydroxydiboron, aryl halides using bis-boronic acid, aryl triflates, aryl mesylates, vinyl halides, vinyl halides of α,β-unsaturated carbonyl compounds, and vinyl triflates.
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Miyaura borylation
Miyaura borylation, also known as the Miyaura borylation reaction, is a named reaction in organic chemistry that allows for the generation of boronates from vinyl or aryl halides with the cross-coupling of bis(pinacolato)diboron in basic conditions with a catalyst such as PdCl2(dppf). The resulting borylated products can be used as coupling partners for the Suzuki reaction.
The Miyaura borylation has shown to work for:
Alkyl halides, aryl halides, aryl halides using tetrahydroxydiboron, aryl halides using bis-boronic acid, aryl triflates, aryl mesylates, vinyl halides, vinyl halides of α,β-unsaturated carbonyl compounds, and vinyl triflates.