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Osmotic power

Osmotic power, salinity gradient power or blue energy is the energy available from the difference in the salt concentration between seawater and river water. Two practical methods for this are reverse electrodialysis (RED) and pressure retarded osmosis (PRO). Both processes rely on osmosis with membranes. The key waste product is brackish water. This byproduct is the result of natural forces that are being harnessed: the flow of fresh water into seas that are made up of salt water.

In 1954, Pattle suggested that there was an untapped source of power when a river mixes with the sea, in terms of the lost osmotic pressure, however it was not until the mid 1970s when a practical method of harnessing it using selectively permeable membranes by Loeb was outlined.

The method of generating power by pressure retarded osmosis was invented by Sidney Loeb in 1973 at the Ben-Gurion University of the Negev, Beersheba, Israel. The idea came to Loeb, in part, as he observed the Jordan River flowing into the Dead Sea. He wanted to harvest the energy of mixing of the two aqueous solutions (the Jordan River being one and the Dead Sea being the other) that was going to waste in this natural mixing process. In 1977, Loeb invented a method of producing power by a reverse electrodialysis heat engine.

The technologies have been confirmed in laboratory conditions. They are being developed for commercial use in the Netherlands (RED) and Norway (PRO). The cost of the membrane has been an obstacle. A new, lower cost membrane, based on an electrically modified polyethylene plastic, made it fit for potential commercial use. Other methods have been proposed and are currently under development. Among them are a method based on electric double-layer capacitor technology and a method based on vapor pressure difference.

Salinity gradient power is a specific renewable energy alternative that creates renewable and sustainable power by using naturally occurring processes. This practice does not contaminate or release carbon dioxide (CO2) emissions (vapor pressure methods will release dissolved air containing CO2 at low pressures—these non-condensable gases can be re-dissolved of course, but with an energy penalty). Also as stated by Jones and Finley within their article "Recent Development in Salinity Gradient Power", there is basically no fuel cost.

Salinity gradient energy is based on using the resources of "osmotic pressure difference between fresh water and sea water." All energy that is proposed to use salinity gradient technology relies on the evaporation to separate water from salt. Osmotic pressure is the "chemical potential of concentrated and dilute solutions of salt". When looking at relations between high osmotic pressure and low, solutions with higher concentrations of salt have higher pressure.

Differing salinity gradient power generations exist but one of the most commonly discussed is pressure-retarded osmosis (PRO). Within PRO seawater is pumped into a pressure chamber where the pressure is lower than the difference between fresh and salt water pressure. Fresh water moves in a semipermeable membrane and increases its volume in the chamber. As the pressure in the chamber is compensated a turbine spins to generate electricity. In Braun's article he states that this process is easy to understand in a more broken down manner. Two solutions, A being salt water and B being fresh water are separated by a membrane. He states "only water molecules can pass the semipermeable membrane. As a result of the osmotic pressure difference between both solutions, the water from solution B thus will diffuse through the membrane in order to dilute solution A". The pressure drives the turbines and power the generator that produces the electrical energy. Osmosis might be used directly to "pump" fresh water out of The Netherlands into the sea. This is currently done using electric pumps.

A 2012 study on efficiency from Yale University concluded that the highest extractable work in constant-pressure PRO with a seawater draw solution and river water feed solution is 0.75 kWh/m3 (2.7 kJ/L) while the free energy of mixing is 0.81 kWh/m3 (2.9 kJ/L) — a thermodynamic extraction efficiency of 91.0%.

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energy available from the difference in the salt concentration between seawater and river water
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