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Tantalum
Tantalum is a chemical element; it has symbol Ta and atomic number 73. It is named after Tantalus, a figure in Greek mythology. Tantalum is a very hard, ductile, lustrous, blue-gray transition metal that is highly corrosion-resistant. It is part of the refractory metals group, which are widely used as components of strong high-melting-point alloys. It is a group 5 element, along with vanadium and niobium, and it always occurs in geologic sources together with the chemically similar niobium, mainly in the mineral groups tantalite, columbite, and coltan.
The chemical inertness and very high melting point of tantalum make it valuable for laboratory and industrial equipment such as reaction vessels and vacuum furnaces. It is used in tantalum capacitors for electronic equipment such as computers. It is being investigated for use as a material for high-quality superconducting resonators in quantum processors.
Tantalum was discovered in Sweden in 1802 by Anders Ekeberg, in two mineral samples – one from Sweden and the other from Finland. One year earlier, Charles Hatchett had discovered columbium (now niobium). In 1809, the English chemist William Hyde Wollaston compared the oxides of columbium and tantalum, columbite and tantalite. Although the two oxides had different measured densities of 5.918 g/cm3 and 7.935 g/cm3, he concluded that they were identical and kept the name tantalum. After Friedrich Wöhler confirmed these results, it was thought that columbium and tantalum were the same element. This conclusion was disputed in 1846 by the German chemist Heinrich Rose, who argued that there were two additional elements in the tantalite sample, and he named them after the children of Tantalus: niobium (from Niobe), and pelopium (from Pelops). The supposed element "pelopium" was later identified as a mixture of tantalum and niobium, and it was found that the niobium was identical to the columbium already discovered in 1801 by Hatchett.
The differences between tantalum and niobium were demonstrated unequivocally in 1864 by Christian Wilhelm Blomstrand, and Henri Etienne Sainte-Claire Deville, as well as by Louis J. Troost, who determined the empirical formulas of some of their compounds in 1865. Further confirmation came from the Swiss chemist Jean Charles Galissard de Marignac, in 1866, who proved that there were only two elements. These discoveries did not stop scientists from publishing articles about the so-called ilmenium until 1871. De Marignac was the first to produce the metallic form of tantalum in 1864, when he reduced tantalum chloride by heating it in an atmosphere of hydrogen. Early investigators had only been able to produce impure tantalum, and the first relatively pure ductile metal was produced by Werner von Bolton in Charlottenburg in 1903. Wires made with metallic tantalum were used for light bulb filaments until tungsten replaced it in widespread use.
The name tantalum was derived from the name of the mythological Tantalus, the father of Niobe in Greek mythology. In the story, he had been punished after death by being condemned to stand knee-deep in water with perfect fruit growing above his head, both of which eternally tantalized him. (If he bent to drink the water, it drained below the level he could reach, and if he reached for the fruit, the branches moved out of his grasp.) Anders Ekeberg wrote "This metal I call tantalum ... partly in allusion to its incapacity, when immersed in acid, to absorb any and be saturated."
For decades, the commercial technology for separating tantalum from niobium involved the fractional crystallization of potassium heptafluorotantalate away from potassium oxypentafluoroniobate monohydrate, a process that was discovered by Jean Charles Galissard de Marignac in 1866. This method has been supplanted by solvent extraction from fluoride-containing solutions of tantalum.
Tantalum is dark (blue-gray), dense, ductile, very hard, easily fabricated, and highly conductive of heat and electricity. The metal is highly resistant to corrosion by acids: at temperatures below 150 °C tantalum is almost completely immune to attack by the normally aggressive aqua regia. It can be dissolved with hydrofluoric acid or acidic solutions containing the fluoride ion and sulfur trioxide, as well as with molten potassium hydroxide. Tantalum's high melting point of 3017 °C (boiling point 5458 °C) is exceeded among the elements only by tungsten, rhenium, and osmium for metals, and carbon.
Tantalum exists in two crystalline phases, alpha and beta. The alpha phase is stable at all temperatures up to the melting point and has body-centered cubic structure with lattice constant a = 0.33029 nm at 20 °C. It is relatively ductile, has Knoop hardness 200–400 HN and electrical resistivity 15–60 μΩ⋅cm. The beta phase is hard and brittle; its crystal symmetry is tetragonal (space group P42/mnm, a = 1.0194 nm, c = 0.5313 nm), Knoop hardness is 1000–1300 HN and electrical resistivity is relatively high at 170–210 μΩ⋅cm. The beta phase is metastable and converts to the alpha phase upon heating to 750–775 °C. Bulk tantalum is almost entirely alpha phase, and the beta phase usually exists as thin films obtained by magnetron sputtering, chemical vapor deposition or electrochemical deposition from a eutectic molten salt solution.
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Tantalum
Tantalum is a chemical element; it has symbol Ta and atomic number 73. It is named after Tantalus, a figure in Greek mythology. Tantalum is a very hard, ductile, lustrous, blue-gray transition metal that is highly corrosion-resistant. It is part of the refractory metals group, which are widely used as components of strong high-melting-point alloys. It is a group 5 element, along with vanadium and niobium, and it always occurs in geologic sources together with the chemically similar niobium, mainly in the mineral groups tantalite, columbite, and coltan.
The chemical inertness and very high melting point of tantalum make it valuable for laboratory and industrial equipment such as reaction vessels and vacuum furnaces. It is used in tantalum capacitors for electronic equipment such as computers. It is being investigated for use as a material for high-quality superconducting resonators in quantum processors.
Tantalum was discovered in Sweden in 1802 by Anders Ekeberg, in two mineral samples – one from Sweden and the other from Finland. One year earlier, Charles Hatchett had discovered columbium (now niobium). In 1809, the English chemist William Hyde Wollaston compared the oxides of columbium and tantalum, columbite and tantalite. Although the two oxides had different measured densities of 5.918 g/cm3 and 7.935 g/cm3, he concluded that they were identical and kept the name tantalum. After Friedrich Wöhler confirmed these results, it was thought that columbium and tantalum were the same element. This conclusion was disputed in 1846 by the German chemist Heinrich Rose, who argued that there were two additional elements in the tantalite sample, and he named them after the children of Tantalus: niobium (from Niobe), and pelopium (from Pelops). The supposed element "pelopium" was later identified as a mixture of tantalum and niobium, and it was found that the niobium was identical to the columbium already discovered in 1801 by Hatchett.
The differences between tantalum and niobium were demonstrated unequivocally in 1864 by Christian Wilhelm Blomstrand, and Henri Etienne Sainte-Claire Deville, as well as by Louis J. Troost, who determined the empirical formulas of some of their compounds in 1865. Further confirmation came from the Swiss chemist Jean Charles Galissard de Marignac, in 1866, who proved that there were only two elements. These discoveries did not stop scientists from publishing articles about the so-called ilmenium until 1871. De Marignac was the first to produce the metallic form of tantalum in 1864, when he reduced tantalum chloride by heating it in an atmosphere of hydrogen. Early investigators had only been able to produce impure tantalum, and the first relatively pure ductile metal was produced by Werner von Bolton in Charlottenburg in 1903. Wires made with metallic tantalum were used for light bulb filaments until tungsten replaced it in widespread use.
The name tantalum was derived from the name of the mythological Tantalus, the father of Niobe in Greek mythology. In the story, he had been punished after death by being condemned to stand knee-deep in water with perfect fruit growing above his head, both of which eternally tantalized him. (If he bent to drink the water, it drained below the level he could reach, and if he reached for the fruit, the branches moved out of his grasp.) Anders Ekeberg wrote "This metal I call tantalum ... partly in allusion to its incapacity, when immersed in acid, to absorb any and be saturated."
For decades, the commercial technology for separating tantalum from niobium involved the fractional crystallization of potassium heptafluorotantalate away from potassium oxypentafluoroniobate monohydrate, a process that was discovered by Jean Charles Galissard de Marignac in 1866. This method has been supplanted by solvent extraction from fluoride-containing solutions of tantalum.
Tantalum is dark (blue-gray), dense, ductile, very hard, easily fabricated, and highly conductive of heat and electricity. The metal is highly resistant to corrosion by acids: at temperatures below 150 °C tantalum is almost completely immune to attack by the normally aggressive aqua regia. It can be dissolved with hydrofluoric acid or acidic solutions containing the fluoride ion and sulfur trioxide, as well as with molten potassium hydroxide. Tantalum's high melting point of 3017 °C (boiling point 5458 °C) is exceeded among the elements only by tungsten, rhenium, and osmium for metals, and carbon.
Tantalum exists in two crystalline phases, alpha and beta. The alpha phase is stable at all temperatures up to the melting point and has body-centered cubic structure with lattice constant a = 0.33029 nm at 20 °C. It is relatively ductile, has Knoop hardness 200–400 HN and electrical resistivity 15–60 μΩ⋅cm. The beta phase is hard and brittle; its crystal symmetry is tetragonal (space group P42/mnm, a = 1.0194 nm, c = 0.5313 nm), Knoop hardness is 1000–1300 HN and electrical resistivity is relatively high at 170–210 μΩ⋅cm. The beta phase is metastable and converts to the alpha phase upon heating to 750–775 °C. Bulk tantalum is almost entirely alpha phase, and the beta phase usually exists as thin films obtained by magnetron sputtering, chemical vapor deposition or electrochemical deposition from a eutectic molten salt solution.