Following his retirement, Volta lived a quiet life at his estate in Camnago near Como. He continued to follow scientific developments and enjoyed spending time with his family. While his active research days were largely over, he remained a respected figure in the scientific world.

Alessandro Volta died on March 5, 1827, in Como, Italy, at the age of 82. The cause of death was likely related to his advanced age. He was buried in Como, leaving behind a legacy as one of the most important scientists in history.