Atmosphere of the Moon

The atmosphere of the Moon is a very sparse layer of gases surrounding the Moon, consisting only of an exosphere. For most practical purposes, the Moon is considered to be surrounded by vacuum. The elevated presence of atomic and molecular particles in its vicinity compared to interplanetary medium, referred to as "lunar atmosphere" for scientific objectives, is negligible in comparison with the gaseous envelopes surrounding Earth and most planets of the Solar System, and comparable to their exospheres. The pressure of this small mass is around 3×10⁻¹⁵ atm (0.3 nPa), varying throughout the day, and has a total mass of less than 10 metric tonnes. Otherwise, the Moon is considered not to have an atmosphere because it cannot absorb measurable quantities of radiation, does not appear layered or self-circulating, and requires constant replenishment due to the high rate at which its gases are lost into space.

Roger Joseph Boscovich was the first modern astronomer to argue for the lack of atmosphere around the Moon in his De lunae atmosphaera (1753).

One source of the lunar atmosphere is outgassing: the release of gases such as radon and helium resulting from radioactive decay within the crust and mantle. Another important source is the bombardment of the lunar surface by micrometeorites, the solar wind, and sunlight, in a process known as sputtering.

Gases can:

What little atmosphere the Moon has consists of some unusual gases, including sodium and potassium, which are not found in the atmospheres of Earth, Mars, or Venus. At sea level on Earth, each cubic centimeter of the atmosphere contains approximately 10¹⁹ molecules; by comparison the lunar atmosphere contains fewer than 10⁶ molecules in the same volume. On Earth, this is considered to be a very good vacuum. In fact, the density of the atmosphere at the Moon's surface is comparable to the density of some of the outermost fringes of Earth's atmosphere, where the International Space Station orbits.

The elements sodium and potassium have been detected in the Moon's atmosphere using Earth-based spectroscopic methods, whereas the isotopes radon-222 and polonium-210 have been inferred from data obtained by the Lunar Prospector alpha particle spectrometer. Argon-40, helium-4, oxygen and/or methane (CH₄), nitrogen (N₂) and/or carbon monoxide (CO), and carbon dioxide (CO₂)) were detected by in-situ detectors placed by the Apollo astronauts.

The average daytime abundances of the elements known to be present in the lunar atmosphere, in atoms per cubic centimeter, are as follows:

This yields approximately 80,000 total atoms per cubic centimeter, marginally higher than the quantity posited to exist in the atmosphere of Mercury. While this greatly exceeds the density of the solar wind, which is usually on the order of just a few protons per cubic centimeter, it is virtually a vacuum in comparison with the atmosphere of the Earth.