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Salinity

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Salinity

Salinity (/səˈlɪnɪti/) is the saltiness or amount of salt dissolved in a body of water, called saline water (see also soil salinity). It is usually measured in g/L or g/kg (grams of salt per liter/kilogram of water; the latter is dimensionless and equal to ).

Salinity is an important factor in determining many aspects of the chemistry of natural waters and of biological processes within it, and is a thermodynamic state variable that, along with temperature and pressure, governs physical characteristics like the density and heat capacity of the water. These in turn are important for understanding ocean currents and heat exchange with the atmosphere.

A contour line of constant salinity is called an isohaline, or sometimes isohale.

Salinity in rivers, lakes, and the ocean is conceptually simple, but technically challenging to define and measure precisely. Conceptually the salinity is the quantity of dissolved salt content of the water. Salts are compounds like sodium chloride, magnesium sulfate, potassium nitrate, and sodium bicarbonate which dissolve into ions. The concentration of dissolved chloride ions is sometimes referred to as chlorinity. Operationally, dissolved matter is defined as that which can pass through a very fine filter (historically a filter with a pore size of 0.45 μm, but later[when?] usually 0.2 μm). Salinity can be expressed in the form of a mass fraction, i.e. the mass of the dissolved material in a unit mass of solution.

Seawater typically has a mass salinity of around 35 g/kg, although lower values are typical near coasts where rivers enter the ocean. Rivers and lakes can have a wide range of salinities, from less than 0.01 g/kg to a few g/kg, although there are many places where higher salinities are found. The Dead Sea has a salinity of more than 200 g/kg. Precipitation typically has a TDS of 20 mg/kg or less.

Whatever pore size is used in the definition, the resulting salinity value of a given sample of natural water will not vary by more than a few percent (%). Physical oceanographers working in the abyssal ocean, however, are often concerned with precision and intercomparability of measurements by different researchers, at different times, to almost five significant digits. A bottled seawater product known as IAPSO Standard Seawater is used by oceanographers to standardize their measurements with enough precision to meet this requirement.

Measurement and definition difficulties arise because natural waters contain a complex mixture of many different elements from different sources (not all from dissolved salts) in different molecular forms. The chemical properties of some of these forms depend on temperature and pressure. Many of these forms are difficult to measure with high accuracy, and in any case complete chemical analysis is not practical when analyzing multiple samples. Different practical definitions of salinity result from different attempts to account for these problems, to different levels of precision, while still remaining reasonably easy to use.

For practical reasons salinity is usually related to the sum of masses of a subset of these dissolved chemical constituents (so-called solution salinity), rather than to the unknown mass of salts that gave rise to this composition (an exception is when artificial seawater is created). For many purposes this sum can be limited to a set of eight major ions in natural waters, although for seawater at highest precision an additional seven minor ions are also included. The major ions dominate the inorganic composition of most (but by no means all) natural waters. Exceptions include some pit lakes and waters from some hydrothermal springs.

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