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Spectral line

A spectral line is a weaker or stronger region in an otherwise uniform and continuous spectrum. It may result from emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to identify atoms and molecules. These "fingerprints" can be compared to the previously collected ones of atoms and molecules, and are thus used to identify the atomic and molecular components of stars and planets, which would otherwise be impossible.

Spectral lines are the result of interaction between a quantum system (usually atoms, but sometimes molecules or atomic nuclei) and a single photon. When a photon has about the right amount of energy (which is connected to its frequency) to allow a change in the energy state of the system (in the case of an atom this is usually an electron changing orbitals), the photon is absorbed. Then the energy will be spontaneously re-emitted, either as one photon at the same frequency as the original one or in a cascade, where the sum of the energies of the photons emitted will be equal to the energy of the one absorbed (assuming the system returns to its original state).

A spectral line may be observed either as an emission line or an absorption line. Which type of line is observed depends on the type of material and its temperature relative to another emission source. An absorption line is produced when photons from a hot, broad spectrum source pass through a cooler material. The intensity of light, over a narrow frequency range, is reduced due to absorption by the material and re-emission in random directions. By contrast, a bright emission line is produced when photons from a hot material are detected, perhaps in the presence of a broad spectrum from a cooler source. The intensity of light, over a narrow frequency range, is increased due to emission by the hot material.

Spectral lines are highly atom-specific, and can be used to identify the chemical composition of any medium. Several elements, including helium, thallium, and caesium, were discovered by spectroscopic means. Spectral lines also depend on the temperature and density of the material, so they are widely used to determine the physical composition and condition of distant stars and other celestial bodies. Some of these data cannot be obtained or analyzed by other means, and so the field of spectroscopy has grown as astronomical and telescopic exploration has grown.

Depending on the material and its physical conditions, the energy of the involved photons can vary widely, with the spectral lines observed across the electromagnetic spectrum, from radio waves to gamma rays.

Strong spectral lines in the visible part of the electromagnetic spectrum often have a unique Fraunhofer line designation, such as K for a line at 393.366 nm emerging from singly-ionized calcium atom, Ca+, though some of the Fraunhofer "lines" are blends of multiple lines from several different species.

In other cases, the lines are designated according to the level of ionization by adding a Roman numeral to the designation of the chemical element. Neutral atoms are denoted with the Roman numeral I, singly ionized atoms with II, and so on, so that, for example:

Cu II — copper ion with +1 charge, Cu1+

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