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Hub AI
Hypophosphorous acid AI simulator
(@Hypophosphorous acid_simulator)
Hub AI
Hypophosphorous acid AI simulator
(@Hypophosphorous acid_simulator)
Hypophosphorous acid
Hypophosphorous acid (HPA), or phosphinic acid, is a phosphorus oxyacid and a powerful reducing agent with molecular formula H3PO2. It is a colorless low-melting compound, which is soluble in water, dioxane and alcohols. The formula for this acid is generally written H3PO2, but a more descriptive presentation is HOP(O)H2, which highlights its monoprotic character. Salts derived from this acid are called hypophosphites.
HOP(O)H2 exists in equilibrium with the minor tautomer HP(OH)2. Sometimes the minor tautomer is called hypophosphorous acid and the major tautomer is called phosphinic acid.
Hypophosphorous acid was first prepared in 1816 by the French chemist Pierre Louis Dulong (1785–1838).
The acid is prepared industrially via a two step process: Firstly, elemental white phosphorus reacts with alkali and alkaline earth hydroxides to give an aqueous solution of hypophosphites:
Any phosphites produced in this step can be selectively precipitated out by treatment with calcium salts. The purified material is then treated with a strong, non-oxidizing acid (often sulfuric acid) to give the free hypophosphorous acid:
HPA is usually supplied as a 50% aqueous solution. Anhydrous acid cannot be obtained by simple evaporation of the water, as the acid readily oxidises to phosphorous acid and phosphoric acid and also disproportionates to phosphorous acid and phosphine. Pure anhydrous hypophosphorous acid can be formed by the continuous extraction of aqueous solutions with diethyl ether.
The molecule displays P(═O)H to P–OH tautomerism similar to that of phosphorous acid; the P(═O) form is strongly favoured.
HPA is usually supplied as a 50% aqueous solution and heating at low temperatures (up to about 90 °C) prompts it to react with water to form phosphorous acid and hydrogen gas.
Hypophosphorous acid
Hypophosphorous acid (HPA), or phosphinic acid, is a phosphorus oxyacid and a powerful reducing agent with molecular formula H3PO2. It is a colorless low-melting compound, which is soluble in water, dioxane and alcohols. The formula for this acid is generally written H3PO2, but a more descriptive presentation is HOP(O)H2, which highlights its monoprotic character. Salts derived from this acid are called hypophosphites.
HOP(O)H2 exists in equilibrium with the minor tautomer HP(OH)2. Sometimes the minor tautomer is called hypophosphorous acid and the major tautomer is called phosphinic acid.
Hypophosphorous acid was first prepared in 1816 by the French chemist Pierre Louis Dulong (1785–1838).
The acid is prepared industrially via a two step process: Firstly, elemental white phosphorus reacts with alkali and alkaline earth hydroxides to give an aqueous solution of hypophosphites:
Any phosphites produced in this step can be selectively precipitated out by treatment with calcium salts. The purified material is then treated with a strong, non-oxidizing acid (often sulfuric acid) to give the free hypophosphorous acid:
HPA is usually supplied as a 50% aqueous solution. Anhydrous acid cannot be obtained by simple evaporation of the water, as the acid readily oxidises to phosphorous acid and phosphoric acid and also disproportionates to phosphorous acid and phosphine. Pure anhydrous hypophosphorous acid can be formed by the continuous extraction of aqueous solutions with diethyl ether.
The molecule displays P(═O)H to P–OH tautomerism similar to that of phosphorous acid; the P(═O) form is strongly favoured.
HPA is usually supplied as a 50% aqueous solution and heating at low temperatures (up to about 90 °C) prompts it to react with water to form phosphorous acid and hydrogen gas.