The Rhenohercynian Zone or Rheno-Hercynian zone in structural geology describes a fold belt of west and central Europe, formed during the Hercynian orogeny (about 350 to 280 million years ago). The zone consists of folded and thrust Devonian and early Carboniferous sedimentary rocks that were deposited in a back-arc basin along the southern margin of the then existing paleocontinent Laurussia.

The Rhenohercynian Zone, named for the Rhine River and the Hercynian Forest of Antiquity, forms a narrow zone through western and central Europe, from Cornwall and Ireland in the west to the Harz mountains of central Germany in the east, including the Rhenish Massif (Ardennes, Taunus, Eifel and Hunsrück). The total length of this ancient basin (the Rhenohercynian Basin) could have been more than 2500 km. In the east the basin merges with the East-Silesian basin of southern Poland. The sedimentary rocks that were laid down in the basin are often weakly metamorphic (greenschist facies). Most geologists consider the South-Portuguese zone to be a continuation of the zone to the west.

Whether the Rhenohercynian Basin was a continuous feature or rather a string of temporaneously interconnected smaller basins is not well understood, because in many places the Devonian and Carboniferous rock strata are covered with younger deposits. Parts of the basin have their own names, like the Cornwall basin in Cornwall, the Munster basin in Ireland or the Rhenisch basin in Belgium and Germany.

The Rhenohercynian Zone is a part of the northern foreland of the Hercynian orogeny. It has a lower grade of metamorphism than the Saxothuringian Zone to the south, meaning its rocks have generally been at smaller depths and under lower temperatures. The Subvariscan Zone north of the Rhenohercynian Zone was untouched by Hercynian metamorphism. During the Hercynian orogeny, the Rhenohercynian zone was folded and thrust internally. It was thrust over the foreland to the north (the London-Brabant Massif and other Avalonian terranes). From the south it was overthrust by the Mid-German Crystalline High, part of the Saxothuringian Zone.

The metamorphic grade or degree of metamorphism increases towards the south or southeast. The southern edge of the Rhenish Massif lies in the Northern Phyllite Zone, which has a higher grade than other parts of the zone.

The Rhenohercynian basin was situated north of the Rheic Ocean, the ocean that spread between the continents of Laurussia (north) and Gondwana (south) from the Silurian onwards. The southern margin of Laurussia was formed during the Caledonian orogeny of the Silurian period, about 420 million years ago. In the Gedinnian/Lochkovian (Early Devonian) the southern part of the Caledonian mountain belt became a region of north–south extension. An elongated basin was formed parallel to the continental margin. It separated the London-Brabant Massif to the north from the Normannian and Mid-German Highs to the south.

In the Middle Devonian (from 390 million years ago) a subduction zone existed south of Laurussia, where oceanic lithosphere of the Rheic Ocean subducted beneath the Mid-German/Normannian highs. Volcanism above the subduction zone created a cordillera-type mountain chain, the Ligerian cordillera. In the Siegenian/Pragian and Emsian the Rhenohercynic basin was a back-arc basin behind this cordillera. Tectonic subsidence in a system of horsts and grabens together with basaltic volcanism resulted in the creation of new oceanic lithosphere. In the Middle Devonian a second basin, the Saxothuringian/Armorican basin, developed south of the Rhenohercynian basin. To the west some crustal convergence took place, and the Normannian High was partly thrust over the sedimentary basin fill of the Rhenohercynian basin.

The Rhenohercynian basin disappeared when the continent Gondwana collided with Laurussia in the course of the Carboniferous period (the Hercynian orogeny). The sedimentary rocks in the basin were thrust in a series of piggyback basins over the northern foreland (the London-Brabant Massif). These rocks now form the folded sequences of Cornwall, the Ardennes, the Eifel and the Harz.