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Sellmeier equation

The Sellmeier equation is an empirical relationship between refractive index and wavelength for a particular transparent medium. The equation is used to determine the dispersion of light in the medium.

It was first proposed in 1872 by Wolfgang Sellmeier and was a development of the work of Augustin Cauchy on Cauchy's equation for modelling dispersion.

In its original and the most general form, the Sellmeier equation is given as

where n is the refractive index, λ is the wavelength, and Bi and Ci are experimentally determined Sellmeier coefficients. These coefficients are usually quoted for λ in micrometres. Note that this λ is the vacuum wavelength, not that in the material itself, which is λ/n. A different form of the equation is sometimes used for certain types of materials, e.g. crystals.

Each term of the sum representing an absorption resonance of strength Bi at a wavelength Ci. For example, the coefficients for BK7 below correspond to two absorption resonances in the ultraviolet, and one in the mid-infrared region. Analytically, this process is based on approximating the underlying optical resonances as dirac delta functions, followed by the application of the Kramers-Kronig relations. This results in real and imaginary parts of the refractive index which are physically sensible. However, close to each absorption peak, the equation gives non-physical values of n2 = ±∞, and in these wavelength regions a more precise model of dispersion such as Helmholtz's must be used.

If all terms are specified for a material, at long wavelengths far from the absorption peaks the value of n tends to

where εr is the relative permittivity of the medium.

For characterization of glasses the equation consisting of three terms is commonly used:

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empirical relationship between refractive index and wavelength
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