Spontaneous parametric down-conversion (also known as SPDC, parametric fluorescence or parametric scattering) is a nonlinear instant optical process that converts one photon of higher energy (namely, a pump photon) into a pair of photons (namely, signal and idler photons) of lower energy, in accordance with the laws of energy conservation and momentum conservation. It is an important process in quantum optics, for the generation of entangled photon pairs and of single photons.

A nonlinear crystal is used to produce pairs of photons from a photon beam. In accordance with conservations of energy and momentum, the pairs need to have combined energies and momenta equal to the energy and momentum of the original photon. Because the index of refraction changes with frequency (dispersion), only certain triplets of frequencies will be phase-matched so that simultaneous energy and momentum conservation can be achieved. Phase-matching is most commonly achieved using birefringent nonlinear materials, whose index of refraction changes with polarization. As a result of this, different types of SPDC are categorized by the polarizations of the input photon (pump) and the two output photons (signal and idler).

The conversion efficiency of SPDC is typically very low, with the highest efficiency obtained on the order of 4x10⁻⁶ incoming photons for periodically poled lithium niobate (PPLN) in waveguides. However, if one half of the pair is detected at any time then its partner is known to be present. The degenerate portion of the output of a Type I down converter is a squeezed vacuum that contains only even photon number terms. The nondegenerate output of the Type II down converter is a two-mode squeezed vacuum.

In a commonly used SPDC apparatus design, a strong laser beam, termed the "pump" beam, is directed at a BBO (beta-barium borate) or lithium niobate crystal. Most of the photons continue straight through the crystal. However, occasionally, some of the photons undergo spontaneous down-conversion with Type II polarization correlation, and the resultant correlated photon pairs have trajectories that are constrained along the sides of two cones whose axes are symmetrically arranged relative to the pump beam. Due to the conservation of momentum, the two photons are always symmetrically located on the sides of the cones, relative to the pump beam. In particular, the trajectories of a small proportion of photon pairs will lie simultaneously on the two lines where the surfaces of the two cones intersect. This results in entanglement of the polarizations of the pairs of photons emerging on those two lines. The photon pairs are in an equal weight quantum superposition of the unentangled states ${\displaystyle \vert H\rangle \vert V\rangle }$ and ${\displaystyle \vert V\rangle \vert H\rangle }$, corresponding to polarizations of left-hand side photon, right-hand side photon.

Another crystal is KDP (potassium dihydrogen phosphate) which is mostly used in Type I down conversion, where both photons have the same polarization.

Some of the characteristics of effective parametric down-converting nonlinear crystals include:

SPDC was demonstrated as early as 1967 by S. E. Harris, M. K. Oshman, and R. L. Byer, as well as by D. Magde and H. Mahr. It was first applied to experiments related to coherence by two independent pairs of researchers in the late 1980s: Carroll Alley and Yanhua Shih, and Rupamanjari Ghosh and Leonard Mandel. The duality between incoherent (Van Cittert–Zernike theorem) and biphoton emissions was found.

SPDC allows for the creation of optical fields containing (to a good approximation) a single photon. As of 2005, this is the predominant mechanism for an experimenter to create single photons (also known as Fock states). The single photons as well as the photon pairs are often used in quantum information experiments and applications like quantum cryptography and Bell test experiments.