Steam reforming
Steam reforming
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Steam reforming

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Steam reforming

Steam reforming or steam methane reforming (SMR) is a method for producing syngas (hydrogen and carbon monoxide) by reaction of hydrocarbons with water. Commonly, natural gas is the feedstock. The main purpose of this technology is often hydrogen production, although syngas has multiple other uses such as production of ammonia or methanol. The reaction is represented by this equilibrium:

The reaction is strongly endothermicHSR = 206 kJ/mol).

Hydrogen produced by steam reforming is termed 'grey' hydrogen when the waste carbon dioxide is released to the atmosphere and 'blue' hydrogen when the carbon dioxide is (mostly) captured and stored geologically—see carbon capture and storage. Zero carbon 'green' hydrogen is produced by thermochemical water splitting, using solar thermal, low- or zero-carbon electricity or waste heat, or electrolysis, using low- or zero-carbon electricity. Zero carbon emissions 'turquoise' hydrogen is produced by one-step methane pyrolysis of natural gas.

Steam reforming of natural gas produces most of the world's hydrogen. Hydrogen is used in the industrial synthesis of ammonia and other chemicals.

Steam reforming reaction kinetics, in particular using nickel-alumina catalysts, have been studied in detail since the 1950s.

The purpose of pre-reforming is to break down higher hydrocarbons such as propane, butane or naphtha into methane (CH4), which allows for more efficient reforming downstream.

The name-giving reaction is the steam reforming (SR) reaction and is expressed by the equation:

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