Lava

Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or underwater, usually at temperatures from 800 to 1,200 °C (1,470 to 2,190 °F). Lava may be erupted directly onto the land surface or onto the sea floor or it may be ejected into the atmosphere before falling back down. The solid volcanic rock resulting from subsequent cooling of the molten material is often also called lava.

A lava flow is an outpouring of lava during an effusive eruption. (An explosive eruption, by contrast, produces a mixture of volcanic ash and other fragments called tephra, not lava flows.) The viscosity of most molten lava is about that of ketchup, roughly 10,000 to 100,000 times that of water (the latter two substances measured at 25 °C (77 °F) and 1 atm). Even so, lava can flow great distances before cooling causes it to solidify, because lava exposed to air quickly develops a solid crust that insulates the remaining liquid lava, helping to keep it hot and inviscid enough to continue flowing.

The word lava comes from Italian and is probably derived from the Latin word labes, which means a 'fall' or 'slide'. An early use of the word in connection with extrusion of magma from below the surface is found in a short account of the 1737 eruption of Vesuvius, written by Francesco Serao, who described "a flow of fiery lava" as an analogy to the flow of water and mud down the flanks of the volcano (a lahar) after heavy rain.

Solidified lava on the Earth's crust is predominantly silicate minerals: mostly feldspars, feldspathoids, olivine, pyroxenes, amphiboles, micas and quartz. Rare nonsilicate lavas can be formed by local melting of nonsilicate mineral deposits or by separation of a magma into immiscible silicate and nonsilicate liquid phases.

Silicate lavas are molten mixtures dominated by oxygen and silicon, the most abundant elements of the Earth's crust, with smaller quantities of aluminium, calcium, magnesium, iron, sodium, and potassium and minor amounts of many other elements. Petrologists routinely express the composition of a silicate lava in terms of the weight or molar mass fraction of the oxides of the major elements (other than oxygen) present in the lava.

The silica component dominates the physical behavior of silicate magmas. Silicon ions in lava strongly bind to four oxygen ions in a tetrahedral arrangement. If an oxygen ion is bound to two silicon ions in the melt, it is described as a bridging oxygen, and lava with many clumps or chains of silicon ions connected by bridging oxygen ions is described as partially polymerized. Aluminium in combination with alkali metal oxides (sodium and potassium) also tends to polymerize the lava. Other cations, such as ferrous iron, calcium, and magnesium, bond much more weakly to oxygen and reduce the tendency to polymerize. Partial polymerization makes the lava viscous, so lava high in silica is much more viscous than lava low in silica.

Because of the role of silica in determining viscosity and because many other properties of a lava (such as its temperature) are observed to correlate with silica content, silicate lavas are divided into four chemical types based on silica content: felsic, intermediate, mafic, and ultramafic.

Felsic or silicic lavas have a silica content greater than 63%. They include rhyolite and dacite lavas. With such a high silica content, these lavas are extremely viscous, ranging from 10⁸ cP (10⁵ Pa⋅s) for hot rhyolite lava at 1,200 °C (2,190 °F) to 10¹¹ cP (10⁸ Pa⋅s) for cool rhyolite lava at 800 °C (1,470 °F). For comparison, water has a viscosity of about 1 cP (0.001 Pa⋅s). Because of this very high viscosity, felsic lavas usually erupt explosively to produce pyroclastic (fragmental) deposits. However, rhyolite lavas occasionally erupt effusively to form lava spines, lava domes or "coulees" (which are thick, short lava flows). The lavas typically fragment as they extrude, producing block lava flows. These often contain obsidian.