Chalk

Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed under the sea by the accumulation and lithification of hard parts of organisms, mostly microscopic plankton, which had settled to the sea floor. Chalk is common throughout Western Europe, where deposits underlie parts of France, and steep cliffs are often seen where they meet the sea in places such as the Dover cliffs on the Kent coast of the English Channel.

Chalk is mined for use in industry, such as for quicklime, bricks and builder's putty, and in agriculture, for raising pH in soils with high acidity. It is also used for "blackboard chalk" for writing and drawing on various types of surfaces, although these can also be manufactured from other carbonate-based minerals, or gypsum.

Chalk is a fine-textured, earthy type of limestone distinguished by its light colour, softness, and high porosity. It is composed mostly of tiny fragments of the calcite shells or skeletons of plankton, such as foraminifera or coccolithophores. These fragments mostly take the form of calcite plates ranging from 0.5 to 4 microns in size, though about 10% to 25% of a typical chalk is composed of fragments that are 10 to 100 microns in size. The larger fragments include intact plankton skeletons and skeletal fragments of larger organisms, such as molluscs, echinoderms, or bryozoans.

Chalk is typically almost pure calcite, CaCO₃, with just 2% to 4% of other minerals. These are usually quartz and clay minerals, though collophane (cryptocrystalline apatite, a phosphate mineral) is also sometimes present, as nodules or as small pellets interpreted as fecal pellets. In some chalk beds, the calcite has been converted to dolomite, CaMg(CO₃)₂, and in a few cases the dolomitized chalk has been dedolomitized back to calcite.

Chalk is highly porous, with typical values of porosity ranging from 35 to 47 per cent. While it is similar in appearance to both gypsum and diatomite, chalk is identifiable by its hardness, fossil content, and its reaction to acid (it produces effervescence on contact).

In Western Europe, chalk was formed in the Late Cretaceous Epoch and the early Palaeocene Epoch (between 100 and 61 million years ago). It was deposited on extensive continental shelves at depths between 100 and 600 metres (330 and 1,970 ft), during a time of nonseasonal (likely arid) climate that reduced the amount of erosion from nearby exposed rock. The lack of nearby erosion explains the high purity of chalk. The coccolithophores, foraminifera, and other microscopic organisms from which the chalk came mostly form low-magnesium calcite skeletons, so the sediments were already in the form of highly stable low-magnesium calcite when deposited. This is in contrast with most other limestones, which formed from high-magnesium calcite or aragonite that rapidly converted to the more stable low-magnesium calcite after deposition, resulting in the early cementation of such limestones. In chalk, the absence of calcium carbonate conversion process prevented early cementation, and it accounts for chalk's high porosity. Additionally, chalk is the only form of limestone that commonly shows signs of compaction.

Flint (a type of chert) is very common as bands parallel to the bedding or as nodules in seams, or linings to fractures, embedded in chalk. It is probably derived from sponge spicules or other siliceous organisms as water is expelled upwards during compaction. Flint is often deposited around larger fossils such as Echinoidea which may be silicified (i.e. replaced molecule by molecule by flint).

Chalk is so common in Cretaceous marine beds that the Cretaceous Period was named for these deposits. The name Cretaceous was derived from Latin creta, meaning chalk. Some deposits of chalk were formed after the Cretaceous.