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Chert

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Chert

Chert (/ɜːrt/) is a hard, fine-grained sedimentary rock composed of microcrystalline or cryptocrystalline quartz, the mineral form of silicon dioxide (SiO2). Chert is characteristically of biological origin, but may also occur inorganically as a chemical precipitate or a diagenetic replacement, as in petrified wood. Where chert occurs in chalk or marl, it is usually called flint.

Chert is typically composed of the petrified remains of siliceous ooze, the biogenic sediment that covers large areas of the deep ocean floor, and which contains the silicon skeletal remains of diatoms, silicoflagellates, and radiolarians. Precambrian cherts are notable for the presence of fossil cyanobacteria. In addition to microfossils, chert occasionally contains macrofossils. However, some chert is devoid of any fossils.

Chert varies greatly in color, from white to black, but is most often found as gray, brown, grayish brown and light green to rusty red and occasionally as dark green. Its color is an expression of trace elements present in the rock. Both red and green are most often related to traces of iron in its oxidized and reduced forms, respectively.

In petrology, the term "chert" refers generally to all chemically precipitated sedimentary rocks composed primarily of microcrystalline, cryptocrystalline and microfibrous silica. Most cherts are nearly pure silica, with less than 5% other minerals (mostly calcite, dolomite, clay minerals, hematite, and organic matter.) However, cherts range from very pure cherts with over 99% silica content to impure nodular cherts with less than 65% silica content. Aluminium is the most abundant minor element, followed by iron and manganese or potassium, sodium, and calcium. Extracrystalline water (tiny inclusions of water within and around the quartz grains) make up less than 1% of most cherts.

The Folk classification divides chert into three textural categories. Granular microquartz is the component of chert consisting of roughly equidimensional quartz grains, ranging in size from a fraction of a micron to 20 microns, but most typically 8 to 10 microns. Chalcedony is a microfibrous variety of quartz, consisting of radiating bundles of very thin crystals about 100 microns long. Megaquartz is composed of equidimensional grains over 20 microns in size. Most chert is microcrystalline quartz with minor chalcedony and sometimes opal, but cherts range from nearly pure opal to nearly pure quartz chert. However, little opal is over 60 million years old. Opaline chert often contains visible fossils of diatoms, radiolarians, and glass sponge spicules.

Chert is found in settings as diverse as hot spring deposits (siliceous sinter), banded iron formation (jaspilite), or alkaline lakes. However, most chert is found either as bedded chert or as nodular chert. Bedded chert is more common in Precambrian beds, but nodular chert became more common in the Phanerozoic as the total volume of chert in the rock record diminished. Bedded chert is rare after the early Mesozoic. Chert became moderately abundant during the Devonian and Carboniferous and again became moderately abundant from the Jurassic to the present.

Bedded chert, also known as ribbon chert, takes the form of thinly bedded layers (a few centimeters to a meter in thickness) of nearly pure chert separated by very thin layers of silica-rich shale. It is usually black to green in color, and the full sequence of beds may be several hundred meters thick. The shale is typically black shale, sometimes with pyrite, indicating deposition in an anoxic environment. Bedded chert is most often found in association with turbidites, deep water limestone, submarine volcanic rock, ophiolites, and mélanges on active margins of tectonic plates. Sedimentary structures are rare in bedded cherts. The typically high purity of bedded chert, like the high purity of other chemically precipitated rock, points to deposition in areas where there is little influx of detrital sediments (such as river water laden with silt and clay particles.) Such impurities as are present include authigenic pyrite and hematite, formed in the sediments after they were deposited, in addition to traces of detrital minerals.

Seawater typically contains between 0.01 and 11 parts per million (ppm) of silica, with around 1 ppm being typical. This is far below saturation, indicating that silica cannot normally be precipitated from seawater through inorganic processes. The silica is instead extracted from seawater by living organisms, such as diatoms, radiolarians, and glass sponges, which can efficiently extract silica even from very unsaturated water, and which are estimated to presently produce 12 cubic kilometers (2.9 cu mi) of opal per year in the world's oceans. Diatoms can double their numbers eight times a day under ideal conditions (though doubling once per day is more typical in normal seawater) and can extract silica from water with as little as 0.1 ppm silica. The organisms protect their skeletons from dissolution by "armoring" them with metal ions. Once the organisms die, their skeletons will quickly dissolve unless they accumulate on the ocean bottom and are buried, forming siliceous ooze that is 30% to 60% silica. Thus, bedded cherts are typically composed mostly of fossil remains of organisms that secrete silica skeletons, which are usually altered by solution and recrystallization.

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