International Prototype of the Kilogram

The International Prototype of the Kilogram (referred to by metrologists as the IPK or Le Grand K; sometimes called the ur-kilogram, or urkilogram, particularly by German-language authors writing in English^:30) is an object whose mass was used to define the kilogram from 1889, when it replaced the Kilogramme des Archives, until 2019, when it was replaced by a new definition of the kilogram based entirely on physical constants. During that time, the IPK and its duplicates were used to calibrate all other kilogram mass standards on Earth.

The IPK is a roughly golfball-sized object made of a platinum–iridium alloy known as "Pt‑10Ir", which is 90% platinum and 10% iridium (by mass) and is machined into a right-circular cylinder with perpendicular height equal to its diameter of about 39 millimetres to reduce its surface area. The addition of 10% iridium improved upon the all-platinum Kilogramme des Archives by greatly increasing hardness while still retaining platinum's many virtues: extreme resistance to oxidation, extremely high density (almost twice as dense as lead and more than 21 times as dense as water), satisfactory electrical and thermal conductivities, and low magnetic susceptibility.

By 2018, the IPK underpinned the definitions of four of the seven SI base units: the kilogram itself, plus the mole, ampere, and candela (whose definitions at the time referenced the gram, newton, and watt respectively) as well as the definitions of every named SI derived unit except the hertz, becquerel, degree Celsius, gray, sievert, farad, ohm, siemens, henry, radian, and steradian.

The IPK and its six sister copies are stored at the International Bureau of Weights and Measures (known by its French-language initials BIPM) in an environmentally monitored safe in the lower vault located in the basement of the BIPM's Pavillon de Breteuil in Saint-Cloud on the outskirts of Paris (see External images, below, for photographs). Three independently controlled keys are required to open the vault. Official copies of the IPK were made available to other nations to serve as their national standards. These were compared to the IPK roughly every 40 years, thereby providing traceability of local measurements back to the IPK.

The Metre Convention was signed on 20 May 1875 and further formalised the metric system (a predecessor to the SI), quickly leading to the production of the IPK. The IPK is one of three cylinders made in London in 1879 by Johnson Matthey, which continued to manufacture nearly all of the national prototypes as needed until the new definition of the kilogram came into effect in 2019. In 1883, the mass of the IPK was found to be indistinguishable from that of the Kilogramme des Archives made eighty-four years prior, and was formally ratified as the kilogram by the 1st CGPM in 1889.

The IPK and its various copies are given the following designations in the literature:

Before 2019, by definition, the error in the measured value of the IPK's mass was exactly zero; the mass of the IPK was the kilogram. However, any changes in the IPK's mass over time could be deduced by comparing its mass to that of its official copies stored throughout the world, a rarely undertaken process called "periodic verification". The only three verifications occurred in 1889, 1948, and 1989. For instance, the US owns five 90% platinum / 10% iridium (Pt‑10Ir) kilogram standards, two of which, K4 and K20, are from the original batch of 40 replicas distributed in 1884. The K20 prototype was designated as the primary national standard of mass for the US. Both of these, as well as those from other nations, are periodically returned to the BIPM for verification. Great care is exercised when transporting prototypes. In 1984, the K4 and K20 prototypes were hand-carried in the passenger section of separate commercial flights.

None of the replicas has a mass precisely equal to that of the IPK; their masses are calibrated and documented as offset values. For instance, K20, the US's primary standard, originally had an official mass of 1 kg − 39 μg (micrograms) in 1889; that is to say, K20 was 39 μg less than the IPK. A verification performed in 1948 showed a mass of 1 kg − 19 μg. The latest verification performed in 1989 shows a mass precisely identical to its original 1889 value. Quite unlike transient variations such as this, the US's check standard, K4, has persistently declined in mass relative to the IPK—and for an identifiable reason: check standards are used much more often than primary standards and are prone to scratches and other wear. K4 was originally delivered with an official mass of 1 kg − 75 μg in 1889, but as of 1989 was officially calibrated at 1 kg − 106 μg and ten years later was 1 kg − 116 μg. Over a period of 110 years, K4 lost 41 μg relative to the IPK.