Lime kiln

A lime kiln is a kiln used for the calcination of limestone (calcium carbonate) to produce the form of lime called quicklime (calcium oxide). The chemical equation for this reaction is: CaCO₃ + heat → CaO + CO₂

This reaction can take place at anywhere above 840 °C (1,540 °F), but is generally considered to occur at 900 °C (1,650 °F) (at which temperature the partial pressure of CO₂ is 1 atmosphere), but a temperature around 1,000 °C (1,830 °F) (at which temperature the partial pressure of CO₂ is 3.8 atmospheres) is usually used to make the reaction proceed quickly. Excessive temperature is avoided because it produces unreactive, "dead-burned" lime.

Slaked lime (calcium hydroxide) can be formed by mixing quicklime with water.

Because it is so readily made by heating limestone, lime must have been known from the earliest times, and all the early civilizations used it in building mortars and as a stabilizer in mud renders and floors. According to finds at 'Ain Ghazal in Jordan, Yiftahel in Israel, and Abu Hureyra in Syria dating to 7500–6000 BC, the earliest use of lime was mostly as a binder on floors and in plaster for coating walls. This use of plaster may in turn have led to the development of proto-pottery, made from lime and ash. In mortar, the oldest binder was mud. According to finds at Catal Hüyük in Turkey, mud was soon followed by clay, and then by lime in the 6th millennium BC.

Knowledge of its value in agriculture is also ancient, but agricultural use only became widely possible when the use of coal made it cheap in the coalfields in the late 13th century, and an account of agricultural use was given in 1523. The earliest descriptions of lime kilns differ little from those used for small-scale manufacture a century ago.^{[citation needed]} Because land transportation of minerals like limestone and coal was difficult in the pre-industrial era, they were distributed by sea, and lime was most often manufactured at small coastal ports.^{[citation needed]} Many preserved kilns are still to be seen on quaysides around the coasts of Britain.

Permanent lime kilns fall into two broad categories: "flare kilns" also known as "intermittent" or "periodic" kilns; and "draw kilns" also known as "perpetual" or "running" kilns. In a flare kiln, a bottom layer of coal was built up and the kiln above filled solely with chalk. The fire was alight for several days, and then the entire kiln was emptied of the lime.

In a draw kiln, usually a stone structure, the chalk or limestone was layered with wood, coal or coke and lit. As it burnt through, lime was extracted from the bottom of the kiln, through the draw hole. Further layers of stone and fuel were added to the top.

The common feature of early kilns was an egg-cup shaped burning chamber, with an air inlet at the base (the "eye"), constructed of brick. Limestone was crushed (often by hand) to fairly uniform 20–60 mm (1–2+1⁄2 in) lumps – fine stone was rejected. Successive dome-shaped layers of limestone and wood or coal were built up in the kiln on grate bars across the eye. When loading was complete, the kiln was kindled at the bottom, and the fire gradually spread upwards through the charge. When burnt through, the lime was cooled and raked out through the base. Fine ash dropped out and was rejected with the "riddlings".