Metals of antiquity

The metals of antiquity are the seven metals which humans had identified and found use for in prehistoric times in Africa, Europe and throughout Asia: gold, silver, copper, tin, lead, iron, and mercury.

Zinc, arsenic, and antimony were also known during antiquity, but they were not recognised as distinct metals until later. A special case is platinum; it was known to native South Americans around the time Europe was going through classical antiquity, but was unknown to Europeans until the 18th century. Thus, at most eleven elemental metals and metalloids were known by the end of antiquity; this contrasts greatly with the situation today, with over 90 elemental metals known. Bismuth only began to be recognised as distinct around 1500 by the European and Incan civilisations. The first elemental metal with a clearly identifiable discoverer is cobalt, discovered in 1735 by Georg Brandt, by which time the Scientific Revolution was in full swing. (Even then, cobalt might have been prepared before the 13th century by alchemists roasting and reducing its ore, but, in any case, its distinct nature was not recognised.)

Copper was probably the first metal mined and crafted by humans. It was originally obtained as a native metal and later from the smelting of ores. Earliest estimates of the discovery of copper suggest around 9000 BC in the Middle East. It was one of the most important materials to humans throughout the Chalcolithic and Bronze Ages. Copper beads dating from 6000 BC have been found in Çatalhöyük, Anatolia, and the archaeological site of Belovode on the Rudnik mountain in Serbia contains the world's oldest securely dated evidence of copper smelting from 5000 BC.

It is believed that lead smelting began at least 9,000 years ago, and the oldest known artifact of lead is a statuette found at the temple of Osiris on the site of Abydos dated around 3800 BC.

The earliest gold artifacts were discovered at the site of Wadi Qana in the Levant. Silver is estimated to have been discovered in Asia Minor shortly after copper and gold.

There is evidence that iron was known from before 5000 BC. The oldest known iron objects used by humans are some beads of meteoric iron, made in Egypt in about 4000 BC. The discovery of smelting around 3000 BC led to the start of the Iron Age around 1200 BC and the prominent use of iron for tools and weapons.

Tin was first smelted in combination with copper around 3500 BC to produce bronze - and thus giving place to the Bronze Age (except in some places which did not experience a significant Bronze Age, passing directly from the Neolithic Stone Age to the Iron Age). Kestel, in southern Turkey, is the site of an ancient Cassiterite mine that was used from 3250 to 1800 BC. The oldest artifacts date from around 2000 BC.

The metals of antiquity were recognised as distinct elements in Méthode de nomenclature chimique (Method of Chemical Nomenclature), written by a group consisting of Louis Guyton de Morveau, Antoine Lavoisier, Claude Berthollet, and Antoine-François de Fourcroy in 1787.