Neon

Neon is a chemical element; it has symbol Ne and atomic number 10. It is the second noble gas in the periodic table. Neon is a colorless, odorless, inert monatomic gas under standard conditions, with approximately two-thirds the density of air.

Neon was discovered in 1898 alongside krypton and xenon, identified as one of the three remaining rare inert elements in dry air after the removal of nitrogen, oxygen, argon, and carbon dioxide. Its discovery was marked by the distinctive bright red emission spectrum it exhibited, leading to its immediate recognition as a new element. The name neon originates from the Greek word νέον, a neuter singular form of νέος (neos), meaning 'new'. Neon is a chemically inert gas; although neon compounds do exist, they are primarily ionic molecules or fragile molecules held together by van der Waals forces.

The synthesis of most neon in the cosmos resulted from the nuclear fusion within stars of oxygen and helium through the alpha-capture process. Despite its abundant presence in the universe and Solar System—ranking fifth in cosmic abundance following hydrogen, helium, oxygen, and carbon—neon is comparatively scarce on Earth. It constitutes about 18.2 ppm of Earth's atmospheric volume and a lesser fraction in the Earth's crust. The high volatility of neon and its inability to form compounds that would anchor it to solids explain its limited presence on Earth and the inner terrestrial planets. Neon's high volatility facilitated its escape from planetesimals under the early Solar System's nascent Sun's warmth.

Neon's notable applications include its use in low-voltage neon glow lamps, high-voltage discharge tubes, and neon advertising signs, where it emits a distinct reddish-orange glow. This same red emission line is responsible for the characteristic red light of helium–neon lasers. Although neon has some applications in plasma tubes and as a refrigerant, its commercial uses are relatively limited. It is primarily obtained through the fractional distillation of liquid air, making it significantly more expensive than helium due to air being its sole source.

Neon was discovered in 1898 by the British chemists Sir William Ramsay (1852–1916) and Morris Travers (1872–1961) in London. Neon was discovered when Ramsay chilled a sample of air until it became a liquid, then warmed the liquid and captured the gases as they boiled off. The gases nitrogen, oxygen, and argon had been identified, but the remaining gases were isolated in roughly their order of abundance, in a six-week period beginning at the end of May 1898. The first remaining gas to be identified was krypton; the next, after krypton had been removed, was a gas which gave a brilliant red light under spectroscopic discharge. This gas, identified in June, was named "neon", the Greek analogue of the Latin novum ('new') suggested by Ramsay's son. The characteristic brilliant red-orange color emitted by gaseous neon when excited electrically was noted immediately. Travers later wrote: "the blaze of crimson light from the tube told its own story and was a sight to dwell upon and never forget."

A second gas was also reported along with neon, having approximately the same density as argon but with a different spectrum – Ramsay and Travers named it metargon. However, the subsequent spectroscopic analysis revealed it to be argon contaminated with carbon monoxide. Finally, the same team discovered xenon by the same process, in September 1898.

Neon's scarcity precluded its prompt application for lighting along the lines of Moore tubes, which used nitrogen and which were commercialized in the early 1900s. After 1902, Georges Claude's company Air Liquide produced industrial quantities of neon as a byproduct of his air-liquefaction business. In December 1910 Claude demonstrated modern neon lighting based on a sealed tube of neon. Claude tried briefly to sell neon tubes for indoor domestic lighting, due to their intensity, but the market failed because homeowners objected to the color. In 1912, Claude's associate began selling neon discharge tubes as eye-catching advertising signs and was instantly more successful. Neon tubes were introduced to the U.S. in 1923 with two large neon signs bought by a Los Angeles Packard car dealership. The glow and arresting red color made neon advertising completely different from the competition. The intense color and vibrancy of neon equated with American society at the time, suggesting a "century of progress" and transforming cities into sensational new environments filled with radiating advertisements and "electro-graphic architecture".

Neon played a role in the basic understanding of the nature of atoms in 1913, when J. J. Thomson, as part of his exploration into the composition of canal rays, channeled streams of neon ions through a magnetic and an electric field and measured the deflection of the streams with a photographic plate. Thomson observed two separate patches of light on the photographic plate (see image), which suggested two different parabolas of deflection. Thomson eventually concluded that some of the atoms in the neon gas were of higher mass than the rest. Though not understood at the time by Thomson, this was the first discovery of isotopes of stable atoms. Thomson's device was a crude version of the instrument we now term a mass spectrometer.