Optical depth

In physics, optical depth or optical thickness is the natural logarithm of the ratio of incident to transmitted radiant power through a material. Thus, the larger the optical depth, the smaller the amount of transmitted radiant power through the material. Spectral optical depth or spectral optical thickness is the natural logarithm of the ratio of incident to transmitted spectral radiant power through a material. Optical depth is dimensionless, and in particular is not a length, though it is a monotonically increasing function of optical path length, and approaches zero as the path length approaches zero. The use of the term "optical density" for optical depth is discouraged.

In chemistry, a closely related quantity called "absorbance" or "decadic absorbance" is used instead of optical depth: the common logarithm of the ratio of incident to transmitted radiant power through a material. It is the optical depth divided by log_e(10), because of the different logarithm bases used.

The optical depth of a material, denoted ${\textstyle \tau }$, is given by:$${\displaystyle \tau =\ln \!\left({\frac {\Phi _{\mathrm {e} }^{\mathrm {i} }}{\Phi _{\mathrm {e} }^{\mathrm {t} }}}\right)=-\ln T}$$where

The absorbance ${\textstyle A}$ is related to optical depth by:$${\displaystyle \tau =A\ln {10}}$$

The spectral optical depth in frequency (denoted ${\displaystyle \tau _{\nu }}$) or in wavelength (${\displaystyle \tau _{\lambda }}$) of a material is given by: $${\displaystyle \tau _{\nu }=\ln \!\left({\frac {\Phi _{\mathrm {e} ,\nu }^{\mathrm {i} }}{\Phi _{\mathrm {e} ,\nu }^{\mathrm {t} }}}\right)=-\ln T_{\nu }}$$$${\displaystyle \tau _{\lambda }=\ln \!\left({\frac {\Phi _{\mathrm {e} ,\lambda }^{\mathrm {i} }}{\Phi _{\mathrm {e} ,\lambda }^{\mathrm {t} }}}\right)=-\ln T_{\lambda },}$$ where

Spectral absorbance is related to spectral optical depth by: $${\displaystyle \tau _{\nu }=A_{\nu }\ln 10,}$$$${\displaystyle \tau _{\lambda }=A_{\lambda }\ln 10,}$$ where

Optical depth measures the attenuation of the transmitted radiant power in a material. Attenuation can be caused by absorption, but also reflection, scattering, and other physical processes. Optical depth of a material is approximately equal to its attenuation when both the absorbance is much less than 1 and the emittance of that material (not to be confused with radiant exitance or emissivity) is much less than the optical depth: $${\displaystyle \Phi _{\mathrm {e} }^{\mathrm {t} }+\Phi _{\mathrm {e} }^{\mathrm {att} }=\Phi _{\mathrm {e} }^{\mathrm {i} }+\Phi _{\mathrm {e} }^{\mathrm {e} },}$$$${\displaystyle T+ATT=1+E,}$$ where

and according to the Beer–Lambert law, $${\displaystyle T=e^{-\tau },}$$so:$${\displaystyle ATT=1-e^{-\tau }+E\approx \tau +E\approx \tau ,\quad {\text{if}}\ \tau \ll 1\ {\text{and}}\ E\ll \tau .}$$