In graph theory, graph coloring is a methodic assignment of labels traditionally called "colors" to elements of a graph. The assignment is subject to certain constraints, such as that no two adjacent elements have the same color. Graph coloring is a special case of graph labeling. In its simplest form, it is a way of coloring the vertices of a graph such that no two adjacent vertices are of the same color; this is called a vertex coloring. Similarly, an edge coloring assigns a color to each edge so that no two adjacent edges are of the same color, and a face coloring of a planar graph assigns a color to each face (or region) so that no two faces that share a boundary have the same color.

Vertex coloring is often used to introduce graph coloring problems, since other coloring problems can be transformed into a vertex coloring instance. For example, an edge coloring of a graph is just a vertex coloring of its line graph, and a face coloring of a plane graph is just a vertex coloring of its dual. However, non-vertex coloring problems are often stated and studied as-is. This is partly pedagogical, and partly because some problems are best studied in their non-vertex form, as in the case of edge coloring.

The convention of using colors originates from coloring the countries in a political map, where each face is literally colored. This was generalized to coloring the faces of a graph embedded in the plane. By planar duality it became coloring the vertices, and in this form it generalizes to all graphs. In mathematical and computer representations, it is typical to use the first few positive or non-negative integers as the "colors". In general, one can use any finite set as the "color set". The nature of the coloring problem depends on the number of colors but not on what they are.

Graph coloring enjoys many practical applications as well as theoretical challenges. Beside the classical types of problems, different limitations can also be set on the graph, or on the way a color is assigned, or even on the color itself. It has even reached popularity with the general public in the form of the popular number puzzle Sudoku. Graph coloring is still a very active field of research.

The first results about graph coloring deal almost exclusively with planar graphs in the form of map coloring. While trying to color a map of the counties of England, Francis Guthrie postulated the four color conjecture, noting that four colors were sufficient to color the map so that no regions sharing a common border received the same color. Guthrie's brother passed on the question to his mathematics teacher Augustus De Morgan at University College, who mentioned it in a letter to William Hamilton in 1852. Arthur Cayley raised the problem at a meeting of the London Mathematical Society in 1879. The same year, Alfred Kempe published a paper that claimed to establish the result, and for a decade the four color problem was considered solved. For his accomplishment Kempe was elected a Fellow of the Royal Society and later President of the London Mathematical Society.

In 1890, Percy John Heawood pointed out that Kempe's argument was wrong. However, in that paper he proved the five color theorem, saying that every planar map can be colored with no more than five colors, using ideas of Kempe. In the following century, a vast amount of work was done and theories were developed to reduce the number of colors to four, until the four color theorem was finally proved in 1976 by Kenneth Appel and Wolfgang Haken. The proof went back to the ideas of Heawood and Kempe and largely disregarded the intervening developments. The proof of the four color theorem is noteworthy, aside from its solution of a century-old problem, for being the first major computer-aided proof.

In 1912, George David Birkhoff introduced the chromatic polynomial to study the coloring problem, which was generalised to the Tutte polynomial by W. T. Tutte, both of which are important invariants in algebraic graph theory. Kempe had already drawn attention to the general, non-planar case in 1879, and many results on generalisations of planar graph coloring to surfaces of higher order followed in the early 20th century.

In 1960, Claude Berge formulated another conjecture about graph coloring, the strong perfect graph conjecture, originally motivated by an information-theoretic concept called the zero-error capacity of a graph introduced by Shannon. The conjecture remained unresolved for 40 years, until it was established as the celebrated strong perfect graph theorem by Chudnovsky, Robertson, Seymour, and Thomas in 2002.