Titanium hydride normally refers to the inorganic compound TiH₂ and related nonstoichiometric materials. It is commercially available as a stable grey/black powder, which is used as an additive in the production of Alnico sintered magnets, in the sintering of powdered metals, the production of metal foam, the production of powdered titanium metal and in pyrotechnics.

Also known as titanium–hydrogen alloy, it is an alloy of titanium, hydrogen, and possibly other elements. When hydrogen is the main alloying element, its content in the titanium hydride is between 0.02% and 4.0% by weight. Alloying elements intentionally added to modify the characteristics of titanium hydride include gallium, iron, vanadium, and aluminium.

In the commercial process for producing non-stoichiometric TiH_2−x, titanium metal sponge is treated with hydrogen gas at atmospheric pressure at between 300-500 °C. Absorption of hydrogen is exothermic and rapid, changing the color of the sponge grey/black. The brittle product is ground to a powder, which has a composition around TiH_1.95. In the laboratory, titanium hydride is produced by heating titanium powder under flowing hydrogen at 700 °C, the idealized equation being:

Other methods of producing titanium hydride include electrochemical and ball milling methods.

TiH_1.95 is unaffected by water and air.^{[citation needed]} It is slowly attacked by strong acids and is degraded by hydrofluoric and hot sulfuric acids. It reacts rapidly with oxidizing agents, this reactivity leading to the use of titanium hydride in pyrotechnics.

The material has been used to produce highly pure hydrogen, which is released upon heating the solid. Hydrogen release in TiH_~2 starts just above 400 °C but may not be complete until the melting point of titanium metal. Titanium tritide^{[broken anchor]} (Ti³H_x) has been proposed for long-term storage of tritium gas.

As TiH_x approaches stoichiometry, it adopts a distorted body-centered tetragonal structure, termed the ε-form with an axial ratio of less than 1. This composition is very unstable with respect to partial thermal decomposition, unless maintained under a pure hydrogen atmosphere. Otherwise, the composition rapidly decomposes at room temperature until an approximate composition of TiH_1.74 is reached.^{[citation needed]} This composition adopts the fluorite structure, and is termed the δ-form, and only very slowly thermally decomposing at room temperature until an approximate composition of TiH_1.47 is reached, at which point, inclusions of the hexagonal close packed α-form, which is the same form as pure titanium, begin to appear.

The evolution of the dihydride from titanium metal and hydrogen has been examined in some detail. α-Titanium has a hexagonal close packed (hcp) structure at room temperature. Hydrogen initially occupies tetrahedral interstitial sites in the titanium. As the H/Ti ratio approaches 2, the material adopts the β-form to a face centred cubic (fcc), δ-form, the H atoms eventually filling all the tetrahedral sites to give the limiting stoichiometry of TiH₂. The various phases are described in the table below.