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Niter

Niter or nitre is the mineral form of potassium nitrate, KNO3. It is a soft, white, highly soluble mineral found primarily in arid climates or cave deposits.

Potassium and other nitrates are of great importance for use in fertilizers and, historically, gunpowder. Much of the world's demand is now met by synthetically produced nitrates, though the natural mineral is still mined and is still of significant commercial value.

Historically, the term niter was not well differentiated from natron, both of which have been very vaguely defined but generally refer to compounds of sodium or potassium combined with carbonate or nitrate ions.

Niter is a colorless to white mineral crystallizing in the orthorhombic crystal system. It is the mineral form of potassium nitrate, KNO3, and is soft (Mohs hardness 2), highly soluble in water, and easily fusible. Its crystal structure resembles that of aragonite, with potassium replacing calcium and nitrate replacing carbonate. It occurs in the soils of arid regions and as massive encrustations and efflorescent growths on cavern walls and ceilings where solutions containing alkali potassium and nitrate seep into the openings. It occasionally occurs as prismatic acicular crystal groups, and individual crystals commonly show pseudohexagonal twinning on [110]. Niter and other nitrates can also form in association with deposits of guano and similar organic materials.

Niter as a term has been known since ancient times, although there is much historical confusion with natron (an impure sodium carbonate/bicarbonate), and not all of the ancient salts known by this name or similar names in the ancient world contained nitrate. The name is from the Ancient Greek νιτρων nitron from Ancient Egyptian netjeri, related to the Hebrew néter, for salt-derived ashes (their interrelationship is not clear).

The Hebrew néter may have been used as, or in conjunction, with soap, as implied by Jeremiah 2:22, "For though thou wash thee with niter, and take thee much soap..." However, it is not certain which substance (or substances) the Biblical "neter" refers to, with some suggesting sodium carbonate.

The Neo-Latin word for sodium, natrium, is derived from this same class of desert minerals called natron (French) through Spanish natrón from Greek νίτρον (nitron), derived from Ancient Egyptian netjeri, referring to the sodium carbonate salts occurring in the deserts of Egypt, not the nitratine (nitrated sodium salts) typically occurring in the deserts of Chile (classically known as "Chilean saltpeter" and variants of this term).[self-published source?]

A term (ἀφρόνιτρον, aphronitron or aphronitre) which translates as "foam of niter" was a regular purchase in a fourth-century AD series of financial accounts, and since it was expressed as being "for the baths" was probably used as soap.

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