Hubbry Logo
search
logo
Redox
Redox
current hub
2304385

Redox

logo
Community Hub0 Subscribers
Write something...
Be the first to start a discussion here.
Be the first to start a discussion here.
See all
Redox

Redox (/ˈrɛdɒks/ RED-oks, /ˈrdɒks/ REE-doks, reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. The oxidation and reduction processes occur simultaneously in the chemical reaction.

There are two classes of redox reactions:

"Redox" is a portmanteau of "reduction" and "oxidation." The term was first used in a 1928 article by Leonor Michaelis and Louis B. Flexner.

Oxidation is a process in which a substance loses electrons. Reduction is a process in which a substance gains electrons.

The processes of oxidation and reduction occur simultaneously and cannot occur independently. In redox processes, the reductant transfers electrons to the oxidant. Thus, in the reaction, the reductant or reducing agent loses electrons and is oxidized, and the oxidant or oxidizing agent gains electrons and is reduced. The pair of an oxidizing and reducing agent that is involved in a particular reaction is called a redox pair. A redox couple is a reducing species and its corresponding oxidizing form, e.g., Fe2+
/ Fe3+
.The oxidation alone and the reduction alone are each called a half-reaction because two half-reactions always occur together to form a whole reaction.

In electrochemical reactions the oxidation and reduction processes do occur simultaneously but are separated in space.

Oxidation originally implied a reaction with oxygen to form an oxide. Later, the term was expanded to encompass substances that accomplished chemical reactions similar to those of oxygen. Ultimately, the meaning was generalized to include all processes involving the loss of electrons or the increase in the oxidation state of a chemical species. Substances that have the ability to oxidize other substances (cause them to lose electrons) are said to be oxidative or oxidizing, and are known as oxidizing agents, oxidants, or oxidizers. The oxidant removes electrons from another substance, and is thus itself reduced. Because it "accepts" electrons, the oxidizing agent is also called an electron acceptor. Oxidants are usually chemical substances with elements in high oxidation states (e.g., N
2
O
4
, MnO
4
, CrO
3
, Cr
2
O2−
7
, OsO
4
), or else highly electronegative elements (e.g. O2, F2, Cl2, Br2, I2) that can gain extra electrons by oxidizing another substance.

Oxidizers are oxidants, but the term is mainly reserved for sources of oxygen, particularly in the context of explosions. Nitric acid is a strong oxidizer.

See all
User Avatar
No comments yet.