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Phosphor bronze

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Phosphor bronze

Phosphor bronze is a member of the family of copper alloys. It is composed of copper that is alloyed with 0.5–11% of tin and 0.01–0.35% phosphorus, and may contain other elements to confer specific properties (e.g. lead at 0.5–3.0% to form free-machining phosphor bronze). The tin increases the corrosion resistance and strength of the alloy, while the phosphorus increases its wear resistance and stiffness.

Phosphor bronze alloys are notable for their toughness, strength, low coefficient of friction, and fine grain. The phosphorus reduces the viscosity of the molten alloy, which makes it easier and cleaner to cast and reduces grain boundaries between crystallites. It was originally formulated by the Belgian Georges Montefiore-Levi and the German Karl Künzel.

Phosphor bronze is used for springs, bolts, bushings, bearings, electrical switches with moving or sliding parts, dental bridges, the reed components of organ pipes, ship's propellers, and various other products or assemblies where resistance to fatigue, wear, and corrosion are required.

Phosphor bronze comes in a wide array of standard alloys, including nonferrous spring alloys, free-machining phosphor bronze, and bearing bronze. The combination of good physical properties, fair electrical conductivity, and moderate cost make phosphor bronze wire (available in standard round, square, flat, and special formats) desirable for many springs, electrical contacts, and a wide variety of wire forms where the desired properties do not require the use of the more-expensive beryllium copper.

Phosphor bronze with 94.8% copper, 5% tin, and 0.2% phosphorus is also used in cryogenics. In this application, its combination of fair electrical conductivity and low thermal conductivity allows the making of electrical connections to devices at ultra-low temperatures without adding excessive heat.

Oxygen-free copper can be alloyed with phosphorus (CuOFP alloy) to better withstand oxidizing conditions. This alloy has application as thick corrosion-resistant overpack for spent nuclear fuel disposal in deep crystalline rocks.

Magnetic tape was first used to record computer data in 1951 on the Eckert-Mauchly UNIVAC I. The UNISERVO drive recording medium was a thin metal strip of 0.5-inch-wide (12.7-millimetre) nickel-plated phosphor bronze. The recording density was 128 characters per inch (198 micrometre/character) on eight tracks at a linear speed of 100 in/s (2.54 m/s), yielding a data rate of 12,800 characters per second. Of the eight tracks, six were data, one was a parity track, and one was a clock, or timing track. Making allowance for the empty space between tape blocks, the actual transfer rate was around 7,200 characters per second. A small reel of mylar tape provided separation from the metal tape and the read/write head.

Phosphor bronze is preferred over brass for cymbals because of its greater resilience, leading to broader tonal spectrum and greater sustain.

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