Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: dinitrogen (N₂), carbon monoxide (CO), dihydrogen (H₂), and carbon dioxide (CO₂). This is achieved by reacting the feedstock material at high temperatures (typically >700 °C), without combustion, via controlling the amount of oxygen and/or steam present in the reaction. The resulting gas mixture is called syngas (from synthesis gas) or producer gas and is itself a fuel due to the flammability of the H₂ and CO of which the gas is largely composed. Power can be derived from the subsequent combustion of the resultant gas, and is considered to be a source of renewable energy if the gasified compounds were obtained from biomass feedstock.

An advantage of gasification is that syngas can be more efficient than direct combustion of the original feedstock material because it can be combusted at higher temperatures so that the thermodynamic upper limit to the efficiency defined by Carnot's rule is higher. Syngas may also be used as the hydrogen source in fuel cells, however, the syngas produced by most gasification systems requires additional processing and reforming to remove the contaminants and other gases such as CO and CO₂ to be suitable for low-temperature fuel cell use, but high-temperature solid oxide fuel cells are capable of directly accepting mixtures of H₂, CO, CO₂, steam, and methane.

Syngas is most commonly burned directly in gas engines, used to produce methanol and hydrogen, or converted via the Fischer–Tropsch process into synthetic fuel. For some materials gasification can be an alternative to landfilling and incineration, resulting in lowered emissions of atmospheric pollutants such as methane and particulates. Some gasification processes aim at refining out corrosive ash elements such as chloride and potassium, allowing clean gas production from otherwise problematic feedstock material. Gasification of fossil fuels is currently widely used on industrial scales to generate electricity. Gasification can generate lower amounts of some pollutants as SO_x and NO_x than combustion.

Energy has been produced at industrial scale via gasification since the early 19th century. Initially coal and peat were gasified to produce town gas for lighting and cooking, with the first public street lighting installed in Pall Mall, London on January 28, 1807, spreading shortly to supply commercial gas lighting to most industrialized cities until the end of the 19th century when it was replaced with electrical lighting. Gasification and syngas continued to be used in blast furnaces and more significantly in the production of synthetic chemicals where it has been in use since the 1920s. The thousands of sites left toxic residue. Some sites have been remediated, while others are still polluted.

During both world wars, especially the World War II, the need for fuel produced by gasification reemerged due to the shortage of petroleum. Wood gas generators, called Gasogene or Gazogène, were used to power motor vehicles in Europe. By 1945 there were trucks, buses and agricultural machines that were powered by gasification. It is estimated that there were close to 9,000,000 vehicles running on producer gas all over the world.

Another example, the Xe than (literally, "coal car" in Vietnamese) was a minibus that has been converted to run on coal instead of gasoline. This modification regained popularity in Vietnam during the subsidy period, when gasoline was in short supply. Xe than became much less common during the Đổi Mới period, when gasoline became widely accessible again.

In a gasifier, the carbonaceous material undergoes several different processes:

In essence, a limited amount of oxygen or air is introduced into the reactor to allow some of the organic material to be "burned" to produce carbon dioxide and energy, which drives a second reaction that converts further organic material to hydrogen and additional carbon dioxide. Further reactions occur when the formed carbon monoxide and residual water from the organic material react to form methane and excess carbon dioxide (4CO + 2H₂O → CH₄ + 3CO₂). This third reaction occurs more abundantly in reactors that increase the residence time of the reactive gases and organic materials, as well as heat and pressure. Catalysts are used in more sophisticated reactors to improve reaction rates, thus moving the system closer to the reaction equilibrium for a fixed residence time.