Irving Langmuir
Irving Langmuir
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Irving Langmuir

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Irving Langmuir

Irving Langmuir (/ˈlæŋmjʊər/; January 31, 1881 – August 16, 1957) was an American chemist, physicist, and metallurgical engineer. He was awarded the Nobel Prize in Chemistry in 1932 for his work in surface chemistry.

Langmuir's most famous publication is the 1919 article "The Arrangement of Electrons in Atoms and Molecules" in which, building on Gilbert N. Lewis's cubical atom theory and Walther Kossel's chemical bonding theory, he outlined his "concentric theory of atomic structure". Langmuir became embroiled in a priority dispute with Lewis over this work; Langmuir's presentation skills were largely responsible for the popularization of the theory, although the credit for the theory itself belongs mostly to Lewis. While at General Electric from 1909 to 1950, Langmuir advanced several fields of physics and chemistry, inventing the gas-filled incandescent lamp and the hydrogen welding technique. The Langmuir Laboratory for Atmospheric Research near Socorro, New Mexico, was named in his honor, as was the American Chemical Society journal for surface science called Langmuir.

Irving Langmuir was born in Brooklyn, New York, on January 31, 1881. He was the third of the four children of Charles Langmuir and Sadie, née Comings. During his childhood, Langmuir's parents encouraged him to carefully observe nature and to keep a detailed record of his various observations. When Irving was eleven, it was discovered that he had poor eyesight. When this problem was corrected, details that had previously eluded him were revealed, and his interest in the complications of nature was heightened.

During his childhood, Langmuir was influenced by his older brother, Arthur Langmuir. Arthur was a research chemist who encouraged Irving to be curious about nature and how things work. Arthur helped Irving set up his first chemistry lab in the corner of his bedroom, and he was content to answer the myriad questions that Irving would pose. Langmuir's hobbies included mountaineering, skiing, piloting his own plane, and classical music. In addition to his professional interest in the politics of atomic energy, he was concerned about wilderness conservation.

Langmuir attended several schools and institutes in America and Paris (1892–1895) before graduating high school from Chestnut Hill Academy (1898), an elite private school located in the affluent Chestnut Hill area in Philadelphia. He graduated with a Bachelor of Science degree in metallurgical engineering (Met.E.) from the Columbia University School of Mines in 1903. He earned his PhD in 1906 under Friedrich Dolezalek [de] in Göttingen, for research done using the "Nernst glower", an electric lamp invented by Nernst. His doctoral thesis was entitled "On the Partial Recombination of Dissolved Gases During Cooling" (German: Ueber partielle Wiedervereinigung dissociierter Gase im Verlauf einer Abkühlung). He later did postgraduate work in chemistry. Langmuir then taught at Stevens Institute of Technology in Hoboken, New Jersey, until 1909, when he began working at the General Electric research laboratory (Schenectady, New York).

His initial contributions to science came from his study of light bulbs (a continuation of his PhD work). His first major development was the improvement of the diffusion pump, which ultimately led to the invention of the high-vacuum rectifier and amplifier tubes. A year later, he and colleague Lewi Tonks discovered that the lifetime of a tungsten filament could be greatly lengthened by filling the bulb with an inert gas, such as argon, the critical factor (overlooked by other researchers) being the need for extreme cleanliness in all stages of the process. He also discovered that twisting the filament into a tight coil improved its efficiency. These were important developments in the history of the incandescent light bulb. His work in surface chemistry began at this point, when he discovered that molecular hydrogen introduced into a tungsten-filament bulb dissociated into atomic hydrogen and formed a layer one atom thick on the surface of the bulb.

His assistant in vacuum tube research was his cousin William Comings White.

As he continued to study filaments in vacuum and different gas environments, he began to study the emission of charged particles from hot filaments (thermionic emission). He was one of the first scientists to work with plasmas, and he was the first to call these ionized gases by that name because they reminded him of blood plasma. Langmuir and Tonks discovered electron density waves in plasmas that are now known as Langmuir waves.

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