Lithium hexafluorostannate

Lithium hexafluorostannate
Names
	IUPAC name Dilithium hexafluorostannate(2-)
Identifiers
CAS Number	17029-16-2;
3D model (JSmol)	Interactive image;
ChemSpider	19949061;
	InChI InChI=1S/6FH.2Li.Sn/h61H;;;/q;;;;;;2+1;+4/p-6 Key: LDTWGZJNXIAELR-UHFFFAOYSA-H;
	SMILES [Li+].[Li+].F[Sn-2](F)(F)(F)(F)F;
Properties
Chemical formula	F6Li2Sn
Molar mass	246.58 g·mol−1
Appearance	White powder
Density	g/cm3
Solubility in water	Insoluble
Hazards
	GHS labelling:
Signal word	Danger
Hazard statements	H301, H315, H319, H335
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Lithium hexafluorostannate is an inorganic chemical compound with the chemical formula Li₂SnF₆.^[1]^[2]

Synthesis

The compound can be prepared by reacting ammonium hexachlorostannate, lithium carbonate, and fluorine gas at 400 °C,^[3] or by reacting lithium stannate with hydrofluoric acid.^[4]

Physical properties

The compound forms white crystals of the monoclinic system.^[5]^[6]

Lithium hexafluorostannate forms a dihydrate.^[7]

References

^ "Lithium Hexafluorostannate(IV)". American Elements. Retrieved 23 June 2024.
^ "Lithium (CAS Number 17029-16-2) : Strem Product Catalog". strem.com. Retrieved 23 June 2024.
^ Wilde, W.; Kolditz, L. (November 1987). "Über das thermische Verhalten einiger Lithium‐und Natriumhexafluorometallate(IV)". Zeitschrift für anorganische und allgemeine Chemie. 554 (11): 205–216. doi:10.1002/zaac.19875541127. Retrieved 25 June 2024.
^ Hebecker, Christoph; Hoppe, Rudolf (1 January 1966). "Neue Untersuchungen an komplexen Fluoriden von Zinn und Blei [1]". Naturwissenschaften (in German). 53 (4): 106–106. doi:10.1007/BF00601472. ISSN 1432-1904. Retrieved 25 June 2024.
^ Donnay, Joseph Désiré Hubert (1973). Crystal Data: Inorganic compounds. National Bureau of Standards. p. M-163. Retrieved 23 June 2024.
^ Haynes, William M. (9 June 2015). CRC Handbook of Chemistry and Physics, 96th Edition. CRC Press. p. 4-72. ISBN 978-1-4822-6097-7. Retrieved 23 June 2024.
^ Marseglia, E. A.; Brown, I. D. (15 June 1973). "Lithium hexafluorotitanate dihydrate and lithium hexafluorostannate dihydrate". Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry. 29 (6): 1352–1354. doi:10.1107/S0567740873004498. ISSN 0567-7408. Retrieved 23 June 2024.

[1] "Lithium Hexafluorostannate(IV)". American Elements. Retrieved 23 June 2024.

[2] "Lithium (CAS Number 17029-16-2) : Strem Product Catalog". strem.com. Retrieved 23 June 2024.

[3] Wilde, W.; Kolditz, L. (November 1987). "Über das thermische Verhalten einiger Lithium‐und Natriumhexafluorometallate(IV)". Zeitschrift für anorganische und allgemeine Chemie. 554 (11): 205–216. doi:10.1002/zaac.19875541127. Retrieved 25 June 2024.

[4] Hebecker, Christoph; Hoppe, Rudolf (1 January 1966). "Neue Untersuchungen an komplexen Fluoriden von Zinn und Blei [1]". Naturwissenschaften (in German). 53 (4): 106–106. doi:10.1007/BF00601472. ISSN 1432-1904. Retrieved 25 June 2024.

[5] Donnay, Joseph Désiré Hubert (1973). Crystal Data: Inorganic compounds. National Bureau of Standards. p. M-163. Retrieved 23 June 2024.

[6] Haynes, William M. (9 June 2015). CRC Handbook of Chemistry and Physics, 96th Edition. CRC Press. p. 4-72. ISBN 978-1-4822-6097-7. Retrieved 23 June 2024.

[7] Marseglia, E. A.; Brown, I. D. (15 June 1973). "Lithium hexafluorotitanate dihydrate and lithium hexafluorostannate dihydrate". Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry. 29 (6): 1352–1354. doi:10.1107/S0567740873004498. ISSN 0567-7408. Retrieved 23 June 2024.

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v t e Lithium compounds (list)
Inorganic (list)	Li₂ LiAlCl₄ Li_1+xAl_xGe_2−x(PO₄)₃ LiAlH₄ LiAlO₂ LiAl_1+xTi_2−x(PO₄)₃ LiAs LiAsF₆ Li₃AsO₄ LiAt Li[AuCl₄] LiB(C₂O₄)₂ LiB(C₆F₅)₄ LiWF₆ LiBF₄ LiBH₄ LiBO₂ LiB₃O₅ Li₂B₄O₇ LiAsF₆ Li₂SnF₆ Li₂TiF₆ Li₂ZrF₆ Li₂B₄O₇·5H₂O LiBSi₂ LiBr LiBr·2H₂O LiBrO LiBrO₂ LiBrO₃ LiBrO₄ Li₂C₂ LiCF₃SO₃ CH₃CH(OH)COOLi LiC₂H₂ClO₂ LiC₂H₃IO₂ Li(CH₃)₂N LiCHO₂ LiCH₃O LiC₂H₅O LiCN Li₂CN₂ LiCNO Li₂CO₃ Li₂C₂O₄ LiCl LiCl·H₂O LiClO LiFO LiClO₂ LiClO₃ LiClO₄ LiCoO₂ Li₂CrO₄ Li₂CrO₄·2H₂O Li₂Cr₂O₇ CsLiB₆O₁₀ LiD LiF Li₂F LiF₄Al Li₃F₆Al FLiBe LiFePO₄ FLiNaK LiGaH₄ Li₂GeF₆ Li₂GeO₃ LiGe₂(PO₄)₃ LiH LiH₂AsO₄ Li₂HAsO₄ LiHCO₃ Li₃H(CO₃)₂ LiH₂PO₃ LiH₂PO₄ LiHSO₃ LiHSO₄ LiHe LiI LiIO LiIO₂ LiIO₃ LiIO₄ Li₂IrO₃ Li₇La₃Zr₂O₁₂ LiMn₂O₄ Li₂MoO₄ Li_0.9Mo₆O₁₇ LiN₃ Li₃N LiNH₂ Li₂NH LiNO₂ LiNO₃ LiNO₃·H₂O Li₂N₂O₂ LiNa Li₂NaPO₃ LiNaNO₂ LiNbO₃ Li₂NbO₃ LiO⁻ LiO₂ LiO₃ Li₂O Li₂O₂ LiOH Li₃P LiPF₆ Li₃PO₄ Li₂HPO₃ Li₂HPO₄ Li₃PO₃ Li₃PO₄ Li₂Po Li₂PtO₃ Li₂RuO₃ Li₂S LiSCN LiSH LiSO₃F Li₂SO₃ Li₂SO₄ Li[SbF₆] Li₂Se Li₂SeO₃ Li₂SeO₄ LiSi Li₂SiF₆ Li₄SiO₄ Li₂SiO₃ Li₂Si₂O₅ LiTaO₃ Li₂Te LiTe₃ Li₂TeO₃ Li₂TeO₄ Li₂TiO₃ Li₄Ti₅O₁₂ LiTi₂(PO₄)₃ LiVO₃·2H₂O Li₃V₂(PO₄)₃ Li₂WO₄ LiYF₄ Neodymium-doped LiZr₂(PO₄)₃ Li₂ZrO₃
Organic (soaps)	Hemolithin (extraterrestrial protein) Organolithium reagents Gilman reagent CH₃COOLi C₄H₆LiNO₄ LiC₂F₆NO₄S₂ LiN(SiMe₃)₂ Li₃C₆H₅O₇ C₅H₅Li LiN(C₃H₇)₂ (C₆H₅)₂PLi C₁₈H₃₅LiO₃ C₆H₁₃Li C₄H₉Li CH₃CHLiCH₂CH₃ (CH₃)₃CLi C₁₂H₂₈BLi CH₃Li Li⁺C₁₀H−8 C₅H₁₁Li C₅H₃LiN₂O₄ C₆H₅Li LiC₂CH₃ LiO₂C(CH₂)₁₆CH₃ C₄H₅LiO₄ LiEt₃BH LiOC(CH₃)₃ C₉H₁₈LiN LiC₂H₃ Vinyllithium LiC ₁₁H ₂₃COO
Minerals	Amblygonite Berezanskite Brannockite Cryolithionite Darapiosite Darrellhenryite Elbaite Fluorine Elbaite Fluor-liddicoatite Emeleusite Eucryptite LiAlSiO₄ Faizievite Hectorite Hsianghualite Jadarite LiNaSiB₃O₇OH Keatite Li(AlSi₂O₆) Kunzite Lavinskyite Lepidolite Lithiophilite LiMnPO₄ Lithiophosphate Li₃PO₄ Manandonite Manganoneptunite Nambulite Neptunite Olympite Petalite LiAlSi₄O₁₀ Pezzottaite Cs(Be₂Li)Al₂Si₆O₁₈ Rossmanite Saliotite Sogdianite Spodumene LiAl(SiO₃)₂ Sugilite Tiptopite Tourmaline Triphylite LiFePO₄ Zabuyelite Li₂CO₃ Zektzerite Zinnwaldite
Hypothetical	Li_xBe_y HLiHe⁺ LiFHeO LiHe₂ (HeO)(LiF)₂ La_2⁄3–xLi_3xTiO₃He
Other Li-related	Aluminium–lithium alloys Heteroatom-promoted lateral lithiation LB buffer Lithium atom Lithium medication LiNi_xCo_yAl_zO₂ LiNi_xMn_yCo_zO₂ Lithium soap Lithium Triangle Lucifer yellow Magnesium–lithium alloys NASICON Environmentally friendly red light flare

Lithium hexafluorostannate

Lithium hexafluorostannate

Lithium hexafluorostannate

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Lithium hexafluorostannate

Synthesis

Physical properties

References