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Jadarite
View on Wikipedia| Jadarite | |
|---|---|
| General | |
| Category | Nesosilicate |
| Formula | LiNaSiB3O7(OH) |
| IMA symbol | Jad[1] |
| Strunz classification | 9.AJ.40 |
| Crystal system | Monoclinic |
| Crystal class | Prismatic (2/m) (same H-M symbol) |
| Space group | P21/n |
| Unit cell | a = 6.816(2), b = 13.789(2) c = 6.758(2) [Å]; β = 111.08(2)°; Z = 4 |
| Identification | |
| Formula mass | 219.46 g/mol |
| Color | White |
| Crystal habit | As microscopic anhedral grains |
| Fracture | Irregular to conchoidal |
| Tenacity | Brittle |
| Mohs scale hardness | 4 - 5 |
| Luster | Dull |
| Streak | White |
| Diaphaneity | Translucent to opaque |
| Specific gravity | 2.45 |
| Optical properties | Biaxial |
| Ultraviolet fluorescence | Weak pink to orange under UV |
| References | [2][3] |
Jadarite is a white, earthy monoclinic silicate mineral,[2] sodium lithium boron silicate hydroxide[4] with the chemical formula LiNaSiB3O7(OH).[2]
Discovery and classification
[edit]Jadarite was discovered in December 2004, in drill core from the Jadar Valley (Serbian: Јадар, Jadar, [jadaɾ]) in Serbia, from which it is named. The find was located 10 km (6.2 mi) southwest of the Cer mountain.[5] Findings were originally located in the villages of Jarebice and Slatina[6] and later in Draginac.[7]
Exploration geologists from Rio Tinto Exploration discovered the mineral as small rounded nodules in drill core, and were unable to match it with previously known minerals. Jadarite was confirmed as a new mineral after scientists at the Natural History Museum in London and the National Research Council of Canada conducted tests on it.[8][4]
Commercialization
[edit]The mineral discovery may be commercially important because the mineral contains lithium and boron, both relatively rare industrially important elements. Lithium is used for lithium batteries; boron is used in alloys, ceramic, glasses, and other applications.[6]
It was originally estimated that there are 200 million tons of the lithium borate ore, which would make the future Jadar mines one of the world's largest lithium deposits, supplying 10% of the world's demand for lithium.[9] Later on, United States Geological Survey concluded that lithium supply is closer to 1.51% of world's demand for lithium.[10][11] Of that, the Lower Jadar ore deposit has 114.5 million tons with an average content of the profitable components of 1.8% of lithium oxide and 13.1% of boron oxide.
In May 2017, Rio Tinto announced that the Jadar area has one of the largest lithium deposits in the world, lifting Lower Jadar's deposits to 136 million tons. The company stated that the ore deposit's mineral resource estimation confirmed the quality of the mineral. Extraction is scheduled to begin in 2023, with a projected underground exploitability of 50 years.
A jadarite processing plant next to the mines, which will process the ore into lithium carbonate and boric acid, is also planned. The prototype facility has been constructed by the scientists from Serbia, Australia, and USA, and is being tested in Melbourne. Testing includes the processing of the jadarite concentrate.[12]
On 25 July 2017 a memorandum was signed by Rio Tinto and the Government of Serbia, represented by the prime minister Ana Brnabić, which confirmed the year 2023 as the starting year, but also revealed that only now the working groups will be formed, studies will be conducted, and the process of issuing the permits will begin. The entire enterprise was named "Project Jadar".[13]
By 2020, future exploitation of jadarite and extraction of lithium instigated heated public and academic debate, especially after Rio Tinto's destruction of the Juukan Gorge in Australia. Environmentalists, local population and some scientists and professors are against it, citing usage of large quantities of water and various acids and other chemicals in the production process, which will contaminate 2,000 ha (4,900 acres) of fertile, arable land, salinize the underground waters and pollute the rivers of Jadar and Drina. Other experts claim that there is no reason not to trust the company's claim that it will follow the highest anti-pollution measures, that waters are safe and that the land is not that fertile after all. The company itself stated it will employ a new, experimental process which prevents pollution and which was tested 2,000 times in Australia.[14][15][16][17]
As of November 2021[update], construction of a mine has not begun.[18] Amidst the growing opposition, Rio Tinto's Serbian branch "Rio Sava Exploration" announced that construction of the mine will begin in 2022, to be finished in 2026. The company claimed it already invested $250 million in the project, with additional $200 million planned for 2021.[19] However, on 20 January 2022 Serbian prime minister Ana Brnabić announced the cancellation of the project, after mass protests organised by ecological organisations in Serbia.[20]
Kryptonite
[edit]Jadarite's chemical formula is similar but not identical to the formula ("sodium lithium boron silicate hydroxide with fluorine") invented for the fictional substance kryptonite in the 2006 film Superman Returns. This coincidence attracted mass-media attention in 2007, shortly after jadarite's discovery.[21][22][23][24]
The new mineral, unlike the fictional material in the movie, does not contain fluorine and does not have a green glow.[21]
References
[edit]- ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
- ^ a b c "Jadarite". mindat.org. 2007. Retrieved 2007-04-25.
- ^ Webmineral data
- ^ a b 'Kryptonite' discovered in mine. BBC News
- ^ Tanjug (25 May 2009), "Jadarski kriptonit nije na prodaju", Politika (in Serbian)
- ^ a b S.Trifunović (18 June 2009). "Jadarit još čeka" (in Serbian). Politika.
- ^ Aleksandar Apostolovski (17 April 2010). "Supermen oboren u Jadru" (in Serbian). Politika.
- ^ Whitfield, Pamela. LiNaSiB3O7(OH) a novel structure of the new borosilicate mineral jadarite determined from laboratory powder diffraction data Acta Crystallographica Section B Structural Science, International Union of Crystallography, DOI 10.1107/S0108768107010130, ISSN 0567-7408. (abstract).
- ^ S.P. (22 November 2016). ""Rio Tinto" otvorila info centar: Sve informacije o najčuvenijem projektu "Jadar"" (in Serbian). Blic.
- ^ Slađana Vukašinović (14 June 2021). "SRBIJA NEMA 10 ODSTO SVETSKIH ZALIHA LITIJUMA VEĆ 1,51 ODSTO" (in Serbian). Blic.
- ^ USGS (January 2021). "U.S. Geological Survey, Mineral Commodity Summaries" (PDF). USGS.
- ^ Aleksandar Mikavica (20 May 2017), "Jadarit - novo srpsko zlato", Politika (in Serbian), p. 13
- ^ "Proizvodnja litijuma od 2023.", Politika (in Serbian), p. 10, 25 July 2017
- ^ Gordana Grujić (20 December 2020). (Дез)информисање јавности о јадариту [Public (dis)information regarding jadarite]. Politika (in Serbian). p. 12.
- ^ Vesna Prodanović (20 December 2020). Рудник неће наудити ни води ни земљи [The mine will not harm neither water nor ground]. Politika (in Serbian). pp. 12–13.
- ^ Dragana Đorđević (20 December 2020). Угрожавањем реке Јадар угрожава се и Дрина [Endangering of Jadar river endangers Drina, too]. Politika (in Serbian). p. 13.
- ^ Balkan Green Energy News (6 November 2020). "Voices of discontent over Rio Tinto's jadarite mine investment in Serbia grow louder". Balkan Green Energy News.
- ^ "Rio Tinto's past casts a shadow over Serbia's hopes of a lithium revolution". the Guardian. 19 November 2021. Retrieved 19 November 2021.
- ^ "Изградња рудника за вађење јадарита почиње 2022. године" [Construction of the mine for jadarite extraction starts in 2022]. Politika (in Serbian). 4 March 2021. p. 10.
- ^ "Serbia scraps plans for Rio Tinto lithium mine after protests". TheGuardian.com. 21 January 2022.
- ^ a b "'Kryptonite' discovered in mine", BBC News, 24 Apr 2007
- ^ ABC
- ^ CNN
- ^ Washington Post
Jadarite
View on GrokipediaJadarite is a rare monoclinic borosilicate mineral with the chemical formula LiNaSiB₃O₇(OH), consisting of sodium, lithium, boron, silicon, oxygen, and hydrogen, and exhibiting a white, dull appearance, Mohs hardness of 4–5, and specific gravity of 2.45.[1][2] Discovered in 2004 by geologists from Rio Tinto during exploration drilling in Serbia's Jadar Valley and formally described in 2007, it represents the world's only known occurrence of this lithium- and boron-bearing mineral, which forms under highly specific geological conditions involving volcanic activity and sedimentation.[3][4] The Jadar deposit, where jadarite is the principal lithium source, holds significant potential for extracting high-grade lithium carbonate equivalent—estimated at up to 58,000 tons annually if mined—and boron compounds essential for glass, ceramics, and agriculture, positioning it as a key resource for lithium-ion battery production amid global electrification demands.[5] However, development of the proposed underground mine has been mired in controversy since 2019, including large-scale protests over potential water contamination, land expropriation, and biodiversity loss in the fertile Jadar Basin, leading to the Serbian government's revocation of Rio Tinto's exploitation permit in 2022 following environmental impact disputes.[6][7] Despite scientific validation of the mineral's composition and deposit viability through peer-reviewed analyses, the project's future remains uncertain due to ongoing legal challenges and local opposition prioritizing ecological preservation over economic gains from critical mineral supply.[8][1]
Physical and Chemical Properties
Composition and Crystal Structure
Jadarite has the chemical formula LiNaSiB₃O₇(OH), classifying it as a sodium-lithium borosilicate hydroxide mineral.[9][10] This composition features a unique combination of lithium, sodium, silicon, and three boron atoms coordinated within a silicate-hydroxide framework, with empirical analysis from electron microprobe confirming Li₂O 3.14 wt%, Na₂O 10.99 wt%, SiO₂ 13.80 wt%, B₂O₃ 55.80 wt%, and H₂O 14.80 wt% (calculated).[9] The mineral crystallizes in the monoclinic system with space group P2₁/c (or equivalent P2₁/n setting), unit cell parameters a = 6.818(2) Å, b = 13.794(2) Å, c = 6.756(2) Å, β = 111.10(2)°, and Z = 4.[10][9] The crystal structure, solved ab initio from laboratory powder X-ray diffraction data collected on samples from drill cores obtained in 2004, reveals a novel borosilicate framework where lithium ions are bonded to boron-oxygen polyhedra, distinguishing it from other known silicates. No single-crystal studies were feasible due to the sub-micrometer size of jadarite crystallites, embedded in a fine-grained matrix.[9] As the sole known natural occurrence of this structural type, jadarite represents a rare borosilicate with potential for selective lithium-boron associations in its lattice, as evidenced by the refined powder diffraction pattern matching uniquely to this phase.[9][10]Appearance and Diagnostic Features
Jadarite appears as white, earthy masses or microscopic anhedral grains with a dull to porcellanous luster. It is translucent in thin fragments but opaque in larger aggregates, exhibiting a white streak and brittle tenacity.[11][12]
The mineral possesses a Mohs hardness of 4–5 and a specific gravity of 2.45. It displays perfect cleavage on {001} and shows weak pink-orange fluorescence under both short-wave and long-wave ultraviolet radiation.[11][12]
Diagnostic identification relies on infrared spectroscopy, which reveals characteristic B–OH stretching vibrations at 3400–3600 cm⁻¹, distinguishing jadarite from other borosilicates. Powder X-ray diffraction confirms its monoclinic crystal structure with space group P2₁/c, featuring a unique layer of corner-sharing tetrahedra involving Li, Si, and B.[11][13]