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Rheometer

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Rheometer

A rheometer is a laboratory device used to measure the way in which a viscous fluid (a liquid, suspension or slurry) flows in response to applied forces. It is used for those fluids which cannot be defined by a single value of viscosity and therefore require more parameters to be set and measured than is the case for a viscometer. It measures the rheology of the fluid.

There are two distinctively different types of rheometers. Rheometers that control the applied shear stress or shear strain are called rotational or shear rheometers, whereas rheometers that apply extensional stress or extensional strain are extensional rheometers. Rotational or shear type rheometers are usually designed as either a native strain-controlled instrument (control and apply a user-defined shear strain which can then measure the resulting shear stress) or a native stress-controlled instrument (control and apply a user-defined shear stress and measure the resulting shear strain).

The word rheometer comes from the Greek, and means a device for measuring main flow. In the 19th century it was commonly used for devices to measure electric current, until the word was supplanted by galvanometer and ammeter. It was also used for the measurement of the flow of liquids, in medical practice (flow of blood) and in civil engineering (flow of water). This latter use persisted to the second half of the 20th century in some areas. Following the coining of the term rheology the word came to be applied to instruments for measuring the character rather than quantity of flow, and the other meanings are obsolete. (Principal Source: Oxford English Dictionary) The principle and working of rheometers is described in several texts.

Four basic shearing planes can be defined according to their geometry,

The various types of shear rheometers then use one or a combination of these geometries.

One example of a linear shear rheometer is the Goodyear linear skin rheometer, which is used to test cosmetic cream formulations, and for medical research purposes to quantify the elastic properties of tissue. The device works by attaching a linear probe to the surface of the tissue under test, a controlled cyclical force is applied, and the resultant shear force measured using a load cell. Displacement is measured using a Linear variable differential transformer (LVDT). Thus the basic stress–strain parameters are captured and analysed to derive the dynamic spring rate of the tissue under tests.

Liquid is forced through a tube of constant cross-section and precisely known dimensions under conditions of laminar flow. Either the flow-rate or the pressure drop are fixed and the other measured. Knowing the dimensions, the flow-rate can be converted into a value for the shear rate and the pressure drop into a value for the shear stress. Varying the pressure or flow allows a flow curve to be determined. When a relatively small amount of fluid is available for rheometric characterization, a microfluidic rheometer with embedded pressure sensors can be used to measure pressure drop for a controlled flow rate.

Capillary rheometers are especially advantageous for characterization of therapeutic protein solutions since it determines the ability to be syringed. Additionally, there is an inverse relationship between the rheometry and solution stability, as well as thermodynamic interactions.

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