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Synthetic oil

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Synthetic oil

Synthetic oil is a lubricant consisting of chemical compounds that are artificially modified or synthesised. Synthetic oil is used as a substitute for petroleum-refined oils when operating in extreme temperature, in metal stamping to provide environmental and other benefits, and to lubricate pendulum clocks. There are various types of synthetic oils. Advantages of using synthetic motor oils include better low-and high-temperature viscosity performance, better (higher) viscosity index (VI), and chemical and shear stability, while disadvantages are that synthetics are substantially more expensive (per volume) than mineral oils and have potential decomposition problems.

Synthetic oil lubricant comprises chemical compounds that are artificially modified or synthesised. Synthetic lubricants can be manufactured using chemically modified petroleum components rather than whole crude oil, but can also be synthesized from other raw materials. The base material, however, is still overwhelmingly crude oil that is distilled and then modified physically and chemically. The actual synthesis process and composition of additives is generally a commercial trade secret and will vary among producers.

Some synthetic oils are made from Group III base stock, some from Group IV while other synthetic oils may be a blend of the two. Mobil sued Castrol and Castrol prevailed in showing that their Group III base stock oil was changed enough that it qualified as full synthetic. Since then American Petroleum Institute (API) has removed all references to synthetic in their documentation regarding standards. "Full synthetic" is a marketing term and is not a measurable quality.

Poly-alpha-olefin (poly-α-olefin, PAO) is a non-polar polymer made by polymerizing an alpha-olefin. It is designated as API Group IV and is a 100% synthetic chemical compound. It is a specific type of olefin (organic) that is used as a base stock in the production of most synthetic lubricants. An alpha-olefin (or α-olefin) is an alkene where the carbon-carbon double bond starts at the α-carbon atom, i.e. the double bond is between the #1 and #2 carbons in the molecule.

Group V base oils are defined by API as any other type of oil other than mineral oils or PAO lubricants.

Esters are the most famous synthetics in Group V, which are 100% synthetic chemical compounds consisting of a carbonyl adjacent to an ether linkage. They are derived by reacting an oxoacid with a hydroxyl compound such as an alcohol or phenol. Esters are usually derived from an inorganic acid or organic acid in which at least one -OH (hydroxyl) group is replaced by an -O-alkyl (alkoxy) group, most commonly from carboxylic acids and alcohols. That is to say, esters are formed by condensing an acid with an alcohol.

Many chemically different "esters"—due to their polarity and usually excellent lubricity—are used for various reasons as either "additives" or "base stocks" for lubricants.

PAGs offer properties that include: high lubricity, polarity, low traction properties, high viscosity index, controlled quenching speeds, good temperature stability and low wear. They are available in both water soluble and insoluble forms.

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