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Base oils are used to manufacture products including lubricating greases, motor oil and metal processing fluids. Different products require different compositions and properties in the oil. One of the most important factors is the liquid’s viscosity at various temperatures. Whether or not a crude oil is suitable to be made into a base oil is determined by the concentration of base oil molecules as well as how easily these can be extracted.

Base oil is produced by means of refining crude oil. This means that crude oil is heated in order to separate various distillates from one another. During the heating process, light and heavy hydrocarbons are separated – the light ones can be refined to make petrol and other fuels, while the heavier ones are suitable for bitumen and base oils.[1]

There are large numbers of crude oils all around the world that are used to produce base oils. The most common one is a type of paraffinic crude oil, although there are also naphthenic crude oils that create products with better solubility and very good properties at low temperatures. By using hydrogenation technology, in which sulfur and aromatics are removed using hydrogen under high pressure, extremely pure base oils can be obtained, which are suitable when quality requirements are particularly stringent.[2]

Chemical substances – additives – are added to the base oil in order to meet the quality requirements for the end products in terms of, for example, friction and cleaning properties. Certain types of motor oils contain more than twenty percent additives.[3]

Production of mineral base oils

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Mineral base oils are first distilled from petroleum, and they comprise the 26-40 carbon fraction. Aromatic compounds are initially removed by solvent extraction: The distillation cut is mixed with an immiscible solvent such as phenol or furfural. This solvent preferentially dissolves aromatic compounds well, and the aromatic compounds are separated together with the solvent.[4]

Long chain alkanes form waxes that precipitate at relatively high temperature. They are removed either by crystallizing the waxes at low temperature, or they can be isomerized to branched alkanes. Various levels of hydrogenation are used thereafter to remove any remaining aromatic compounds and residual heteroatoms (in the form of nitrogen and sulfur compounds).[4]

Very generally, heteroatoms (as nitrogen and sulfur compounds) and aromatic compounds are removed as the base oil is hydrogenated from Group I through Group III. Reduction in heteroatoms reduces formation of acids when engine oils are exposed to the combustion environment, acids being corrosive to the engine. The reduction in aromatic compounds improves the oxidative stability of the oil, delaying formation of sludge and varnish. Yet both effects lead to the oil becoming less polar, making it a poorer solvent for both the additive package of an engine oil, as well as accumulated oxidation byproducts.[5]

API classifications

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In 1993, the American Petroleum Institute (API), categorized base oils into five main groups. Chemical and physical characteristics are defined for Groups I through III that reflect how refined they are, correlating in some way to high and low-temperature viscosity, oxidative stability, volatility, and so on. Group IV oils comprise polyalphaolefins by definition, and Group V oils are those that do not fit into any previous category. The intent of such categorization is to help ensure that engine oils retain performance when different base oils are used.[6]

Group I

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Originating in the 1930s, the least refined type which is produced by solvent refining. It usually consists of conventional petroleum base oils. An improvement to the refining process in the 1960s called hydro-treating made this base oil more stable, less reactive, and longer lasting than the earlier base oils.

API defines group I as "base stocks contain less than 90 percent saturates and/or greater than 0.03 percent sulfur and have a viscosity index greater than or equal to 80 and less than 120".

Group II

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Originating in 1971, a better grade of petroleum base oil, which may be partially produced by hydrocracking. All impurities will be removed from the oil leading to clearer color.

API defines group II as "base stocks contain greater than or equal to 90 percent saturates and less than or equal to 0.03 percent sulfur and have a viscosity index greater than or equal to 80 and less than 120".

Group III

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Originating in 1993, the most refined grade of petroleum base oil, since they are fully produced by hydrocracking, hydroisomerization, and hydrotreating,[7] which make these oils purer.

API defines group III as "base stocks contain greater than or equal to 90 percent saturates and less than or equal to 0.03 percent sulfur and have a viscosity index greater than or equal to 120".

Group IV

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Originating in 1974, consists of synthetic oils made of polyalphaolefins (PAO). Group IV base oils have a viscosity index range of 125 - 200.

Polyalphaolefin oils have a higher oxidative stability in extreme temperatures, and also have exceptionally low pour points, which makes them much more suitable for use in very cold weather (as found in northern Europe), as well as in very hot weather (as in Middle East).

Group V

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Originating in the 1940s, any type of base oil other than mentioned in the previously defined groups. Group V oils include alkylated naphthalenes (e.g., ExxonMobil Synesstic[8]) and esters.[9]

Unofficial Classifications

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Unofficial base oil classifications are not recognized by the American Petroleum Institute (API), however, they are widely used and marketed for motor oils and automatic transmission fluids.

Group II+

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Originating in the 1990s, a more refined grade of petroleum Group II base oil, produced by Hydrotreating. Group II+ base oils have a high viscosity index at the higher end of the API Group II range. The viscosity index is 110-115 minimum.

Group III+

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Originating in 2015, produced by a gas to liquids (GTL) process. Group III+ base oils have a Very High Viscosity Index (VHVI) at the higher end of the API Group III range. The viscosity index is 130-140 minimum.

Group VI

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Consists of synthetic oils made of Poly-internal-olefins (PIO).

Poly-internal-olefins (PIO) oils are similar to Poly-alpha-olefins (PAO), but use different chemicals in the synthesis process to obtain an even higher viscosity index. (VI)[10]

See also

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  • Mineral oil, a broader term that encompasses many base oils. This term usually refers to the domestic or medical use of oil refined from petroleum.

References

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[edit]
Revisions and contributorsEdit on WikipediaRead on Wikipedia

Base oil

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Base oil is the primary used in the of lubricants, typically constituting 70 to 99 percent of the final product, and serves as the carrier for additives that enhance performance properties such as , oxidation resistance, and wear protection. It is derived either from the refining of crude or through , and its quality directly influences the lubricant's ability to reduce , dissipate heat, and protect machinery in various applications. The () classifies base oils into five groups (I through V) based on key parameters including saturates content, levels, and (VI), which measures stability across temperature ranges. The classification system standardizes base oil quality to ensure interchangeability in formulations while maintaining standards. Group I base oils are solvent-refined mineral oils with less than 90% saturates and/or more than 0.03% and a VI of 80-120. Groups II and III are hydroprocessed mineral oils with at least 90% saturates and 0.03% or less , distinguished by VI (80-120 for II, greater than 120 for III), offering improved purity and often synthetic-like . Group IV consists of polyalphaolefins (PAOs), fully synthetic base oils, while Group V includes all others, such as esters and polyalkylene glycols. Production of mineral base oils (Groups I-III) involves crude oil and processes like solvent extraction or hydroprocessing to remove impurities. Synthetic base oils (Groups IV and V) are manufactured through for tailored properties. These methods have evolved since the system was established in 1993, with innovations like bio-based Group III oils from renewable feedstocks enhancing . Base oils are essential in applications including oils, industrial fluids, and greases, enabling efficient operation and equipment longevity. Higher-group base oils suit demanding conditions due to better stability, contributing to and lower emissions. The global base oil market remains dominated by mineral types but continues to shift toward synthetics (growing at ~3.7% CAGR through 2030) for performance-driven sectors like and electric vehicles, as of 2025.

Introduction

Definition and Composition

Base oil serves as the foundational component in lubricant formulations, typically comprising 70-99% of the final product and providing the essential properties such as , thermal stability, and load-carrying capacity. It consists primarily of hydrocarbons or other organic compounds that form a stable medium capable of reducing and between moving surfaces. In finished s, base oils are blended with additives to enhance specific performance characteristics, but the base oil itself determines the core physicochemical behavior of the lubricant. The chemical composition of base oils varies by source and type, but mineral base oils—derived from —predominantly feature s with carbon chain lengths ranging from C20 to C50, including paraffinic (straight- or branched-chain alkanes), naphthenic (cyclic alkanes), and smaller proportions of aromatic hydrocarbons (ring-structured compounds with alternating double bonds). Synthetic base oils, in contrast, are engineered for superior performance and include polyalphaolefins (PAOs), which are oligomers of linear alpha-olefins forming branched, saturated hydrocarbon chains, and s, produced by reacting organic acids with alcohols to yield polar molecules with ester linkages. Bio-based base oils, derived from renewable sources like oils or animal fats, primarily consist of triglycerides or fatty acid s, offering biodegradability while maintaining efficacy. These compositional differences influence properties like , oxidation resistance, and low-temperature flow. To achieve suitable purity and performance, base oils undergo basic refining steps such as hydrotreating, which uses and catalysts to remove impurities like , , and olefins, thereby improving stability and color, and dewaxing, which eliminates straight-chain paraffins to enhance low-temperature fluidity without significantly altering . These processes ensure the base oil meets standards for use in diverse applications. Base oils are classified under the (API) system into groups I through V, differentiated primarily by their level of saturation and refining severity.

Historical Development

The development of base oils began in the mid-19th century, as the discovery of resources provided a viable alternative to animal and vegetable fats for lubrication. In 1859, the drilling of the first commercial in , marked the onset of petroleum-based lubricants, which were distilled from crude oil residues to replace scarce and expensive used in machinery and lamps. By the late , the first patents for lubricating oils derived from emerged, enabling more reliable industrial applications as demand grew with the expansion of railroads and factories. In the early , refining techniques advanced to improve base oil quality and performance. During the , solvent processes were introduced, allowing manufacturers to extract impurities from crude oil distillates and produce cleaner paraffinic and naphthenic base stocks suitable for the burgeoning . The 1930s saw further innovation with solvent dewaxing methods, which removed crystals to lower pour points and enhance low-temperature fluidity, addressing limitations in earlier oils tied to crude oil . Post-World War II, synthetic base oils gained prominence; polyalphaolefins (PAOs), developed in the , were initially applied in jet engines for their superior stability and oxidation resistance, stemming from wartime research into high-performance lubricants. The 1970s energy crises accelerated the shift toward more efficient refining, with the introduction of hydrocracking technologies producing higher-quality base stocks like early Group II oils to optimize fuel economy amid oil shortages. Technological advancements in the led to the commercialization of severely hydrocracked Group III base oils, which offered greater purity and stability, extending life. Into the and , imperatives propelled the adoption of bio-based base oils derived from renewable feedstocks, minimizing environmental impact and promoting biodegradability amid growing concerns over depletion. By the 2020s, initiatives like the EU Green Deal have further accelerated the development of fully renewable base oils, with production scaling up for use in lubricants and sustainable applications, as of November 2025.

Sources and Production

Mineral Base Oils

Mineral base oils are primarily derived from crude petroleum, which is a complex of hydrocarbons obtained from natural underground reservoirs. The production process starts with the of crude oil in refineries. During , lighter fractions such as , , and diesel are separated at temperatures up to about °C under slightly above . The remaining heavier residuum is then subjected to at reduced pressures (around 10-50 mmHg) and temperatures of 350-450°C to isolate the lube distillates, which consist of hydrocarbons with 20-50 carbon atoms and serve as the primary feedstock for base oils. Following , the lube distillates undergo solvent extraction to remove aromatic compounds and other impurities that could affect stability and performance. Common solvents include or phenol, which selectively dissolve aromatics, leaving behind a purified stream rich in paraffinic and naphthenic hydrocarbons. This step is crucial for improving the oil's oxidation resistance and color. The is then hydrotreated, a catalytic process where gas reacts with the oil in the presence of catalysts like nickel-molybdenum at temperatures of 300-400°C and pressures of 30-100 bar. Hydrotreating saturates unsaturated bonds, removes , , and oxygen compounds, and further reduces aromatics to levels below 10%. To enhance low-temperature properties, the hydrotreated oil is dewaxed, typically using solvent-based methods with mixtures like methyl ethyl ketone and at low temperatures (-20 to -30°C) to precipitate waxes, or catalytic dewaxing via over catalysts at 300-350°C and 20-50 bar. The dewaxed oil is often finished with mild hydrofinishing to improve color, , and stability. Overall, only about 1-2% of the input crude oil is converted into finished base oil, as the majority is allocated to fuels and other products, making base oil production a low-yield but specialized segment of . Major facilities producing mineral base oils include ExxonMobil's Baytown complex in , which focuses on advanced hydrocracked stocks, and its Singapore refinery, which expanded in September 2025 to exceed 20,000 barrels per day of Group II products; Chevron operates significant plants at (25,000 barrels per day, with Group III+ production starting in Q4 2025), and . These operations underscore the capital-intensive nature of base oil refining, with costs driven by high-pressure equipment and usage. Mineral base oils offer economic advantages through significantly lower production costs—often 50-75% less than synthetics—due to the abundance of crude feedstocks, but their quality can vary based on the crude oil's composition, such as paraffinic versus naphthenic content, potentially leading to inconsistencies in viscosity index or purity without advanced refining. Mineral processes underpin API Groups I-III classifications.

Synthetic Base Oils

Synthetic base oils are chemically engineered hydrocarbons or compounds produced through precise synthesis processes, offering superior performance characteristics compared to mineral-derived oils. These base stocks are classified primarily under Group IV for polyalphaolefins (PAOs) and Group V for other synthetics like esters and polyalkylene glycols (PAGs), enabling tailored molecular structures for enhanced stability and efficiency. The most common type, polyalphaolefins (PAOs), are synthesized via the oligomerization of linear alpha-olefins such as 1-decene, typically at temperatures of 200-300°C using Ziegler-Natta catalysts like TiCl4 combined with alkylaluminum compounds. This controlled yields branched hydrocarbons with uniform chain lengths, followed by to saturate double bonds and improve oxidative stability. Esters, another key category, are produced by esterification reactions between alcohols and carboxylic acids; for instance, polyol esters result from polyhydric alcohols (e.g., or ) reacting with monobasic acids under acidic conditions, creating polar molecules with excellent and biodegradability. Polyalkylene glycols (PAGs) are formed through the anionic or of alkylene oxides like or with a starter alcohol or water, resulting in water-soluble or oil-miscible polymers suitable for specific hydraulic and compressor applications. Production of synthetic base oils occurs in specialized facilities employing advanced to maintain purity and consistency, such as Chevron Phillips Chemical's expanded plant in Beringen, , which doubled capacity in August 2025 to 120,000 metric tons of low-viscosity PAOs annually using decene-based processes. The higher production costs—often 2-4 times that of mineral oils—stem from the intricate, controlled synthesis requiring pure feedstocks and energy-intensive reactions, though this is offset by reduced in end-use applications. These base oils provide key benefits including a high often exceeding 120, low volatility (e.g., Noack volatility under 5% for many PAOs), and excellent /oxidative stability, making them ideal for high-performance uses like automotive engines, lubricants, and industrial gears where extreme temperatures and loads prevail. As of 2025, synthetic base oils account for approximately 10-12% of the global base oil market, with growth driven by (EV) demands for efficient, low-viscosity fluids in transmissions and batteries.

Bio-based and Other Base Oils

Bio-based base oils are derived from renewable feedstocks such as vegetable oils, animal fats, and , offering alternatives to traditional petroleum-derived products with lower environmental impact. Vegetable oils, including , , canola, and sunflower varieties, serve as primary sources, often modified into esters through to enhance compatibility for lubrication applications. High-oleic variants of these oils, developed through and in the , improve stability and yield for industrial use. Animal fats, such as and , provide another triglyceride-based feedstock, contributing significantly to renewable oil production; animal fats, along with waste oils and greases, accounted for 37% of feedstocks used in biomass-based diesel production in 2023. Algae-derived hydrocarbons, extracted from lipid-rich , represent an emerging source due to their high productivity and minimal land requirements. Production of bio-based base oils typically involves hydrotreatment processes adapted from mineral oil refining but applied to renewable triglycerides. The (HVO) process converts vegetable oils and animal fats into paraffinic hydrocarbons through hydrodeoxygenation, , and cracking, yielding high-purity base stocks suitable for lubricants. This method removes oxygen and saturates bonds, producing oils with properties akin to synthetic groups while maintaining renewability. advancements since the 2010s have targeted high-oleic crops like soybeans and sunflowers to increase content, reducing the need for extensive processing and improving overall efficiency. Other base oils from alternative sources include those produced via gas-to-liquids (GTL) technology and re-refined oils. GTL base oils are synthesized from using Fischer-Tropsch processes, which polymerize into long-chain hydrocarbons, resulting in highly pure, isoparaffinic products with excellent thermal stability. Recycled base oils, obtained through re-refining of used lubricating oils, undergo and to remove impurities, contaminants, and additives, producing base stocks comparable to I and II oils. These processes promote principles by diverting waste oil from landfills. Despite their sustainability benefits, bio-based base oils face challenges related to oxidative stability and cold flow properties. Vegetable and animal fat-derived oils are prone to oxidation due to unsaturated bonds, leading to and formation under high temperatures, which limits their longevity compared to mineral oils. Cold flow issues, such as high pour points from saturated fatty acids, can cause gelling in low-temperature environments, necessitating additives or genetic modifications for broader applicability. Regulatory frameworks, such as the USDA BioPreferred Program updated in the 2020s, address these by setting minimum biobased content standards (e.g., 25-82% for lubricants) and promoting federal procurement of certified products to encourage adoption. The bio-based base oil sector is experiencing robust growth, accounting for approximately 2-3% of the global base oil market as of 2025, fueled by carbon neutrality initiatives and stricter environmental regulations. This expansion is driven by demand for low-carbon alternatives in industries like automotive and , with biolubricants overall growing at a CAGR exceeding 13% through 2030. Many bio-based oils, particularly esters from sources, fall under API Group V classification due to their unique compositions outside standard hydrocarbon groups.

Classification Systems

API Group I

API Group I base oils represent the traditional category of mineral base stocks derived from crude oil, characterized by less than 90% saturates content and/or sulfur levels exceeding 0.03% by weight, with a viscosity index ranging from 80 to 120. These oils are the least refined among the mineral groups, retaining higher concentrations of aromatic hydrocarbons and impurities compared to more advanced categories. The classification is determined through analytical methods such as ASTM D2007 for measuring saturates and polar compounds, alongside sulfur content via ASTM D4294 and viscosity index per ASTM D2270. Production of Group I base oils primarily occurs in older refineries employing solvent extraction techniques to remove unwanted aromatics and impurities from vacuum distillates. Common processes include or phenol extraction to separate saturates from aromatics, followed by solvent dewaxing to control low-temperature performance and finishing steps like clay treating or mild hydrofinishing for color and stability improvement. These methods, developed in the mid-20th century, do not involve severe hydroprocessing, resulting in base stocks suitable for cost-effective manufacturing but with limitations in purity. Key properties of Group I base oils include moderate oxidation stability due to elevated aromatic content, which can promote sludge formation under prolonged heat exposure, and a pour point typically between -10°C and -20°C for common grades like 100N or 600N. They exhibit higher volatility and poorer response to antioxidants compared to hydroprocessed alternatives, though their aids in blending with additives. These base oils find primary applications in general industrial lubricants, such as hydraulic fluids, oils, and greases, where high-performance demands are moderate and is a priority. They also serve in some lower-tier oils and process oils, though their use in premium formulations is limited by stability constraints. Globally, Group I holds approximately 20% of the base oil as of 2023, reflecting a decline driven by shifts toward higher-quality groups amid environmental and performance regulations.

API Group II

API Group II base oils are hydroprocessed mineral oils characterized by greater than 90% saturates content, sulfur levels below 0.03%, and a ranging from 80 to 120. These specifications distinguish them from earlier mineral base oils by emphasizing higher purity and stability, achieved through advanced refining techniques rather than traditional solvent extraction alone. Production of Group II base oils involves mild hydrocracking and hydrotreating processes, where gas is applied under pressures typically between 1000 and 2000 psi to remove polar compounds, aromatics, and impurities like and . This hydroprocessing enhances the base stock's molecular structure by saturating unsaturated hydrocarbons and stabilizing the oil, resulting in a cleaner product compared to solvent-refined alternatives. These base oils exhibit improved and oxidative stability due to their low and high saturates content, along with reduced volatility that minimizes in high-temperature environments. Their pour point generally falls between -15°C and -30°C, enabling better low-temperature performance without excessive additives. Group II base oils are widely used in oils and hydraulic fluids, where their balanced properties support extended drain intervals and environmental compliance. They hold approximately 40% of the global base oil as of 2023, reflecting their role as a cost-effective upgrade from traditional mineral oils. Introduced in the early 1990s by the as a replacement for Group I base oils, they marked a shift toward hydroprocessed products to meet evolving performance demands.

API Group III

API Group III base oils represent a class of highly refined mineral oils produced through severe hydrocracking of feedstocks, meeting strict specifications of greater than 90% saturates, less than 0.03% content, and a (VI) exceeding 120. These characteristics distinguish them from lower API groups by providing enhanced purity and stability, achieved by breaking down complex molecules and reforming them into more desirable, branched structures. Building briefly on the milder hydrotreating processes used for API Group II, Group III production intensifies these steps to yield base stocks with synthetic-like attributes while remaining derived from crude oil. The manufacturing process for Group III base oils involves high-severity hydrocracking, typically conducted at temperatures between 350°C and 450°C and pressures of 1500 to 3000 psi, in the presence of and catalysts to remove impurities and saturate bonds. This is often followed by hydroisomerization or isodewaxing, which rearranges straight-chain paraffins into branched isomers to improve low-temperature fluidity without excessive formation. Such advanced converts lower-quality feeds, like gas oils, into premium base stocks suitable for demanding applications, with global production capacity exceeding 10 million metric tons annually as of 2025, reflecting significant expansions. As of 2025, expansions like ExxonMobil's addition of approximately 400,000 tons per year capacity at , continue to boost global supply. Key properties of Group III base oils include a VI range of 130 to 140, which ensures minimal change across wide temperature spans, and pour points as low as -40°C or better, enabling reliable performance in cold starts. They also offer superior oxidative stability compared to Group II, low volatility, and reduced to minimize deposit formation, positioning them as near-synthetic alternatives with cost advantages over fully synthesized options. These attributes make Group III oils ideal for formulations requiring longevity under high thermal stress. In applications, Group III base oils are widely used in high-performance oils, gear lubricants, and industrial fluids such as oils, where their stability supports extended drain intervals and emission system compatibility. By 2025, they are projected to hold about 16% of the global base oil market, driven by demand in and excess capacity enabling broader adoption in premium lubricants. A notable controversy surrounding Group III base oils emerged in the 1990s and early 2000s regarding their classification as "synthetic," particularly in claims. sued in 2000, arguing that Castrol's Syntec, based on hydroisomerized Group III stocks, misleadingly used the term without true from non-petroleum sources. The National Advertising Division ultimately ruled in Castrol's favor, accepting performance equivalence as sufficient for the label, which broadened industry use of "synthetic" for Group III products despite ongoing debates over the term's precision.

API Group IV

API Group IV base oils are polyalphaolefins (PAOs), fully synthetic hydrocarbons engineered through rather than . These base stocks are defined by the () as having greater than 90% saturates and less than 0.03% sulfur, but PAOs typically exceed these thresholds with over 99% saturates and zero sulfur content, alongside a (VI) of 120 to 150. They consist primarily of oligomers formed from linear alpha-olefins such as 1-decene, resulting in a uniform, branched isoparaffinic structure that ensures consistent performance. Production of PAOs begins with the of alpha-olefins, predominantly 1-decene, using either traditional cationic catalysts like (BF3) or advanced metallocene catalysts for greater control over molecular weight and branching. The resulting oligomers undergo to saturate any remaining double bonds and to separate grades, which range from low- options at 2 cSt to higher grades up to 100 cSt at 100°C. This process yields base oils with precise molecular architectures tailored for demanding applications. Key properties of Group IV PAOs include superior low-temperature fluidity, with pour points typically ranging from -50°C to -70°C, enabling reliable operation in cold environments, and high thermal stability evidenced by flash points above 250°C. These attributes, combined with excellent oxidative stability and low volatility, make PAOs ideal for extreme conditions where mineral-based oils would degrade. In applications, Group IV PAOs serve as primary base stocks in aviation lubricants, automotive synthetic engine oils, and premium industrial formulations, providing enhanced wear protection, reduced deposits, and extended drain intervals. Their use is particularly valued in high-performance scenarios, such as jet engines and heavy-duty vehicles, where broad temperature tolerance is critical. The global market for Group IV PAOs maintains a stable production capacity of approximately 750,000 metric tons per year, representing a key segment of synthetic base oils despite higher costs compared to mineral alternatives. Major producers include , with its SpectraSyn™ PAO line, and , which together dominate supply for high-end blending.

API Group V

API Group V base oils encompass all base stocks that do not qualify for Groups I through IV under the (API) classification system, including a diverse array of synthetic and specialty fluids such as esters, polyalkylene glycols (PAGs), silicones, and phosphate esters. Unlike the hydrocarbon-based groups, Group V oils exhibit variable levels of saturates and content, with no standardized thresholds for these parameters, allowing for a broad range of chemical compositions tailored to needs. This category overlaps with synthetic and bio-based production methods but is defined primarily by exclusion from the other groups rather than origin. Key types within Group V include diesters, such as adipate esters formed by reacting dicarboxylic acids with alcohols; polyol esters, produced from neopentyl polyols (e.g., or ) esterified with fatty acids; and alkylated naphthalenes, created by alkylating with linear alpha-olefins. These fluids are engineered for enhanced functionality, with diesters and esters providing polarity for better additive and , while alkylated naphthalenes offer superior thermal and oxidative stability. Group V base oils are characterized by high polarity, which enhances solubility of polar additives and improves compatibility in formulations, though this can sometimes lead to hydrolytic instability in moist environments. indices typically range from 100 to 200, providing good temperature stability across applications, but biodegradability varies—many esters exhibit high biodegradability suitable for environmental concerns, while others like silicones may pose challenges in disposal. These properties make Group V oils ideal for demanding conditions where standard hydrocarbons fall short. Applications of Group V base oils are niche, representing a small segment of the overall base oil market, and include compressor oils (often PAG-based for gas compressors), greases requiring high-temperature stability, and eco-friendly lubricants leveraging biodegradable esters. They are particularly valued in formulations needing enhanced solvency, such as in hydraulics or environmentally sensitive operations. Specifications for Group V are defined by the 1509 standard (Appendix E), which relies on ASTM analytical methods like D2007 for saturates and D4294 for but imposes no unified limits on or content, emphasizing performance-based qualification through interchange guidelines. This flexibility allows formulators to select Group V stocks based on end-use requirements rather than rigid chemical benchmarks.

Advanced and Unofficial Classifications

Group II+

Group II+ base oils constitute an unofficial enhancement of the Group II category, featuring a typically exceeding 110–120 and levels below 10 ppm, attained through intensified hydrotreating that further purifies the base stock beyond standard Group II specifications. These oils maintain the core characteristics of Group II—over 90% saturates and low —but achieve marginal improvements in purity and stability via proprietary refining techniques, positioning them as a bridge between conventional oils and higher groups. Production of Group II+ involves add-on processes to standard Group II manufacturing, such as wax or mild hydrocracking, often employing advanced hydroisomerization catalysts under high to rearrange paraffin molecules and minimize branching for better flow. Technologies like Chevron's ISODEWAXING® exemplify this approach, enabling the creation of clearer, more stable stocks from paraffinic crude distillates without shifting to full Group III severity. This results in base oils that are virtually sulfur-free (<6 ppm in some cases) while preserving the economic advantages of mineral refining. Key properties of Group II+ include enhanced cold flow performance, with pour points as low as -15°C to -18°C and improved cold cranking simulator viscosity (e.g., around 800 cP at -20°C for 100N grades), surpassing base Group II by reducing thickening in low temperatures. Oxidation resistance is also superior due to near-complete saturation (>99%) and minimal aromatics, leading to longer fluid life and reduced formation in oxidative environments. Additionally, lower NOACK volatility (e.g., 2–16% depending on grade) supports control in high-temperature applications. In applications, Group II+ excels in mid-tier passenger car motor oils (PCMO) and heavy-duty engine oils (HDMO), enabling formulations for SAE 5W-30 and similar multigrades with extended drain intervals and low-SAPS compatibility for emission systems. Marketed as "premium mineral" options, they provide a cost-effective alternative to synthetics for general automotive and industrial lubricants, balancing performance in wear protection and thermal stability. Adoption of Group II+ has grown since the 2010s, particularly in and , where it meets regional demands for efficient, low-volatility base stocks in modern engines without requiring API reclassification; it is widely industry-recognized for optimizing blends in high-volume production.

Group III+

Group III+ represents an advanced, unofficial subcategory within the API Group III classification, characterized by superior refinement levels that surpass standard Group III criteria. These base oils typically exhibit a exceeding 140, sulfur content below 5 ppm, and saturates greater than 99%, enabling exceptional purity and stability akin to higher synthetic groups. Production of Group III+ base oils involves deep hydroisomerization of wax feedstocks, such as slack waxes derived from refining processes, to achieve highly isoparaffinic structures. Chevron's ISODEWAXING technology, for instance, processes slack wax in a once-through manner to yield base oils with viscosity indices of 140 or higher without the need for recycling unconverted material. ExxonMobil's MWI wax isomerization process similarly converts paraffinic waxes into Group III+ stocks, optimizing yield and molecular uniformity through catalytic hydroisomerization and hydrofinishing. These oils demonstrate synthetic-equivalent properties, including pour points as low as -40°C for superior cold-weather flow and Noack volatility under 5% for reduced and emissions in high-temperature environments. Such attributes provide enhanced oxidative stability and low-temperature performance, bridging the gap between conventional mineral oils and polyalphaolefins. Group III+ base oils find primary applications in premium automotive lubricants, including high-performance engine oils for passenger vehicles and racing formulations that demand extended drain intervals and . They constitute approximately 10% of overall Group III production volume, driven by demand for cost-effective alternatives to true synthetics in top-tier blends. The category emerged in the early , building on Group III advancements, following a pivotal 1999 legal settlement in a between and that permitted hydrocracked oils to be marketed as "full synthetic" when supported by performance data, aligning with FTC guidelines on truthful advertising claims.

Group VI

Group VI is an unofficial, non-API classification sometimes used for polyinternalolefins (PIO), distinct from polyalphaolefins (PAO, Group IV). It was briefly referenced in European (ATIEL) guidelines around 2003 but became obsolete in 2010 as PIO production ceased, lacking widespread commercial adoption in finished lubricants. References to PIO are limited to industrial high-temperature lubricants or historical/obsolete classifications. Group VI remains a rare, non-standard category with no documented use in consumer engine oils.

Properties and Applications

Key Physical and Chemical Properties

Base oils are evaluated based on a suite of standardized physical and chemical properties that determine their suitability for formulation into lubricants and other products. These properties are measured using established protocols from organizations like , ensuring consistency and comparability across the industry. Key assessments focus on flow characteristics, thermal stability, compositional purity, and environmental persistence, which collectively influence the base oil's performance under various conditions. Physical properties primarily include , which measures the oil's resistance to flow and is typically reported as kinematic at 40°C and 100°C using ASTM D445. This standard involves timing the flow of a sample through a calibrated glass capillary under gravity, providing values in centistokes (cSt) that indicate the oil's grade and operational range. The (VI), calculated via ASTM D2270 from viscosities at 40°C and 100°C, quantifies the oil's resistance to change with ; higher VI values signify greater stability for applications involving fluctuations. , determined by ASTM D97, assesses the lowest at which the oil remains fluid after cooling, achieved by incrementally warming a chilled sample until it flows under specified conditions, which is critical for low- performance. , measured by ASTM D92's Cleveland open cup method, identifies the lowest at which oil vapors ignite when exposed to a , serving as an indicator of volatility and safety. Chemical properties encompass saturates content, analyzed through ASTM D2007's clay-gel adsorption chromatography or equivalent methods, which separates and quantifies paraffinic (saturates) from naphthenic and aromatic components to evaluate molecular stability. Sulfur content is quantified using ASTM D4294's energy-dispersive X-ray fluorescence spectrometry, providing precise measurements in weight percent that reflect the oil's potential for corrosion or emissions. Aromatics, often derived as the complement to saturates, influence solvency and oxidation tendencies but are not directly standardized in isolation. Volatility is gauged by the Noack test under ASTM D5800, where a sample is heated to 250°C under reduced pressure and the mass loss from evaporation is recorded as a percentage, indicating evaporative losses in high-temperature environments. Additional properties include oxidative stability, evaluated via the rotating bomb oxidation (RBOT) in ASTM D2272, which measures the time for oxygen pressure to drop by 25 psi in a pressurized, heated sample with and catalyst, highlighting resistance to degradation. Biodegradability is assessed using 301 protocols, such as the ready biodegradability with , tracking the percentage of carbon converted to CO2 over 28 days to determine environmental fate. These tests are essential for ensuring base oil compatibility with additives, as impurities like can interfere with chemical interactions, and industry trends are driving levels below 1 ppm to enhance performance and environmental compatibility. These properties play a foundational role in classifications by establishing baseline quality metrics.

Performance in Lubricants and Other Uses

Base oils play a pivotal role in performance by facilitating reduction through boundary mechanisms, where a of oil separates contacting surfaces under high loads and low speeds. In boundary conditions, polar additives in the base oil adsorb onto metal surfaces, forming protective layers that minimize direct metal-to-metal contact and reduce -induced . This is particularly effective in high-pressure applications like gears and bearings, where base oils with appropriate contribute to up to 50% lower rates compared to unlubricated conditions. Additionally, base oils enhance heat dissipation by conducting away from points, preventing overheating and thermal degradation in engines and machinery. High (VI) base oils further optimize performance by minimizing changes with variations, ensuring consistent film thickness across operating ranges from -40°C to 150°C. For instance, synthetic base oils with VI exceeding 150 maintain pumpability at low while providing robust film strength at high , reducing energy losses and extending equipment life in automotive and industrial settings. This stability is crucial for applications like transmissions, where fluctuations can otherwise lead to 20-30% drops in low-VI oils, compromising efficacy. In formulations, base oils enable synergies with additives, particularly dispersants, which keep particulates suspended to prevent buildup. Low-saturate base oils, such as those in Group I, offer better solvency for polar dispersants due to their higher aromatic content, allowing more effective dispersion of combustion byproducts in oils compared to highly saturated Group III oils that require additional co-solvents. This compatibility enhances overall stability, with additive treat rates as low as 7-10% achieving superior and longevity in modern low-emission s. In engine oil applications, Group IV polyalphaolefin (PAO) base oils exhibit key performance advantages over Group III hydrocracked (HC) base oils. PAO provides superior heat and oxidation stability, lower volatility, a wider operating temperature range, and stronger cleaning capabilities than HC. While HC base oils are suitable for general use, they may oxidize faster during extended drain intervals, potentially leading to deposit formation. Beyond lubricants, base oils serve in metalworking fluids as carriers for emulsions that cool and lubricate during , reducing and improving surface finishes in cutting operations. In hydraulic systems, they form the backbone of fluids that transmit power efficiently while lubricating pumps and valves, with mineral-based formulations providing shear stability under pressures up to 400 bar. Highly refined base oils also function as emollients in , where they soften skin and act as carriers for active ingredients in creams and lotions, offering non-comedogenic hydration without irritation. Emerging applications include electric vehicle (EV) battery coolants, where dielectric synthetic base oils like polyalphaolefins (PAOs) or gas-to-liquid (GTL) fluids enable , dissipating heat rapidly to support sub-10-minute charging while maintaining electrical insulation. Environmental challenges for base oils include limited biodegradability in mineral variants, which can persist in ecosystems if spilled, prompting shifts toward bio-based alternatives that degrade over 60% within 28 days per standards. Recycling efforts are advancing under 2025 circular economy initiatives, with re-refining technologies like converting used oils into high-quality base stocks, recovering up to 99% of input material and reducing virgin crude demand by millions of barrels annually. The recycled base oil market is projected to grow to $1.27 billion by 2030, driven by regulations favoring sustainable practices. Market trends reflect a shift toward low-viscosity base oils to enhance efficiency, particularly in 0W-16 formulations for passenger vehicles. These oils reduce internal friction by 1-2% over 0W-20 grades, improving fuel economy in line with global standards like API SN Plus, while maintaining chain wear protection through optimized additives. Adoption is accelerating in and , with the low-viscosity segment reaching $1.23 billion in 2024, fueled by automaker specifications for hybrid and downsized engines.

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