Ultraviolet

Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of the total electromagnetic radiation output from the Sun. It is also produced by electric arcs, Cherenkov radiation, and specialized lights, such as mercury-vapor lamps, tanning lamps, and black lights.

The photons of ultraviolet have greater energy than those of visible light, from about 3.1 to 12 electron volts, around the minimum energy required to ionize atoms. Although long-wavelength ultraviolet is not considered an ionizing radiation because its photons lack sufficient energy, it can induce chemical reactions and cause many substances to glow or fluoresce. Many practical applications, including chemical and biological effects, are derived from the way that UV radiation can interact with organic molecules. These interactions can involve exciting orbital electrons to higher energy states in molecules potentially breaking chemical bonds. In contrast, the main effect of longer wavelength radiation is to excite vibrational or rotational states of these molecules, increasing their temperature. Short-wave ultraviolet light is ionizing radiation. Consequently, short-wave UV damages DNA and sterilizes surfaces with which it comes into contact.

For humans, suntan and sunburn are familiar effects of exposure of the skin to UV, along with an increased risk of skin cancer. The amount of UV radiation produced by the Sun means that the Earth would not be able to sustain life on dry land if most of that light were not filtered out by the atmosphere. More energetic, shorter-wavelength "extreme" UV below 121 nm ionizes air so strongly that it is absorbed before it reaches the ground. However, UV (specifically, UVB) is also responsible for the formation of vitamin D in most land vertebrates, including humans. The UV spectrum, thus, has effects both beneficial and detrimental to life.

The lower wavelength limit of the visible spectrum is conventionally taken as 400 nm. Although ultraviolet rays are not generally visible to humans, 400 nm is not a sharp cutoff, with shorter and shorter wavelengths becoming less and less visible in this range. Insects, birds, and some mammals can see near-UV (NUV), i.e., somewhat shorter wavelengths than what humans can see.

Humans generally cannot use ultraviolet rays for vision. The lens of the human eye and surgically implanted lens produced since 1986 blocks most radiation in the near UV wavelength range of 300–400 nm; shorter wavelengths are blocked by the cornea. Humans also lack color receptor adaptations for ultraviolet rays. The photoreceptors of the retina are sensitive to near-UV but the lens does not focus this light, causing UV light bulbs to look fuzzy. People lacking a lens (a condition known as aphakia) perceive near-UV as whitish-blue or whitish-violet. Near-UV radiation is visible to insects, some mammals, and some birds. Birds have a fourth color receptor for ultraviolet rays; this, coupled with eye structures that transmit more UV gives smaller birds "true" UV vision.

"Ultraviolet" means "beyond violet" (from Latin ultra, "beyond"), violet being the color of the highest frequencies of visible light. Ultraviolet has a higher frequency (thus a shorter wavelength) than violet light.

UV radiation was discovered in February 1801 when the German physicist Johann Wilhelm Ritter observed that invisible rays just beyond the violet end of the visible spectrum darkened silver chloride-soaked paper more quickly than violet light itself. He announced the discovery in a very brief letter to the Annalen der Physik and later called them "(de-)oxidizing rays" (German: de-oxidierende Strahlen) to emphasize chemical reactivity and to distinguish them from "heat rays", discovered the previous year at the other end of the visible spectrum. The simpler term "chemical rays" was adopted soon afterwards, and remained popular throughout the 19th century, although some said that this radiation was entirely different from light (notably John William Draper, who named them "tithonic rays"). The terms "chemical rays" and "heat rays" were eventually dropped in favor of ultraviolet and infrared radiation, respectively. In 1878, the sterilizing effect of short-wavelength light by killing bacteria was discovered. By 1903, the most effective wavelengths were known to be around 250 nm. In 1960, the effect of ultraviolet radiation on DNA was established.

The discovery of the ultraviolet radiation with wavelengths below 200 nm, named "vacuum ultraviolet" because it is strongly absorbed by the oxygen in air, was made in 1893 by German physicist Victor Schumann. The division of UV into UVA, UVB, and UVC was decided "unanimously" by a committee of the Second International Congress on Light on August 17th, 1932, at the Castle of Christiansborg in Copenhagen.