Josiah Willard Gibbs

Josiah Willard Gibbs (/ɡɪbz/; February 11, 1839 – April 28, 1903) was an American mechanical engineer and scientist who made fundamental theoretical contributions to physics, chemistry, and mathematics. His work on the applications of thermodynamics was instrumental in transforming physical chemistry into a rigorous deductive science. Together with James Clerk Maxwell and Ludwig Boltzmann, he created statistical mechanics (a term that he coined), explaining the laws of thermodynamics as consequences of the statistical properties of ensembles of the possible states of a physical system composed of many particles. Gibbs also worked on the application of Maxwell's equations to problems in physical optics. As a mathematician, he created modern vector calculus (independently of the British scientist Oliver Heaviside, who carried out similar work during the same period) and described the Gibbs phenomenon in the theory of Fourier analysis.

In 1863, Yale University awarded Gibbs the first American doctorate in engineering. After a three-year sojourn in Europe, Gibbs spent the rest of his career at Yale, where he was a professor of mathematical physics from 1871 until his death in 1903. Working in relative isolation, he became the earliest theoretical scientist in the United States to earn an international reputation and was praised by Albert Einstein as "the greatest mind in American history". In 1901, Gibbs received what was then considered the highest honor awarded by the international scientific community, the Copley Medal of the Royal Society of London, "for his contributions to mathematical physics".

Commentators and biographers have remarked on the contrast between Gibbs's quiet, solitary life in turn of the century New England and the great international impact of his ideas. Though his work was almost entirely theoretical, the practical value of Gibbs's contributions became evident with the development of industrial chemistry during the first half of the 20th century. According to Robert A. Millikan, in pure science, Gibbs "did for statistical mechanics and thermodynamics what Laplace did for celestial mechanics and Maxwell did for electrodynamics, namely, made his field a well-nigh finished theoretical structure".

Gibbs was born in New Haven, Connecticut. He belonged to an old Yankee family that had produced distinguished American clergymen and academics since the 17th century. He was the fourth of five children and the only son of Josiah Willard Gibbs Sr., and his wife Mary Anna, née Van Cleve. On his father's side, he was descended from Samuel Willard, who served as acting President of Harvard College from 1701 to 1707. On his mother's side, one of his ancestors was the Rev. Jonathan Dickinson, the first president of the College of New Jersey (later Princeton University). Gibbs's given name, which he shared with his father and several other members of his extended family, derived from his ancestor Josiah Willard, who had been Secretary of the Province of Massachusetts Bay in the 18th century. His paternal grandmother, Mercy (Prescott) Gibbs, was the sister of Rebecca Minot Prescott Sherman, the wife of American founding father Roger Sherman; and he was the second cousin of Roger Sherman Baldwin, see the Amistad case below.

The elder Gibbs was generally known to his family and colleagues as "Josiah", while the son was called "Willard". Josiah Gibbs was a linguist and theologian who served as professor of sacred literature at Yale Divinity School from 1824 until his death in 1861. He is chiefly remembered today as the abolitionist who found an interpreter for the African passengers of the ship Amistad, allowing them to testify during the trial that followed their rebellion against being sold as slaves.

Willard Gibbs was educated at the Hopkins School and entered Yale College in 1854 at the age of 15. At Yale, Gibbs received prizes for excellence in mathematics and Latin, and he graduated in 1858, near the top of his class. He remained at Yale as a graduate student at the Sheffield Scientific School. At age 19, soon after his graduation from college, Gibbs was inducted into the Connecticut Academy of Arts and Sciences, a scholarly institution composed primarily of members of the Yale faculty.

Relatively few documents from the period survive and it is difficult to reconstruct the details of Gibbs's early career with precision. In the opinion of biographers, Gibbs's principal mentor and champion, both at Yale and in the Connecticut Academy, was probably the astronomer and mathematician Hubert Anson Newton, a leading authority on meteors, who remained Gibbs's lifelong friend and confidant. After the death of his father in 1861, Gibbs inherited enough money to make him financially independent.

Recurrent pulmonary trouble ailed the young Gibbs and his physicians were concerned that he might be susceptible to tuberculosis, which had killed his mother. He also suffered from astigmatism, whose treatment was then still largely unfamiliar to oculists, so that Gibbs had to diagnose himself and grind his own lenses. Though in later years he used glasses only for reading or other close work, Gibbs's delicate health and imperfect eyesight probably explain why he did not volunteer to fight in the Civil War of 1861–65. He was not conscripted and he remained at Yale for the duration of the war.