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Ilfochrome
View on WikipediaIlfochrome (also commonly known as Cibachrome) is a dye destruction positive-to-positive photographic process used for the reproduction of film transparencies on photographic paper. The prints are made on a dimensionally stable polyester base as opposed to traditional paper base. Since it uses 13 layers of azo dyes sealed in a polyester base, the print will not fade, discolour, or deteriorate for an extended time. Accelerated aging tests conducted by Henry Wilhelm rated the process as producing prints which, framed under glass, would last for 29 years before color shifts could be detected.[1] Characteristics of Ilfochrome prints are image clarity, color purity, and being an archival process able to produce critical accuracy to the original transparency.
History
[edit]Dr. Bela Gaspar created Gasparcolor, the dye bleach process upon which the Cibachrome process was originally based. It was considered vital to the war effort in the 1940s. Gaspar turned down many offers to sell the rights to his process and after he died, Paul Dreyfus, who was the chemist and technician for Gaspar, went to work for CIBA AG. When the patents ran out, he developed the process for Cibachrome. (Frozen Moments - Richard C. Miller) In the 1960s, the Cibachrome process was originally engineered by the Ciba Geigy Corporation of Switzerland. Ciba acquired Ilford in 1969,[2] and sold it to International Paper in 1989;[3] in 1992 [4] the product was renamed to "Ilfochrome". Colloquially, however the process is still referred to as "Cibachrome".
Before 2004 Ilford Ltd had two main manufacturing sites: Mobberley in the UK, where most traditional products were made, and Fribourg (Freiburg) in Switzerland, where Ilfochrome and Ilfocolor papers were made, as well as the inkjet papers. The UK side was subject to a management buyout, and the Swiss operation (Ilford Imaging Switzerland GmbH) was sold to the Japanese Oji paper group in 2005 and to Paradigm Global Partners LLP in 2010. The Swiss plant retained the Ilford name, while the UK operation was inaugurated under the name HARMAN, taken from the name of the founder of the original Britannia Works. Ilford Photo HARMAN Technology Ltd can still use the Ilford brandname and logo under license on previously existing products, while new products will carry the Harman name.
In 2012, Ilford announced its final production run of Ilfochrome Classic in response to declining market demand attributed to the expanding popularity of digital image making.
Advantages
[edit]The composition of the emulsion used in Ilfochrome prints is responsible for color purity, image clarity, and archival permanence. Azo dyes, which provide stable vivid colors, are embedded in the Ilfochrome emulsion and bleached out in processing. Since the dyes are in the emulsion rather than formed from couplers in the chemistry, the image is also much sharper and clearer because the dyes create an anti-light-scattering layer which keeps the image from being diffused when viewed. As the azo dyes are far more stable than chromogenic dyes, prints made by this process are of archival quality and galleries and art collectors report they do not fade in normal light.
Use directly in camera
[edit]An alternative use of Ilfochrome was for image capture directly inside a large format or ultra large format camera. This created a unique original positive photograph, in which the subject is reversed left-right unless a mirror or prism was used in front of the camera lens. A much longer exposure was required than with sheet films or plates designed for use in a camera. The procedure thus resembled the slow daguerreotype and ambrotype direct positive black-and-white processes used in the 1850s.[5][6]
Sources
[edit]- Coote, Jack H. (1978). The FOCALGUIDE to Cibachrome. London: Focal Press. ISBN 0-240-50981-1.
- Ilford Cibachrome-A. Switzerland: Ilford. MAN 03 GB.
- Peres, Michael R. (2007). "Silver Dye-Bleach Photography". Focal encyclopedia of photography (4th ed.). Focal Press. p. 709. ISBN 978-0-240-80740-9.
References
[edit]- ^ Wilhelm, Henry (2006). "A 15-Year History of Digital Printing Technology and Print Permanence in the Evolution of Digital Fine Art Photography - From 1991 to 2006" (PDF). Society for Imaging Science and Technology. Retrieved 17 April 2018.
- ^ Araujo, Anderson. "Ilford chronology". Ciba 1963. Retrieved 2011-11-13.
- ^ Araujo, Anderson. "Ilford chronology". Ciba 1989. Retrieved 2011-11-13.
- ^ Araujo, Anderson. "Ilford chronology". Ciba 1992. Retrieved 2011-11-13.
- ^ Annaratone, Marco. "Going Ultra: Ultra Large Format and In-Camera Ilfochrome" (PDF). Going Ultra. Archived from the original (PDF) on 2016-03-03. Retrieved 2008-02-25.
- ^ Evans, Glenn. "Shooting Cibachrome in-camera". Glennview. Retrieved 2008-02-25.
External links
[edit]Ilfochrome
View on GrokipediaHistory
Origins and development
Ilfochrome, originally known as Cibachrome, was invented in 1963 by Ciba Photochemie, a division of the Swiss chemical company Ciba-Geigy, as a positive-to-positive dye destruction process for producing high-fidelity color prints directly from transparencies.[7] This innovation built on earlier silver dye-bleach techniques pioneered in the 1930s by Hungarian chemist Béla Gázpar for his Gasparcolor process, which Ciba researchers adapted and refined for modern photographic applications.[8] The core advancement involved embedding stable polyazo dyes—known for their resistance to fading, humidity, and chemical degradation—directly into a pigmented cellulose tri-acetate base, eliminating the need for traditional gelatin emulsions and enabling exceptional image permanence estimated at over 100 years under proper storage conditions.[7] Key patents held by Ciba Photochemie covered the dye formulation and bleach chemistry, with early processing guidelines published by engineer E. Ch. Gehret in 1964, detailing the multi-step chemical treatment to selectively destroy unwanted dyes while preserving the image.[7] The process was initially commercialized under the name Cilchrome in 1964 through a collaborative agreement between Ciba, the British firm Ilford, and Lumière, aimed at exchanging research and jointly marketing the materials across Europe.[2] Targeted at professional photographers and fine art reproducers, it addressed the demand for vibrant, archival-quality enlargements from color slides, offering superior color saturation and detail compared to conventional chromogenic prints of the era.[7] The P-7A process, dating from 1964, was first used commercially in 1967 in Switzerland and Germany, simplifying the chemistry to six solutions and a 36-minute cycle, which facilitated adoption in commercial labs.[9] Early technical specifications emphasized accessibility for darkroom use, with print materials available in sheet formats ranging from 4x5 inches to a maximum of 16x20 inches, suitable for exhibition-scale reproductions.[7] Processing required standard darkroom equipment, including amber safelights, temperature-controlled trays or motorized drums for even chemical agitation, and high-intensity halogen or tungsten lamps for exposure, typically necessitating a dedicated space to manage the acidic bleach solutions safely.[7] These features positioned Cibachrome as a premium tool for professionals seeking museum-grade outputs from 35mm or medium-format transparencies.[10]Acquisition, renaming, and discontinuation
In 1989, Ciba-Geigy sold Ilford to the International Paper Corporation, severing its direct involvement with the company and its products.[11] As a result, in early 1992, Ilford rebranded the material from Cibachrome to Ilfochrome Classic to align the name with its own portfolio, a change officially announced at the Photo Marketing Association (PMA) show in Las Vegas.[11] This rebranding reflected Ilford's full ownership and control over the dye-destruction printing process, which had originated from the earlier Ciba-Ilford partnership.[12] Following the rebranding, production of Ilfochrome continued at facilities including the established plant in Marly, Switzerland—built by Ciba in 1963 for initial Cibachrome output—operated by Ilford Imaging Switzerland after the separation of Swiss operations in 2005, as well as earlier UK operations.[11] During this period, formats were expanded, offering paper and film up to 40x50 inches to meet professional demands for large-scale prints from transparencies.[13] These developments maintained Ilfochrome's position as a premium positive-to-positive medium through the 1990s and 2000s, even as digital technologies began to emerge.[12] By the early 2010s, declining demand for analog color printing materials, driven by the rise of digital imaging and inkjet alternatives, prompted Ilford Imaging Switzerland to reassess production.[11] In 2011, the company announced the discontinuation of Ilfochrome Classic, citing unsustainable market conditions, and committed to a final production run in 2012 to fulfill outstanding orders.[11] Materials remained available through the end of 2012, with remaining inventory fully depleted by 2013, marking the end of commercial production for the process following the bankruptcy of Ilford Imaging Switzerland in 2013.[12]Technical process
Chemical principles
Ilfochrome, also known as Cibachrome prior to 1991, employs a dye destruction or dye bleach process that relies on pre-embedded azo dyes within a multi-layer emulsion structure to produce positive images directly from color transparencies.[14] The material consists of three superimposed emulsion layers, each containing silver halide salts sensitive to specific wavelengths—blue for the yellow dye layer, green for the magenta dye layer, and red for the cyan dye layer—along with the corresponding azo dyes integrated during manufacturing.[15] Upon exposure, light activates the silver halides in proportion to the intensity of each color channel, and subsequent black-and-white development converts these halides to metallic silver grains solely in the exposed areas, without the color coupling reactions typical of chromogenic processes.[3] This metallic silver then acts as a catalyst during the bleaching step, selectively destroying the overlying azo dyes to form the positive image, where unexposed areas retain their full dye density.[16] The core of the process is the catalytic dye bleaching mechanism, where the developed silver grains facilitate the reduction of azo dyes (-N=N-) to colorless, water-soluble leuco compounds through oxidation-reduction reactions in an acidic environment.[3] For the cyan and magenta layers, potassium ferricyanide serves as the primary oxidizing agent in the bleach bath, converting the silver to silver bromide while enabling dye destruction around each grain, creating a colorless halo that merges to form clear image areas.[14] The yellow layer requires a distinct approach due to its dye's differing reactivity, employing thiourea in an acidic solution to achieve selective bleaching, as thiourea acts as a reducing agent that targets the azo bond without affecting the other layers.[14] Following bleaching, a fixer removes residual silver halides and compounds, leaving the unbleached dyes intact to render the final image.[15] Unlike traditional gelatin-emulsified papers, Ilfochrome uses a dimensionally stable base, such as polyester or cellulose triacetate, which encapsulates the 13 layers—including emulsions, dyes, and protective overcoats—providing resistance to environmental degradation and ensuring the positive-to-positive reversal without needing an internegative. Early versions used cellulose triacetate, while later materials employed polyester for enhanced dimensional stability.[3][14] This base material, often voided polyester with microbubbles for enhanced opacity and reflectance, supports the direct transfer of transparency details while minimizing distortion during processing.[14] The azo dyes' inherent stability stems from their chemical structure, which resists fading better than chromogenic dyes formed in situ, contributing to the process's reputation for archival quality.[17]Step-by-step printing procedure
The Ilfochrome printing process begins with careful preparation to handle the light-sensitive polyester-based paper, which must be loaded into processing equipment in total darkness to prevent unintended exposure.[18] The emulsion side of the paper, identifiable by its glossy texture and slight tackiness when touched gently, faces upward during exposure and inward during drum processing; improper orientation can result in reversed or fogged images.[7] Use inert plastic trays, drums, or tubes for all steps, as the chemicals are corrosive to metal surfaces.[18] Exposure involves contact printing a color transparency directly onto the Ilfochrome paper or using an enlarger for projected printing, typically with a diffuse light source like halogen or tungsten lamps to ensure even illumination.[18] Place the transparency emulsion-to-emulsion with the paper in a contact printing frame for maximum sharpness, or secure it in the enlarger carrier; adjust exposure time based on test strips to achieve the desired density.[7] Color balance is controlled using gelatin filters (e.g., cyan, magenta, yellow) in the enlarger head, with initial filtration often starting at 50M 40Y for neutral transparencies, fine-tuned through iterative test exposures.[18] Following exposure, the processing sequence employs the P-30 chemistry kit in a three-bath dye-destruction method, where the first developer forms a silver image in the exposed areas to protect underlying dyes, and subsequent steps remove silver and unmasked dyes.[18] At a standard temperature of 20-25°C (68-77°F), agitate continuously in a rotating drum or tray; typical times are as follows:| Step | Solution | Time (minutes) | Notes |
|---|---|---|---|
| Pre-soak (optional) | Water | 0.5 | At 29°C for large prints to ensure even wetting.[18] |
| Development | P-30 Developer A/B | 2-3 | Forms silver image; shorter at higher temperatures (e.g., 2 min at 29°C).[7] |
| Rinse | Water | 0.5 | Brief stop bath to halt development.[18] |
| Bleaching | P-30 Bleach | 3 | Destroys dyes in exposed areas via oxidation; agitate vigorously.[7] |
| Fixing | P-30 Fixer | 3 | Removes remaining silver halides; equal time to bleach for balance.[18] |
| Final Wash | Running water | 3-5 | Thorough rinsing to remove residues; use water at 20-30°C.[7] |
