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Elgiloy
Elgiloy
Elgiloy
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Elgiloy (Co-Cr-Ni Alloy) is a "super-alloy" consisting of 39-41% cobalt, 19-21% chromium, 14-16% nickel, 11.3-20.5% iron, 6-8% molybdenum, 1.5-2.5% manganese and 0.15% max. carbon.

It is used to make springs that are corrosion resistant and exhibit high strength, ductility, and good fatigue life. These same properties led to it being used for control cables in the Lockheed SR-71 Blackbird airplane, as they needed to cope with repeated stretching and contracting.[1]

Elgiloy meets specifications AMS 5876, AMS 5833, and UNS R30003.

Due to its chemical composition, Elgiloy is highly resistant to sulfide stress corrosion cracking and pitting, and can operate at temperatures up to 454 °C.

Elgiloy is a trade name for this super alloy. Phynox is another trade name for the same super alloy.

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Elgiloy

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Elgiloy is a non-magnetic, -based composed primarily of 39-41% , 19-21% , 14-16% , and 6-8% , with iron as and minor additions of , , carbon, , , and sulfur. Developed in the late 1940s by as a corrosion-resistant material for watch springs intended to have an "infinite lifespan," it was introduced to address the failure of timepieces in harsh wartime environments. This exhibits exceptional mechanical properties, including high tensile strength ranging from 220-290 (1515-2000 MPa) in spring temper condition, a modulus of elasticity of 32.0 x 10³ (190 GPa) at , and outstanding resistance, making it suitable for demanding applications under cyclic loading. Elgiloy demonstrates superior resistance in diverse environments, such as , sulfides, and elevated temperatures up to 850°F (454°C), while maintaining and resistance to pitting, , and stress cracking. Its of 0.300 lb/in³ (8.30 g/cm³) and operational range from -300°F to 850°F (-184°C to 454°C) further enhance its versatility across extreme conditions. Elgiloy is available in various forms, including wire (from 0.006" to 0.625" diameter), strip (0.0015" to 0.075" thickness), and bar, conforming to standards such as AMS 5833, ASTM F1058, and ISO 5832-7. It finds widespread use in industries requiring high-performance materials, including medical devices (such as implants, orthodontic wires, and surgical instruments), aerospace and defense (for springs, seals, and torsion bars), and gas (in corrosive subsurface environments), and . Over nearly eight decades since its introduction in 1947, Elgiloy has evolved from a watchmaking innovation to a critical alloy in modern engineering, prized for its reliability in biocompatible and high-stress applications.

History and Development

Invention and Early Research

The development of Elgiloy was initiated in the mid-1940s by the , shortly after , in response to widespread complaints from servicemen about corrosion in watch springs exposed to harsh environmental conditions during the war. Engineers at the company sought a durable, non-corroding specifically for precision timepieces, where traditional springs often failed due to and degradation, compromising reliability in humid, saline, and tropical settings. Over the course of four years of intensive research in collaboration with the , the Elgin team formulated Elgiloy around 1947 as a cobalt-based designed to provide infinite-lifespan watch springs resistant to . This innovation addressed the core need for a material that maintained structural integrity without corrosion, even under prolonged exposure to moisture and salts, marking a significant advancement in horological materials. Initial applications were confined to the horology industry, where the alloy was integrated into mainsprings to eliminate rust-related failures and enhance the longevity of Elgin's precision watches.

Commercialization and Milestones

Elgiloy was first commercialized in 1947 by the Elgin National Watch Company as a corrosion-resistant alloy specifically developed for watch springs and other components, addressing durability issues in harsh environments reported by servicemen after World War II. This debut marked a significant advancement in materials for precision timepieces, with the alloy quickly gaining recognition for its non-magnetic properties and extended lifespan. In the following decades, particularly during the and , Elgiloy saw broader adoption in and sectors, driven by Cold War-era demands for high-performance, reliable materials in extreme conditions. The alloy's expansion beyond horology was facilitated by its proven resilience, leading to increased production scales to meet industrial needs. By the , the company underwent significant evolution, with the Elgin facility acquired in 1988 by Combined Metals, which rebranded operations as Elgiloy Specialty Metals and initiated expansions into additional markets. This period also saw facility growth in , enhancing capabilities for producing precision strip, wire, and foil forms to support diverse applications. Key milestones include the 1988 expansion that broadened the product line to over 125 high-performance alloys, encompassing , , and other specialty metals, thereby solidifying Elgiloy's role as a leader in processing. In 1989, further into and oil & gas sectors was achieved following processes, reflecting sustained growth in critical industries. The alloy's enduring legacy was celebrated with its 75th anniversary in , highlighting seventy-five years of innovation from its origins in watchmaking to global industrial use.

Composition and Structure

Chemical Composition

Elgiloy is a cobalt-based with a precisely defined that contributes to its exceptional performance characteristics. The nominal elemental breakdown includes 39-41% as the primary , 19-21% , 14-16% , 11.25-20.5% iron as the balance, 6-8% , 1.5-2.5% , a maximum of 0.15% carbon, and trace amounts of other elements such as up to 1.2% , 0.1% , 0.015% , and 0.015% . This composition adheres to several international standards, including UNS R30003, ASTM F1058, and AMS 5876, ensuring consistency in and application. Equivalent trade names for the include Phynox (commonly used in ), Conichrome, Nivaflex, and the designation Co40CrNiMo or 3J21 in certain industrial contexts. Key alloying elements play specific roles in enhancing the material's properties: serves as the base, providing foundational strength and resistance; imparts oxidation and general resistance; and improves resistance to pitting and localized in aggressive environments.

Microstructural Features

Elgiloy exhibits a predominantly austenitic face-centered cubic (FCC) matrix, stabilized by its high and contents, which promote the gamma phase at both room and elevated temperatures. This FCC structure provides the alloy with inherent and resistance to deformation-induced phase transformations under standard conditions. In the solution-treated or annealed state, the microstructure consists of a homogeneous, fine-grained FCC matrix with no detectable magnetic phases, ensuring the remains non-magnetic for applications requiring and minimal interference in magnetic fields. Potential carbide precipitates, primarily M23C6 types involving and , can form within the FCC matrix during prolonged high-temperature aging above °C, appearing as coarse particles that influence long-term microstructural stability. These precipitates arise from the of carbon and alloying elements in the matrix, but they are minimal or absent in typical processing conditions focused on or moderate aging. The content plays a key role in alloying effects on the microstructure by contributing to and stabilizing transformation pathways, such as the formation of low-temperature ε-hexagonal close-packed (HCP) phases during aging, which enhances overall without inducing . Cold working refines the grain structure significantly, typically reducing grain sizes to around 2-3 μm through deformation mechanisms that introduce a high of low-angle boundaries and annealing twins in subsequent stabilization treatments. In work-hardened states, the FCC matrix develops networks of deformation twins and thin ε-HCP platelets, which contribute to strain hardening without compromising the alloy's performance. This refined microstructure, achieved via reductions up to 70%, results in a high proportion of high-angle boundaries (over 98%) after heat stabilization at approximately 520°C, promoting uniform deformation and enhanced mechanical reliability.

Physical Properties

Density and Thermal Characteristics

Elgiloy, a cobalt-based , exhibits a of 8.30 g/cm³ at , which remains stable across a broad temperature range owing to its high cobalt content that contributes to consistent mass-volume characteristics in demanding environments. This value supports its use in precision components where weight predictability is essential, such as in medical implants and springs. The alloy's is approximately 1427°C (2601°F), reflecting its robust high-temperature stability derived from the synergistic effects of , , and in the composition. Elgiloy demonstrates moderate thermal conductivity of 12.5 W/m·K, enabling efficient heat dissipation in applications exposed to thermal gradients without excessive energy loss. The coefficient of for Elgiloy is 15.2 × 10^{-6}/°C over the range of 20–300°C and a mean of 15.17 × 10^{-6}/°C from 0–500°C, which allows dimensional stability in components subjected to temperature fluctuations. This property, combined with its capacity for continuous service up to 454°C (850°F), makes Elgiloy suitable for high-temperature applications like components and cryogenic seals, where thermal cycling does not compromise structural integrity.

Electrical and Magnetic Properties

Elgiloy, a , is characterized by its non-magnetic nature, primarily due to its austenitic microstructure that inhibits ferromagnetic ordering. The alloy's relative magnetic permeability is approximately 1.0004, rendering it effectively non-magnetic for practical purposes across a wide range of conditions. This property arises from the stable austenitic matrix, which resists phase transformations that could induce magnetism. Studies using superconducting quantum interference device (SQUID) magnetometry on as-drawn and heat-treated Elgiloy wires confirm its paramagnetic behavior, with no evidence of macroscopic even at cryogenic temperatures. Low-temperature further reveals only submicroscopic ferromagnetic clusters within the matrix, which do not compromise the alloy's overall non-magnetic profile. Electrically, Elgiloy demonstrates moderate resistivity of 99.6 μΩ·cm (or 39.2 μΩ·in) at 20°C (70°F) in the annealed condition, positioning it as a poor conductor relative to pure metals like . Cold working induces a slight increase in resistivity due to defect introduction, enhancing its utility in scenarios demanding low electrical conductivity without significant magnetic interference.

Mechanical Properties

Strength and Ductility

Elgiloy exhibits exceptional (UTS) in its spring temper + aged condition, typically ranging from 260 to 330 (1790 to 2275 MPa), achieved through a of and subsequent aging . This high strength makes it suitable for demanding spring applications where load-bearing capacity is critical. Without additional after cold reduction, the UTS can reach up to 310 (2100 MPa) in strip form, highlighting the alloy's responsiveness to processing variations. The yield strength of Elgiloy in spring-tempered wire generally falls between 200 and 280 ksi (1380 to 1930 MPa), with minimum values increasing for smaller diameters due to higher degrees of cold work—such as 290 ksi for wires under 0.100 inches. Elongation at break varies from 5% to 15% depending on the extent of cold reduction, with lower values (around 5%) observed in heavily worked conditions and higher ductility in moderately reduced states. This range reflects the alloy's ability to balance formability and performance during fabrication. Despite heavy , Elgiloy retains significant while achieving elevated strength levels without propensity to . This retention stems from its coherent mechanism, which enhances strength through fine precipitates while preserving sufficient plastic deformation capacity.

Fatigue and Corrosion Resistance

Elgiloy demonstrates exceptional resistance, particularly in spring applications, where it achieves an limit of approximately 102 ksi at 10^7 cycles under reverse bending conditions for cold-reduced and heat-treated strip forms. This performance allows for prolonged service in demanding mechanical environments without significant degradation. The alloy's resistance is outstanding across various media, including saline solutions, acids, and alkalis, owing to the formation of a stable passive layer primarily from its content. In , Elgiloy is virtually immune to pitting, , and , even at elevated strength levels, with electrochemical tests confirming high pitting potentials that indicate robust protection against localized attack. Under prolonged exposure to corrosive conditions, Elgiloy maintains structural integrity, retaining full tensile strength after 365 days of alternate immersion in 3.5% NaCl solution at ambient temperature when stressed up to 90% of yield strength.

Processing and Heat Treatment

Fabrication Techniques

Elgiloy, a cobalt-based , is primarily fabricated through processes to produce wire, strip, and foil forms, leveraging its ability to undergo significant deformation without cracking. is the preferred method for shaping these products, enabling reductions up to approximately 70% in thickness or diameter, which enhances strength through by inducing deformation twinning and martensitic transformations in the austenitic matrix. This technique allows for the production of ultra-thin foils as fine as 0.0008 inches (0.02 mm), suitable for precision applications requiring high uniformity and surface quality. Machining Elgiloy presents challenges due to its high strength and work-hardening tendency, which can lead to rapid and surface if not managed properly. tools are essential for operations such as turning, milling, and , with moderate to low cutting speeds recommended—typically in the range of 20-50 surface feet per minute (sfm)—to maintain tool life and achieve acceptable surface finishes. The use of lubricants or coolants is critical during machining to reduce , prevent built-up edge formation, and minimize heat generation that could alter the alloy's microstructure. Forming Elgiloy, particularly for spring coiling, exploits its excellent ductility and elastic properties, allowing complex shapes to be produced with minimal springback. The alloy's spring temper condition facilitates tight coil windings, but intermediate annealing steps are often required between forming stages to restore ductility and relieve residual stresses from prior deformation. These anneals are typically conducted at temperatures between 1050°C and 1100°C for about 45 minutes, followed by controlled cooling to prevent unwanted phase changes. This process ensures the material retains its formability while preparing it for subsequent strengthening via aging.

Heat Treatment Methods

Elgiloy undergoes solution annealing to dissolve carbides, homogenize the microstructure, and restore after or fabrication. This process involves heating the to 2025–2075°F (1107–1135°C) for 1 to 2 hours, followed by a rapid water quench to prevent re-precipitation of phases that could reduce workability. The resulting annealed condition yields tensile strengths of 120–150 (830–1035 MPa), making it suitable for subsequent forming operations. Age hardening is a key thermal treatment for Elgiloy, typically applied after cold reduction to develop high strength through . The alloy is aged at 980°F (527°C) for 5 hours in air, which promotes the formation of fine precipitates that impede motion and achieve peak tensile strengths of 260–330 ksi (1790–2275 MPa). This treatment is particularly effective following cold work levels of 30–50% reduction, enhancing the alloy's suitability for high-stress components without significantly compromising resistance. For spring applications, Elgiloy components are often subjected to spring tempering after to relieve residual stresses and optimize performance. This involves heating at 850–950°F (454–510°C) for 4–6 hours, followed by , which balances the elastic modulus at approximately 29,000 while improving relaxation resistance under load. The process ensures stable dimensional recovery and life in coiled forms, with operating temperatures up to 850°F (-184°C to 454°C).

Applications

Medical and Biomedical Uses

Elgiloy, a cobalt-chromium-nickel-molybdenum alloy, is widely utilized in medical and biomedical applications due to its biocompatibility, high fatigue strength, and corrosion resistance in physiological environments. Its ability to maintain structural integrity under repeated stress makes it suitable for implantable and long-term contact devices. In cardiovascular devices, Elgiloy is employed in self-expanding stents, such as the Wallstent endoprosthesis, leveraging its superelastic properties for precise deployment and expansion within blood vessels. The stent's radiopacity, enhanced by a core, facilitates visibility under during procedures, ensuring reliability over years of pulsatile loading. Additionally, Elgiloy serves as a core in guidewires, providing low modulus for navigability through vasculature and resistance to kinking. For orthodontics and implants, Elgiloy wires and brackets are favored for dental alignment due to their adjustable stiffness through , allowing controlled force application over extended periods. The exhibits low leaching in oral environments, reducing risks of while maintaining for direct tissue contact. This makes it ideal for palatal expanders and orthodontic appliances requiring prolonged intraoral use. In surgical tools, Elgiloy is incorporated into springs for clamps and retractors, such as in clips, where its high yield strength and corrosion resistance ensure consistent performance during repeated openings and closures. The material supports its corrosion resistance that enhances overall in surgical settings.

Industrial and Aerospace Applications

Elgiloy, a cobalt-chromium-nickel-molybdenum , plays a critical role in applications due to its exceptional strength, resistance, and ability to perform in extreme thermal conditions. It is commonly utilized in torsion bars, seals, and components for civil and engines, as well as in space exploration hardware. The alloy's by Rolls-Royce ensures its reliability in high-stakes environments, where components must endure rigorous standards. Elgiloy maintains structural integrity across a temperature range of -184°C to 454°C, enabling its use in cryogenic to elevated-heat scenarios without significant degradation. In the oil and gas industry, Elgiloy is valued for its deployment in downhole springs and valves, where it confronts aggressive corrosive conditions involving (H₂S) and (CO₂). The material's resistance to stress cracking aligns with NACE MR0175/ISO 15156-3 standards, making it suitable for deep-well operations and control equipment. Its inherently non-magnetic properties further enhance its utility in downhole tools, including those for (MWD), by minimizing interference with magnetic sensing technologies in harsh subsurface environments. For and manufacturing, Elgiloy serves in precision components such as connectors and diaphragms, leveraging its non-magnetic characteristics and superior resistance to operate reliably in chambers or under high-vibration conditions. These attributes prevent signal in sensitive electronic assemblies and ensure longevity in processing equipment exposed to cyclic stresses. The alloy's combination of high tensile strength—up to 2600 MPa in aged conditions—and resistance supports its integration into satellite communications and other mission-critical electronic systems.

Comparisons and Advantages

Key Benefits

Elgiloy exhibits exceptional fatigue life, often surpassing that of conventional alloys in demanding cyclic loading conditions, which stems from its optimized microstructure achieved through age-hardening processes. This property, combined with a high strength-to-weight —typically yielding tensile strengths around 970 MPa at a of 8.30 g/cm³—allows for the of more compact components without sacrificing performance or durability. The demonstrates broad environmental tolerance, maintaining structural integrity from cryogenic temperatures up to 850°F (454°C), making it suitable for extreme operational conditions. Its superior resistance in harsh environments, including those with chlorides, acids, and elevated temperatures, minimizes degradation over time and thereby reduces long-term maintenance requirements. Elgiloy's versatility is enhanced by its availability in various forms, such as wire, strip, and foil, facilitating adaptation to diverse needs. Additionally, it is non-magnetic, ensuring compatibility in electromagnetic-sensitive applications, and biocompatible.

Comparisons with Similar Alloys

Elgiloy exhibits significantly higher fatigue life compared to 316L in spring applications under cyclic loading, along with superior resistance in chloride-containing environments such as bodily fluids or saline solutions; however, its higher and costs make it a premium choice reserved for demanding conditions. In medical implants like orthodontic wires and cardiac devices, Elgiloy offers dimensional stability. Compared to MP35N, a nickel-cobalt , Elgiloy provides similar levels of high strength and corrosion resistance. Both alloys are non-magnetic, making them suitable for applications requiring consistent performance, such as MRI-compatible medical tools, while Elgiloy may offer lower costs for precision springs in moderate-pressure environments. MP35N, however, outperforms Elgiloy in ultra-high-pressure scenarios, like deep-sea or oilfield equipment, where its enhanced resistance to is critical. Elgiloy demonstrates higher at than Haynes 25 (L-605), a cobalt-based , enabling better formability for intricate components like fine wires and springs without cracking. In contrast, Haynes 25 maintains superior strength and stability above 1000°C in gas turbine or furnace applications, where Elgiloy's performance diminishes. Trade-offs exist in oxidation resistance, with Haynes 25 forming a more robust protective layer for prolonged exposure to high-temperature oxidizing atmospheres, while Elgiloy suffices for moderate thermal conditions up to around 500°C.

References

  1. https://www.elgiloy.com/wire-elgiloy-alloy
  2. https://www.elgiloy.com/news
  3. https://www.elgiloy.com/2024/01/22/elgiloy-alloy-past-present-future
  4. https://www.elgiloy.com/about-us/about-us
  5. https://www.battelle.org/history/milestones
  6. https://www.combmet.com/our-history/
  7. https://www.azom.com/article.aspx?ArticleID=9574
  8. https://www.matweb.com/search/DataSheet.aspx?MatGUID=9bd90091755740648e2afa5cdb9fb09b
  9. https://www.stainless.eu/en/products/cobalt-alloys/elgiloy-phynox/
  10. https://link.springer.com/article/10.1007/BF01026957
  11. https://www.stainless.eu/wp-content/uploads/2023/03/Elgiloy%C2%AE-%E2%80%93-Phynox%C2%AE-EN.pdf
  12. https://www.elgiloy.com/strip-elgiloy-alloy
  13. https://pmc.ncbi.nlm.nih.gov/articles/PMC10140835/
  14. https://link.springer.com/article/10.1023/A:1008920415237
  15. https://suhm.net/wp-content/uploads/2015/09/Elgiloy_Spring_Tempered_Wire-EN-US_v3.html
  16. https://www.researchgate.net/publication/286776486_Thermo-mechanical_processing_of_Elgiloy
  17. http://www.hightechalloys.eu/pdf/Elgiloy_Flyer.pdf
  18. https://www.lookpolymers.com/pdf/Elgiloy-Co-Cr-Ni-Alloy-Strip-85-Cold-Reduction-Heat-Treated.pdf
  19. https://pubmed.ncbi.nlm.nih.gov/12557104/
  20. https://ntrs.nasa.gov/api/citations/20190027318/downloads/20190027318.pdf
  21. https://www.elgiloy.com/strip-division/capabilities
  22. https://www.stainless.eu/wp-content/uploads/2023/03/Elgiloy%25C2%25AE-%25E2%2580%2593-Phynox%25C2%25AE-EN.pdf
  23. https://dl.asminternational.org/handbooks/monograph/chapter-pdf/680794/t59310351.pdf
  24. https://www.acxesspring.com/how-to-heat-treat-spring-steel.html
  25. https://www.elgiloy.com/wire-division/markets-served/medical
  26. https://www.elgiloy.com/2024/01/22/elgiloy-for-medical-alloys-wire-and-strip
  27. https://evtoday.com/device-guide/euro/venous-stents-1
  28. https://www.accessdata.fda.gov/cdrh_docs/pdf5/P050019c.pdf
  29. https://patents.google.com/patent/WO2015020724A1/en
  30. https://www.sciencedirect.com/science/article/abs/pii/S0109564116300586
  31. https://www.mdpi.com/1420-3049/29/23/5685
  32. https://xdentlab.com/blue-elgiloy-composition-properties-and-clinical-applications
  33. https://www.deltamed.com.tr/urunler/aneurysm-clips-026920608478284747/mizuho-elgiloy-clips
  34. https://www.elgiloy.com/wire-division/markets-served/aerospace
  35. https://www.elgiloy.com/strip-division/accreditations
  36. https://www.elgiloy.com/wire-division/markets-served/oil-gas-extraction
  37. https://www.jamesspring.com/news/part-1-superiority-of-elgiloy-wire-in-challenging-environments/
  38. https://www.coilingtech.com/elgiloy-springs/
  39. https://www.elgiloy.com/
  40. https://kcseals.ca/when-to-consider-using-an-elgiloy-spring-over-a-316-stainless-steel-spring-as-the-energizer-for-ptfe-seals/
  41. https://www.elgiloy.com/wire-mp35n
  42. https://www.elgiloy.com/strip-mp35n-alloy
  43. https://www.elgiloy.com/strip-haynes-25-l605
  44. https://haynesintl.com/en/alloys/alloy-portfolio/high-temperature-alloys/haynes-25/
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